Electrochromic windows based on anodic electrochromic polymesitylenes containing 9H-carbazole-9-ethanol moieties
The anodic monomer 1,3,5-tris(2-(9H-carbazol-9-yl)methyl)benzene, CzE3B, was electropolymerized on the surface of an ITO coated glass. The optical and electrochemical properties of the poly-CzE3B film were investigated by UV/VIS/NIR spectroscopy and cyclic voltammetry. Electrochromic characteristics...
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| Veröffentlicht in: | Solar energy materials and solar cells 2013-10, Vol.117, p.183-188 |
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| creator | Kim, Sooyeun Kong, Xiangxing Taya, Minoru |
| description | The anodic monomer 1,3,5-tris(2-(9H-carbazol-9-yl)methyl)benzene, CzE3B, was electropolymerized on the surface of an ITO coated glass. The optical and electrochemical properties of the poly-CzE3B film were investigated by UV/VIS/NIR spectroscopy and cyclic voltammetry. Electrochromic characteristics of the polymer film were examined in continuously cyclic scans between colorlessness and dark green. The poly-CzE3B film functioned as an anodic coloring counter electrode in the electrochromic window and intensified coloration of the window throughout the visible region. The electrochromic window based on poly-3,3-dimethyl-3,4-dihydro-2H-thieno [3,4–b][1,4] dioxepine (PProDOT-Me2) and poly-CzE3B films exhibited a high electrochromic contrast. The large-sized electrochromic window was successfully fabricated. It exhibited optical and electrochemical cyclic stability. Also, the color-switching time of the window was investigated.
•PProDOT-Me2 and poly-CzE3B films based EC windows exhibited a high contrast.•Poly-CzE3B coated counter electrodes intensified coloration of EC windows.•Poly-CzE3B films in oxidized states showed strong absorption in the visible regions.•Poly-CzE3B films showed reversible EC characteristics from colorless to dark green. |
| doi_str_mv | 10.1016/j.solmat.2013.04.030 |
| format | Article |
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•PProDOT-Me2 and poly-CzE3B films based EC windows exhibited a high contrast.•Poly-CzE3B coated counter electrodes intensified coloration of EC windows.•Poly-CzE3B films in oxidized states showed strong absorption in the visible regions.•Poly-CzE3B films showed reversible EC characteristics from colorless to dark green.</description><identifier>ISSN: 0927-0248</identifier><identifier>EISSN: 1879-3398</identifier><identifier>DOI: 10.1016/j.solmat.2013.04.030</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Anodic ; Anodic coloring counter electrode ; Applied sciences ; Carbazole ; Electrical engineering. Electrical power engineering ; Electrochromic contrast ; Electrochromic window ; Electrochromism ; Electrodes ; Energy ; Exact sciences and technology ; Materials ; Miscellaneous ; Monomers ; Natural energy ; Optical properties ; PProDOT-Me2 ; Solar energy ; Windows (computer programs) ; Windows (intervals)</subject><ispartof>Solar energy materials and solar cells, 2013-10, Vol.117, p.183-188</ispartof><rights>2013 Elsevier B.V.</rights><rights>2014 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c468t-db9b8e5fa4e4c747d56fa256737d7e85b74dada6f6c36fe48e70c4a284cd757e3</citedby><cites>FETCH-LOGICAL-c468t-db9b8e5fa4e4c747d56fa256737d7e85b74dada6f6c36fe48e70c4a284cd757e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0927024813002079$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27728028$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Kim, Sooyeun</creatorcontrib><creatorcontrib>Kong, Xiangxing</creatorcontrib><creatorcontrib>Taya, Minoru</creatorcontrib><title>Electrochromic windows based on anodic electrochromic polymesitylenes containing 9H-carbazole-9-ethanol moieties</title><title>Solar energy materials and solar cells</title><description>The anodic monomer 1,3,5-tris(2-(9H-carbazol-9-yl)methyl)benzene, CzE3B, was electropolymerized on the surface of an ITO coated glass. The optical and electrochemical properties of the poly-CzE3B film were investigated by UV/VIS/NIR spectroscopy and cyclic voltammetry. Electrochromic characteristics of the polymer film were examined in continuously cyclic scans between colorlessness and dark green. The poly-CzE3B film functioned as an anodic coloring counter electrode in the electrochromic window and intensified coloration of the window throughout the visible region. The electrochromic window based on poly-3,3-dimethyl-3,4-dihydro-2H-thieno [3,4–b][1,4] dioxepine (PProDOT-Me2) and poly-CzE3B films exhibited a high electrochromic contrast. The large-sized electrochromic window was successfully fabricated. It exhibited optical and electrochemical cyclic stability. Also, the color-switching time of the window was investigated.
