Na[FSA]-[C sub(3)C sub(1)pyrr][FSA] ionic liquids as electrolytes for sodium secondary batteries: Effects of Na ion concentration and operation temperature
As electrolytes for sodium secondary batteries operating over a wide temperature range, Na[FSA]-[C sub(3)C sub(1)pyrr][FSA] (FSA = bis(fluorosulfonyl)amide, C sub(3)C sub(1)pyrr = N-methyl-N-propylpyrrolidinium) ionic liquids have been investigated. The effects of Na ion concentration (0-60 mol% Na[...
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| Veröffentlicht in: | Journal of power sources 2014-12, Vol.269, p.124-128 |
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| container_title | Journal of power sources |
| container_volume | 269 |
| creator | Ding, Changsheng Nohira, Toshiyuki Hagiwara, Rika Matsumoto, Kazuhiko Okamoto, Yu Fukunaga, Atsushi Sakai, Shoichiro Nitta, Koji Inazawa, Shinji |
| description | As electrolytes for sodium secondary batteries operating over a wide temperature range, Na[FSA]-[C sub(3)C sub(1)pyrr][FSA] (FSA = bis(fluorosulfonyl)amide, C sub(3)C sub(1)pyrr = N-methyl-N-propylpyrrolidinium) ionic liquids have been investigated. The effects of Na ion concentration (0-60 mol% Na[FSA]) and operation temperature (253-363 K) on the viscosity and ionic conductivity and charge-discharge performance of Na/Na[FSA]-[C sub(3)C sub(1)pyrr] [FSA]/NaCrO sub(2) cells are studied. Results show that Na ion concentration strongly affects the rate capability of the cells, and that the best rate capability at 363 K is obtained at 40 mol% Na [FSA]. The operation temperature also significantly influences the charge-discharge performance, especially at low temperatures. At operation temperatures below 273 K, 25 mol% Na[FSA] is found to be the optimum Na ion concentration. There exist different optimum ranges of Na ion concentration depending on the operation temperatures. |
| doi_str_mv | 10.1016/j.jpowsour.2014.06.033 |
| format | Article |
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The effects of Na ion concentration (0-60 mol% Na[FSA]) and operation temperature (253-363 K) on the viscosity and ionic conductivity and charge-discharge performance of Na/Na[FSA]-[C sub(3)C sub(1)pyrr] [FSA]/NaCrO sub(2) cells are studied. Results show that Na ion concentration strongly affects the rate capability of the cells, and that the best rate capability at 363 K is obtained at 40 mol% Na [FSA]. The operation temperature also significantly influences the charge-discharge performance, especially at low temperatures. At operation temperatures below 273 K, 25 mol% Na[FSA] is found to be the optimum Na ion concentration. 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The effects of Na ion concentration (0-60 mol% Na[FSA]) and operation temperature (253-363 K) on the viscosity and ionic conductivity and charge-discharge performance of Na/Na[FSA]-[C sub(3)C sub(1)pyrr] [FSA]/NaCrO sub(2) cells are studied. Results show that Na ion concentration strongly affects the rate capability of the cells, and that the best rate capability at 363 K is obtained at 40 mol% Na [FSA]. The operation temperature also significantly influences the charge-discharge performance, especially at low temperatures. At operation temperatures below 273 K, 25 mol% Na[FSA] is found to be the optimum Na ion concentration. 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The effects of Na ion concentration (0-60 mol% Na[FSA]) and operation temperature (253-363 K) on the viscosity and ionic conductivity and charge-discharge performance of Na/Na[FSA]-[C sub(3)C sub(1)pyrr] [FSA]/NaCrO sub(2) cells are studied. Results show that Na ion concentration strongly affects the rate capability of the cells, and that the best rate capability at 363 K is obtained at 40 mol% Na [FSA]. The operation temperature also significantly influences the charge-discharge performance, especially at low temperatures. At operation temperatures below 273 K, 25 mol% Na[FSA] is found to be the optimum Na ion concentration. There exist different optimum ranges of Na ion concentration depending on the operation temperatures.</abstract><doi>10.1016/j.jpowsour.2014.06.033</doi><tpages>5</tpages></addata></record> |
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| ispartof | Journal of power sources, 2014-12, Vol.269, p.124-128 |
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| language | eng |
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| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Electrolytes Electrolytic cells Ion concentration Ionic conductivity Ionic liquids Optimization Sodium Storage batteries |
| title | Na[FSA]-[C sub(3)C sub(1)pyrr][FSA] ionic liquids as electrolytes for sodium secondary batteries: Effects of Na ion concentration and operation temperature |
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