Geometrically Restricted Intermediates in the Self-Assembly of an M12L24 Cuboctahedral Complex

The self‐assembly of a cuboctahedral M12L24 complex is traced by time‐dependent NMR spectroscopy and mass spectrometry. The metastable intermediate structures that exist during the self‐assembly process are not a chaotic mixture of numerous species, but instead are geometrically restricted. Short‐li...

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Veröffentlicht in:	Angewandte Chemie International Edition 2015-01, Vol.54 (1), p.155-158
Hauptverfasser:	Fujita, Daishi, Yokoyama, Hiroyuki, Ueda, Yoshihiro, Sato, Sota, Fujita, Makoto
Format:	Artikel
Sprache:	eng
Schlagworte:	Assembly Crystallography geometrical restriction Intermediates Magnetic resonance spectroscopy Mass spectrometry Mass spectroscopy metastable intermediates NMR NMR spectroscopy Nuclear magnetic resonance palladium self-assembly Spectroscopy Topology
Online-Zugang:	Volltext
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