Separations of lanthanides and actinides using novel hybrid ion exchange materials, M(IV) phosphonates
Zirconium diethylene triamine pentamethylene phosphonate and titanium diethylene triamine pentamethylene phosphonate, novel hybrid cation exchange materials of the class of tetravalent metal acid salts, synthesized by sol-gel method has been characterized by spectroscopy and thermal analysis. Distri...
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Veröffentlicht in: | Desalination and water treatment 2014, Vol.52 (1-3), p.481-489 |
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description | Zirconium diethylene triamine pentamethylene phosphonate and titanium diethylene triamine pentamethylene phosphonate, novel hybrid cation exchange materials of the class of tetravalent metal acid salts, synthesized by sol-gel method has been characterized by spectroscopy and thermal analysis. Distribution coefficient and breakthrough capacity for La3+, Ce3+, Pr3+, Nd3+, Sm3+ (lanthanides) and Th4+, UO22+ (actinides) have been studied. Based on the differential affinity/selectivity and elution behavior of various metal ions, a few binary and ternary metal ion separations have been carried out. |
doi_str_mv | 10.1080/19443994.2013.808796 |
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Distribution coefficient and breakthrough capacity for La3+, Ce3+, Pr3+, Nd3+, Sm3+ (lanthanides) and Th4+, UO22+ (actinides) have been studied. Based on the differential affinity/selectivity and elution behavior of various metal ions, a few binary and ternary metal ion separations have been carried out.</description><identifier>ISSN: 1944-3986</identifier><identifier>ISSN: 1944-3994</identifier><identifier>EISSN: 1944-3986</identifier><identifier>DOI: 10.1080/19443994.2013.808796</identifier><language>eng</language><publisher>Elsevier Inc</publisher><subject>Actinides ; Cation exchangers ; Diethylene triamine ; Exchange ; Hybrid materials ; Ion exchange materials ; Ion exchangers ; Lanthanides ; Metal phosphonates ; Metal separations ; Phosphonates ; Separation ; Tetravalent metal acid salts ; Titanium diethylene triamine pentamethylene phosphonate ; Zirconium diethylene triamine pentamethylene phosphonate</subject><ispartof>Desalination and water treatment, 2014, Vol.52 (1-3), p.481-489</ispartof><rights>2013 Elsevier Inc.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c438t-6ff9201829746c928d6e44c3e22fb19c7321ab866bcac84293930e20484b97573</citedby><cites>FETCH-LOGICAL-c438t-6ff9201829746c928d6e44c3e22fb19c7321ab866bcac84293930e20484b97573</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,4014,27914,27915,27916</link.rule.ids></links><search><creatorcontrib>Patel, Parimal R.</creatorcontrib><creatorcontrib>Chudasama, Uma V.</creatorcontrib><title>Separations of lanthanides and actinides using novel hybrid ion exchange materials, M(IV) phosphonates</title><title>Desalination and water treatment</title><description>Zirconium diethylene triamine pentamethylene phosphonate and titanium diethylene triamine pentamethylene phosphonate, novel hybrid cation exchange materials of the class of tetravalent metal acid salts, synthesized by sol-gel method has been characterized by spectroscopy and thermal analysis. Distribution coefficient and breakthrough capacity for La3+, Ce3+, Pr3+, Nd3+, Sm3+ (lanthanides) and Th4+, UO22+ (actinides) have been studied. Based on the differential affinity/selectivity and elution behavior of various metal ions, a few binary and ternary metal ion separations have been carried out.</description><subject>Actinides</subject><subject>Cation exchangers</subject><subject>Diethylene triamine</subject><subject>Exchange</subject><subject>Hybrid materials</subject><subject>Ion exchange materials</subject><subject>Ion exchangers</subject><subject>Lanthanides</subject><subject>Metal phosphonates</subject><subject>Metal separations</subject><subject>Phosphonates</subject><subject>Separation</subject><subject>Tetravalent metal acid salts</subject><subject>Titanium diethylene triamine pentamethylene phosphonate</subject><subject>Zirconium diethylene triamine pentamethylene phosphonate</subject><issn>1944-3986</issn><issn>1944-3994</issn><issn>1944-3986</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqFUV1LwzAULaLgmPsHPuRxgp1pkqbJiyDDj8HEBz9eQ5rebpGuqUk33L83owo-6YXLTe4958DhJMl5hmcZFvgqk4xRKdmM4IzOBBaF5EfJ6LBOqRT8-Nf7NJmE8I5j5azIGRkl9TN02uveujYgV6NGt_1at7aCgHRbIW16O_y2wbYr1LodNGi9L72tUCQh-DQRvwK00T14q5twiR6ni7cL1K1diN3GfThLTup4gsn3HCevd7cv84d0-XS_mN8sU8Oo6FNe1zLaEEQWjBtJRMWBMUOBkLrMpCkoyXQpOC-NNoIRSSXFQDATrJRFXtBxMh10O-8-thB6tbHBQBNtgdsGlXFGiMRU8v-heS55FJYkQtkANd6F4KFWnbcb7fcqw-oQgvoJQR1CUEMIkXY90CA63lnwKhgLrYHKejC9qpz9W-AL7xyMdA</recordid><startdate>2014</startdate><enddate>2014</enddate><creator>Patel, Parimal R.</creator><creator>Chudasama, Uma V.</creator><general>Elsevier Inc</general><scope>6I.</scope><scope>AAFTH</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope><scope>7ST</scope><scope>7TN</scope><scope>7UA</scope><scope>C1K</scope><scope>F1W</scope><scope>H96</scope><scope>H97</scope><scope>L.G</scope><scope>SOI</scope><scope>7SU</scope><scope>8FD</scope><scope>FR3</scope><scope>KR7</scope></search><sort><creationdate>2014</creationdate><title>Separations of lanthanides and actinides using novel hybrid ion exchange materials, M(IV) phosphonates</title><author>Patel, Parimal R. ; 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Distribution coefficient and breakthrough capacity for La3+, Ce3+, Pr3+, Nd3+, Sm3+ (lanthanides) and Th4+, UO22+ (actinides) have been studied. Based on the differential affinity/selectivity and elution behavior of various metal ions, a few binary and ternary metal ion separations have been carried out.</abstract><pub>Elsevier Inc</pub><doi>10.1080/19443994.2013.808796</doi><tpages>9</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Actinides Cation exchangers Diethylene triamine Exchange Hybrid materials Ion exchange materials Ion exchangers Lanthanides Metal phosphonates Metal separations Phosphonates Separation Tetravalent metal acid salts Titanium diethylene triamine pentamethylene phosphonate Zirconium diethylene triamine pentamethylene phosphonate |
title | Separations of lanthanides and actinides using novel hybrid ion exchange materials, M(IV) phosphonates |
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