Separations of lanthanides and actinides using novel hybrid ion exchange materials, M(IV) phosphonates

Zirconium diethylene triamine pentamethylene phosphonate and titanium diethylene triamine pentamethylene phosphonate, novel hybrid cation exchange materials of the class of tetravalent metal acid salts, synthesized by sol-gel method has been characterized by spectroscopy and thermal analysis. Distri...

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Veröffentlicht in:Desalination and water treatment 2014, Vol.52 (1-3), p.481-489
Hauptverfasser: Patel, Parimal R., Chudasama, Uma V.
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description Zirconium diethylene triamine pentamethylene phosphonate and titanium diethylene triamine pentamethylene phosphonate, novel hybrid cation exchange materials of the class of tetravalent metal acid salts, synthesized by sol-gel method has been characterized by spectroscopy and thermal analysis. Distribution coefficient and breakthrough capacity for La3+, Ce3+, Pr3+, Nd3+, Sm3+ (lanthanides) and Th4+, UO22+ (actinides) have been studied. Based on the differential affinity/selectivity and elution behavior of various metal ions, a few binary and ternary metal ion separations have been carried out.
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subjects Actinides
Cation exchangers
Diethylene triamine
Exchange
Hybrid materials
Ion exchange materials
Ion exchangers
Lanthanides
Metal phosphonates
Metal separations
Phosphonates
Separation
Tetravalent metal acid salts
Titanium diethylene triamine pentamethylene phosphonate
Zirconium diethylene triamine pentamethylene phosphonate
title Separations of lanthanides and actinides using novel hybrid ion exchange materials, M(IV) phosphonates
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