Dual cloud point extraction coupled with hydrodynamic-electrokinetic two-step injection followed by micellar electrokinetic chromatography for simultaneous determination of trace phenolic estrogens in water samples
A dual cloud point extraction (dCPE) off-line enrichment procedure coupled with a hydrodynamic–electrokinetic two-step injection online enrichment technique was successfully developed for simultaneous preconcentration of trace phenolic estrogens (hexestrol, dienestrol, and diethylstilbestrol) in wat...
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| Veröffentlicht in: | Analytical and bioanalytical chemistry 2013-07, Vol.405 (17), p.5843-5852 |
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| creator | Wen, Yingying Li, Jinhua Liu, Junshen Lu, Wenhui Ma, Jiping Chen, Lingxin |
| description | A dual cloud point extraction (dCPE) off-line enrichment procedure coupled with a hydrodynamic–electrokinetic two-step injection online enrichment technique was successfully developed for simultaneous preconcentration of trace phenolic estrogens (hexestrol, dienestrol, and diethylstilbestrol) in water samples followed by micellar electrokinetic chromatography (MEKC) analysis. Several parameters affecting the extraction and online injection conditions were optimized. Under optimal dCPE–two-step injection–MEKC conditions, detection limits of 7.9–8.9 ng/mL and good linearity in the range from 0.05 to 5 μg/mL with correlation coefficients
R
2
≥ 0.9990 were achieved. Satisfactory recoveries ranging from 83 to 108 % were obtained with lake and tap water spiked at 0.1 and 0.5 μg/mL, respectively, with relative standard deviations (
n
= 6) of 1.3–3.1 %. This method was demonstrated to be convenient, rapid, cost-effective, and environmentally benign, and could be used as an alternative to existing methods for analyzing trace residues of phenolic estrogens in water samples.
Figure
A dual cloud point extraction (dCPE) off-line enrichment procedure coupled with a hydrodynamic–electrokinetic two-step injection online enrichment technique was successfully developed for simultaneous preconcentration of trace phenolic estrogens in water samples followed by MEKC analysis. |
| doi_str_mv | 10.1007/s00216-013-6989-8 |
| format | Article |
| fullrecord | <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_miscellaneous_1642286739</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A341128003</galeid><sourcerecordid>A341128003</sourcerecordid><originalsourceid>FETCH-LOGICAL-c585t-6ba86412b3c51d948464ff3d37cf9c6ac5384c537f2c2c812d54302030a7a5af3</originalsourceid><addsrcrecordid>eNqFks1u1DAUhSMEoqXwAGyQJTZsUvybOMuq_EqV2MDa8jj2jItjB9vRdF6U5-HOTClQgZAlO7LPd3KvfZrmOcHnBOP-dcGYkq7FhLXdIIdWPmhOSUdkSzuBH959c3rSPCnlGmMiJOkeNyeUdaLngp42398sOiAT0jKiOflYkb2pWZvqU0QmLXOwI9r6ukGb3ZjTuIt68qa1wZqa01cfbfUG1W1qS7Uz8vHaHlmXQkhbgFc7BIQNQWd0DzObnCZd0zrrebMDJKPipyVUHW1aChpttXnyUR8ck0P7yiyaNzamALwtYLa2scB_0VaDGBU9QcnlafPI6VDss9v1rPny7u3nyw_t1af3Hy8vrlojpKhtt9Ky44SumBFkHLjkHXeOjaw3bjCdNoJJDlPvqKFGEjoKzjDFDOteC-3YWfPq6Dvn9G2BetTky6HZQweKwOVT2fVs-L-Us6HnjPU9SF_ek16nJUdoBAx7TJmggv5SrXWwykeX9tezN1UXjBNCJcYMVOd_UcEYLTxLitZ52P8DIEfA5FRKtk7N2U867xTBah87dYydgtipfeyUBObFbcHLarLjHfEzZyCgR0GBo7i2-beO_un6A8cx52w</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1670235252</pqid></control><display><type>article</type><title>Dual cloud point extraction coupled with hydrodynamic-electrokinetic two-step injection followed by micellar electrokinetic chromatography for simultaneous determination of trace phenolic estrogens in water samples</title><source>MEDLINE</source><source>SpringerLink Journals - AutoHoldings</source><creator>Wen, Yingying ; Li, Jinhua ; Liu, Junshen ; Lu, Wenhui ; Ma, Jiping ; Chen, Lingxin</creator><creatorcontrib>Wen, Yingying ; Li, Jinhua ; Liu, Junshen ; Lu, Wenhui ; Ma, Jiping ; Chen, Lingxin</creatorcontrib><description>A dual cloud point extraction (dCPE) off-line enrichment procedure coupled with a hydrodynamic–electrokinetic two-step injection online enrichment technique was successfully developed for simultaneous preconcentration of trace phenolic estrogens (hexestrol, dienestrol, and diethylstilbestrol) in water samples followed by micellar electrokinetic chromatography (MEKC) analysis. Several parameters affecting the extraction and online injection conditions were optimized. Under optimal dCPE–two-step injection–MEKC conditions, detection limits of 7.9–8.9 ng/mL and good linearity in the range from 0.05 to 5 μg/mL with correlation coefficients
