Ultra-broadband near-infrared emission in bismuth borosilicate glasses incorporated with Er3+, Tm3+, and Yb3+ ions

Bismuth containing glasses are interesting photonic materials due to their broadband emission properties in the near-infrared wavelength range. Bismuth alumino-borosilicate glasses co-doped with Er3+, Tm3+, and Yb3+ ions were prepared by the conventional glass melting process and their optical absor...

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Veröffentlicht in:Journal of non-crystalline solids 2014-10, Vol.402, p.106-110
Hauptverfasser: Son, Dong Hoon, Kim, Bok Hyeon, Lee, Seung Ho, Boo, Seongjae, Han, Won-Taek
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Kim, Bok Hyeon
Lee, Seung Ho
Boo, Seongjae
Han, Won-Taek
description Bismuth containing glasses are interesting photonic materials due to their broadband emission properties in the near-infrared wavelength range. Bismuth alumino-borosilicate glasses co-doped with Er3+, Tm3+, and Yb3+ ions were prepared by the conventional glass melting process and their optical absorption, near-infrared emission, and lifetime characteristics were investigated. Upon pumping at 800nm with a Ti:sapphire laser, a very broad emission band covering at 900–1700nm was found to appear due to overlapping of the emissions centering at 1003, 1266, 1536, and 1643nm from the co-doped ions of Yb3+, Bi, Er3+, and Tm3+, respectively. The emission intensity and the lifetime of the emission bands were significantly influenced by the addition of Yb2O3. The pump energy absorbed by Bi was transferred to Yb3+ and Er3+ ions and the amount of the transferred energy was enhanced with the increase of Yb2O3. The energy transfer efficiency from Bi to the co-doped rare earth ions was ~4.0% at 2mol% of Yb2O3. •A very broadband emission was obtained in the Er3+/Tm3+/Yb3+ triply doped Bi borosilicate glasses.•The broad emission band resulted from the overlapping of the individual emission bands.•The pump energy absorbed by Bi+ was transferred to Yb3+ and Er3+.•The amount of transferred energy increased with the increase of Yb2O3 concentration.
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Bismuth alumino-borosilicate glasses co-doped with Er3+, Tm3+, and Yb3+ ions were prepared by the conventional glass melting process and their optical absorption, near-infrared emission, and lifetime characteristics were investigated. Upon pumping at 800nm with a Ti:sapphire laser, a very broad emission band covering at 900–1700nm was found to appear due to overlapping of the emissions centering at 1003, 1266, 1536, and 1643nm from the co-doped ions of Yb3+, Bi, Er3+, and Tm3+, respectively. The emission intensity and the lifetime of the emission bands were significantly influenced by the addition of Yb2O3. The pump energy absorbed by Bi was transferred to Yb3+ and Er3+ ions and the amount of the transferred energy was enhanced with the increase of Yb2O3. 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The energy transfer efficiency from Bi to the co-doped rare earth ions was ~4.0% at 2mol% of Yb2O3. •A very broadband emission was obtained in the Er3+/Tm3+/Yb3+ triply doped Bi borosilicate glasses.•The broad emission band resulted from the overlapping of the individual emission bands.•The pump energy absorbed by Bi+ was transferred to Yb3+ and Er3+.•The amount of transferred energy increased with the increase of Yb2O3 concentration.</abstract><cop>Oxford</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jnoncrysol.2014.05.022</doi><tpages>5</tpages></addata></record>
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subjects Bands
Bismuth
Bismuth alumino-borosilicate glass
Broadband near-infrared emission
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Cross-disciplinary physics: materials science
rheology
Emission
Energy transfer
Exact sciences and technology
Glass
Glass melting process
Glasses (including metallic glasses)
Lifetime
Materials science
Optical data processing
Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation
Optical pumping
Photoluminescence
Physics
Pumps
Rare earth metals
Specific materials
title Ultra-broadband near-infrared emission in bismuth borosilicate glasses incorporated with Er3+, Tm3+, and Yb3+ ions
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