Second-coordination-sphere and electronic effects enhance iridium(iii)-catalyzed homogeneous hydrogenation of carbon dioxide in water near ambient temperature and pressure

A new series of water soluble Ir(iii) catalysts has been designed and synthesized to determine the catalyst ligand's role in activating CO sub(2) through electronic and second-coordination-sphere effects for the homogeneous catalytic hydrogenation of CO sub(2). We report high catalytic hydrogen...

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Veröffentlicht in:	Energy & environmental science 2012-07, Vol.5 (7), p.7923-7926
Hauptverfasser:	Wang, Wan-Hui, Hull, Jonathan F, Muckerman, James T, Fujita, Etsuko, Himeda, Yuichiro
Format:	Artikel
Sprache:	eng
Schlagworte:	Ambient temperature Carbon dioxide Catalysis Catalysts Electronics Hydrogenation Ligands Mathematical analysis
Online-Zugang:	Volltext
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