R
2
≥ 0.9990 were achieved. Satisfactory recoveries ranging from 83 to 108 % were obtained with lake and tap water spiked at 0.1 and 0.5 μg/mL, respectively, with relative standard deviations (
n
= 6) of 1.3–3.1 %. This method was demonstrated to be convenient, rapid, cost-effective, and environmentally benign, and could be used as an alternative to existing methods for analyzing trace residues of phenolic estrogens in water samples.
Figure
A dual cloud point extraction (dCPE) off-line enrichment procedure coupled with a hydrodynamic–electrokinetic two-step injection online enrichment technique was successfully developed for simultaneous preconcentration of trace phenolic estrogens in water samples followed by MEKC analysis.</description><identifier>ISSN: 1618-2642</identifier><identifier>EISSN: 1618-2650</identifier><identifier>DOI: 10.1007/s00216-013-6989-8</identifier><identifier>PMID: 23657452</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer-Verlag</publisher><subject>Analytical Chemistry ; Biochemistry ; Characterization and Evaluation of Materials ; Chemical properties ; Chemistry ; Chemistry and Materials Science ; Chromatography ; Chromatography, Micellar Electrokinetic Capillary - instrumentation ; Chromatography, Micellar Electrokinetic Capillary - methods ; Correlation coefficient ; Detection limits ; Drinking water ; Electrokinetics ; Endocrine Disruptors - analysis ; Endocrine Disruptors - isolation & purification ; Enrichment ; Estrogen ; Estrogens ; Estrogens - analysis ; Estrogens - isolation & purification ; Extraction ; Extraction (Chemistry) ; Food Science ; Fresh Water - analysis ; Hydrodynamics ; Hydrofoil boats ; Identification and classification ; Injection ; Laboratory Medicine ; Liquid-Liquid Extraction - methods ; Mass spectrometry ; Methods ; Micropollutants ; Monitoring/Environmental Analysis ; On-line systems ; Online ; Phenols ; Phenols - analysis ; Phenols - isolation & purification ; Research Paper ; Standard deviation ; Surfactants ; Water analysis ; Water chemistry ; Water Pollutants, Chemical - analysis ; Water Pollutants, Chemical - isolation & purification ; Water sampling</subject><ispartof>Analytical and bioanalytical chemistry, 2013-07, Vol.405 (17), p.5843-5852</ispartof><rights>Springer-Verlag Berlin Heidelberg 2013</rights><rights>COPYRIGHT 2013 Springer</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c585t-6ba86412b3c51d948464ff3d37cf9c6ac5384c537f2c2c812d54302030a7a5af3</citedby><cites>FETCH-LOGICAL-c585t-6ba86412b3c51d948464ff3d37cf9c6ac5384c537f2c2c812d54302030a7a5af3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00216-013-6989-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00216-013-6989-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/23657452$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Wen, Yingying</creatorcontrib><creatorcontrib>Li, Jinhua</creatorcontrib><creatorcontrib>Liu, Junshen</creatorcontrib><creatorcontrib>Lu, Wenhui</creatorcontrib><creatorcontrib>Ma, Jiping</creatorcontrib><creatorcontrib>Chen, Lingxin</creatorcontrib><title>Dual cloud point extraction coupled with hydrodynamic-electrokinetic two-step injection followed by micellar electrokinetic chromatography for simultaneous determination of trace phenolic estrogens in water samples</title><title>Analytical and bioanalytical chemistry</title><addtitle>Anal Bioanal Chem</addtitle><addtitle>Anal Bioanal Chem</addtitle><description>A dual cloud point extraction (dCPE) off-line enrichment procedure coupled with a hydrodynamic–electrokinetic two-step injection online enrichment technique was successfully developed for simultaneous preconcentration of trace phenolic estrogens (hexestrol, dienestrol, and diethylstilbestrol) in water samples followed by micellar electrokinetic chromatography (MEKC) analysis. Several parameters affecting the extraction and online injection conditions were optimized. Under optimal dCPE–two-step injection–MEKC conditions, detection limits of 7.9–8.9 ng/mL and good linearity in the range from 0.05 to 5 μg/mL with correlation coefficients
