Cyclic vanadium(V) alkoxide. An analog of the ribonuclease inhibitors
This article reports the preparation and structural characterization of the first cyclic vanadium alkoxide. This pinacol-vanadium(V) complex was formed from VOCl sub(2) and pinacol in methylene chloride and recrystallized from chloroform in 83% yield. The vanadium atoms in the complex were pentacoor...
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| Veröffentlicht in: | Journal of the American Chemical Society 1991-01, Vol.113 (1), p.265-269 |
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| container_end_page | 269 |
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| container_title | Journal of the American Chemical Society |
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| creator | Crans, Debbie C Felty, Robert A Miller, Mary M |
| description | This article reports the preparation and structural characterization of the first cyclic vanadium alkoxide. This pinacol-vanadium(V) complex was formed from VOCl sub(2) and pinacol in methylene chloride and recrystallized from chloroform in 83% yield. The vanadium atoms in the complex were pentacoordinate in a distorted trigonal-bipyrimid geometry achieved by dimerization through bridging of one of the oxygen atoms of each of the pinacol moieties. |
| doi_str_mv | 10.1021/ja00001a038 |
| format | Article |
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| ispartof | Journal of the American Chemical Society, 1991-01, Vol.113 (1), p.265-269 |
| issn | 0002-7863 1520-5126 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_16430322 |
| source | ACS Publications |
| subjects | Bioinorganic chemistry Chemistry Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Inorganic chemistry and origins of life Inorganic compounds Metal complexes Physics Structure of solids and liquids crystallography Structure of specific crystalline solids |
| title | Cyclic vanadium(V) alkoxide. An analog of the ribonuclease inhibitors |
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