R
2
≥ 0.9990 were achieved. Satisfactory recoveries ranging from 83 to 108 % were obtained with lake and tap water spiked at 0.1 and 0.5 μg/mL, respectively, with relative standard deviations (
n
= 6) of 1.3–3.1 %. This method was demonstrated to be convenient, rapid, cost-effective, and environmentally benign, and could be used as an alternative to existing methods for analyzing trace residues of phenolic estrogens in water samples.
Figure
A dual cloud point extraction (dCPE) off-line enrichment procedure coupled with a hydrodynamic–electrokinetic two-step injection online enrichment technique was successfully developed for simultaneous preconcentration of trace phenolic estrogens in water samples followed by MEKC analysis.</description><subject>Analytical Chemistry</subject><subject>Biochemistry</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical properties</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chromatography</subject><subject>Chromatography, Micellar Electrokinetic Capillary - instrumentation</subject><subject>Chromatography, Micellar Electrokinetic Capillary - methods</subject><subject>Correlation coefficient</subject><subject>Detection limits</subject><subject>Drinking water</subject><subject>Electrokinetics</subject><subject>Endocrine Disruptors - analysis</subject><subject>Endocrine Disruptors - isolation & purification</subject><subject>Enrichment</subject><subject>Estrogen</subject><subject>Estrogens</subject><subject>Estrogens - analysis</subject><subject>Estrogens - isolation & purification</subject><subject>Extraction</subject><subject>Extraction (Chemistry)</subject><subject>Food Science</subject><subject>Fresh Water - analysis</subject><subject>Hydrodynamics</subject><subject>Hydrofoil boats</subject><subject>Identification and classification</subject><subject>Injection</subject><subject>Laboratory Medicine</subject><subject>Liquid-Liquid Extraction - methods</subject><subject>Mass spectrometry</subject><subject>Methods</subject><subject>Micropollutants</subject><subject>Monitoring/Environmental Analysis</subject><subject>On-line systems</subject><subject>Online</subject><subject>Phenols</subject><subject>Phenols - analysis</subject><subject>Phenols - isolation & purification</subject><subject>Research Paper</subject><subject>Standard deviation</subject><subject>Surfactants</subject><subject>Water analysis</subject><subject>Water chemistry</subject><subject>Water Pollutants, Chemical - analysis</subject><subject>Water Pollutants, Chemical - isolation & purification</subject><subject>Water 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cloud point extraction coupled with hydrodynamic-electrokinetic two-step injection followed by micellar electrokinetic chromatography for simultaneous determination of trace phenolic estrogens in water samples</title><author>Wen, Yingying ; Li, Jinhua ; Liu, Junshen ; Lu, Wenhui ; Ma, Jiping ; Chen, Lingxin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c585t-6ba86412b3c51d948464ff3d37cf9c6ac5384c537f2c2c812d54302030a7a5af3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Analytical Chemistry</topic><topic>Biochemistry</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical properties</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chromatography</topic><topic>Chromatography, Micellar Electrokinetic Capillary - instrumentation</topic><topic>Chromatography, Micellar Electrokinetic Capillary - methods</topic><topic>Correlation coefficient</topic><topic>Detection limits</topic><topic>Drinking water</topic><topic>Electrokinetics</topic><topic>Endocrine Disruptors - analysis</topic><topic>Endocrine Disruptors - isolation & purification</topic><topic>Enrichment</topic><topic>Estrogen</topic><topic>Estrogens</topic><topic>Estrogens - analysis</topic><topic>Estrogens - isolation & purification</topic><topic>Extraction</topic><topic>Extraction (Chemistry)</topic><topic>Food Science</topic><topic>Fresh Water - analysis</topic><topic>Hydrodynamics</topic><topic>Hydrofoil boats</topic><topic>Identification and classification</topic><topic>Injection</topic><topic>Laboratory Medicine</topic><topic>Liquid-Liquid Extraction - methods</topic><topic>Mass spectrometry</topic><topic>Methods</topic><topic>Micropollutants</topic><topic>Monitoring/Environmental Analysis</topic><topic>On-line systems</topic><topic>Online</topic><topic>Phenols</topic><topic>Phenols - analysis</topic><topic>Phenols 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Junshen</au><au>Lu, Wenhui</au><au>Ma, Jiping</au><au>Chen, Lingxin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dual cloud point extraction coupled with hydrodynamic-electrokinetic two-step injection followed by micellar electrokinetic chromatography for simultaneous determination of trace phenolic estrogens in water samples</atitle><jtitle>Analytical and bioanalytical chemistry</jtitle><stitle>Anal Bioanal Chem</stitle><addtitle>Anal Bioanal Chem</addtitle><date>2013-07-01</date><risdate>2013</risdate><volume>405</volume><issue>17</issue><spage>5843</spage><epage>5852</epage><pages>5843-5852</pages><issn>1618-2642</issn><eissn>1618-2650</eissn><abstract>A dual cloud point extraction (dCPE) off-line enrichment procedure coupled with a hydrodynamic–electrokinetic two-step injection online enrichment technique was successfully developed for simultaneous preconcentration of trace phenolic estrogens (hexestrol, dienestrol, and diethylstilbestrol) in water samples followed by micellar electrokinetic chromatography (MEKC) analysis. Several parameters affecting the extraction and online injection conditions were optimized. Under optimal dCPE–two-step injection–MEKC conditions, detection limits of 7.9–8.9 ng/mL and good linearity in the range from 0.05 to 5 μg/mL with correlation coefficients
R
2
≥ 0.9990 were achieved. Satisfactory recoveries ranging from 83 to 108 % were obtained with lake and tap water spiked at 0.1 and 0.5 μg/mL, respectively, with relative standard deviations (
n
= 6) of 1.3–3.1 %. This method was demonstrated to be convenient, rapid, cost-effective, and environmentally benign, and could be used as an alternative to existing methods for analyzing trace residues of phenolic estrogens in water samples.
Figure
A dual cloud point extraction (dCPE) off-line enrichment procedure coupled with a hydrodynamic–electrokinetic two-step injection online enrichment technique was successfully developed for simultaneous preconcentration of trace phenolic estrogens in water samples followed by MEKC analysis.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer-Verlag</pub><pmid>23657452</pmid><doi>10.1007/s00216-013-6989-8</doi><tpages>10</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | Analytical Chemistry Biochemistry Characterization and Evaluation of Materials Chemical properties Chemistry Chemistry and Materials Science Chromatography Chromatography, Micellar Electrokinetic Capillary - instrumentation Chromatography, Micellar Electrokinetic Capillary - methods Correlation coefficient Detection limits Drinking water Electrokinetics Endocrine Disruptors - analysis Endocrine Disruptors - isolation & purification Enrichment Estrogen Estrogens Estrogens - analysis Estrogens - isolation & purification Extraction Extraction (Chemistry) Food Science Fresh Water - analysis Hydrodynamics Hydrofoil boats Identification and classification Injection Laboratory Medicine Liquid-Liquid Extraction - methods Mass spectrometry Methods Micropollutants Monitoring/Environmental Analysis On-line systems Online Phenols Phenols - analysis Phenols - isolation & purification Research Paper Standard deviation Surfactants Water analysis Water chemistry Water Pollutants, Chemical - analysis Water Pollutants, Chemical - isolation & purification Water sampling |
| title | Dual cloud point extraction coupled with hydrodynamic-electrokinetic two-step injection followed by micellar electrokinetic chromatography for simultaneous determination of trace phenolic estrogens in water samples |
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