•PProDOT-Me2 and poly-CzE3B films based EC windows exhibited a high contrast.•Poly-CzE3B coated counter electrodes intensified coloration of EC windows.•Poly-CzE3B films in oxidized states showed strong absorption in the visible regions.•Poly-CzE3B films showed reversible EC characteristics from colorless to dark green.</description><subject>Anodic</subject><subject>Anodic coloring counter electrode</subject><subject>Applied sciences</subject><subject>Carbazole</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Electrochromic contrast</subject><subject>Electrochromic window</subject><subject>Electrochromism</subject><subject>Electrodes</subject><subject>Energy</subject><subject>Exact sciences and technology</subject><subject>Materials</subject><subject>Miscellaneous</subject><subject>Monomers</subject><subject>Natural energy</subject><subject>Optical properties</subject><subject>PProDOT-Me2</subject><subject>Solar energy</subject><subject>Windows (computer programs)</subject><subject>Windows (intervals)</subject><issn>0927-0248</issn><issn>1879-3398</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNqNkU2LFDEQhoMoOI7-Aw99Ebx0W_lOXwRZVldY8KLnkE6q3QzpZEx6XcZfby-zCF50TwXF81ZR9RDymsJAgap3h6GVtLh1YED5AGIADk_Ijho99pyP5inZwch0D0yY5-RFawcAYIqLHTleJvRrLf6mliX67i7mUO5aN7mGoSu5c7mErY9_Y8eSTgu2uJ4SZmydL3l1Mcf8vRuveu_q5H6VhP3Y43qzjUjdUiKuEdtL8mx2qeGrh7on3z5efr246q-_fPp88eG690KZtQ_TOBmUsxMovBY6SDU7JpXmOmg0ctIiuODUrDxXMwqDGrxwzAgftNTI9-Ttee6xlh-32Fa7xOYxJZex3DZLlWDMcCrV41AuhXkEKsFoxSjA_1GhhAQ6Krah4oz6WlqrONtjjYurJ0vB3hu2B3s2bO8NWxB2M7zF3jxscM27NFeXfWx_skxrZmC7cU_enznc_v0zYrXNR8weQ6ybVRtK_Pei328ev50</recordid><startdate>20131001</startdate><enddate>20131001</enddate><creator>Kim, Sooyeun</creator><creator>Kong, Xiangxing</creator><creator>Taya, Minoru</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TG</scope><scope>KL.</scope><scope>7SP</scope><scope>7TB</scope><scope>7U5</scope><scope>8FD</scope><scope>FR3</scope><scope>L7M</scope></search><sort><creationdate>20131001</creationdate><title>Electrochromic windows based on anodic electrochromic polymesitylenes containing 9H-carbazole-9-ethanol moieties</title><author>Kim, Sooyeun ; Kong, Xiangxing ; Taya, Minoru</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c468t-db9b8e5fa4e4c747d56fa256737d7e85b74dada6f6c36fe48e70c4a284cd757e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Anodic</topic><topic>Anodic coloring counter electrode</topic><topic>Applied sciences</topic><topic>Carbazole</topic><topic>Electrical engineering. Electrical power engineering</topic><topic>Electrochromic contrast</topic><topic>Electrochromic window</topic><topic>Electrochromism</topic><topic>Electrodes</topic><topic>Energy</topic><topic>Exact sciences and technology</topic><topic>Materials</topic><topic>Miscellaneous</topic><topic>Monomers</topic><topic>Natural energy</topic><topic>Optical properties</topic><topic>PProDOT-Me2</topic><topic>Solar energy</topic><topic>Windows (computer programs)</topic><topic>Windows (intervals)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kim, Sooyeun</creatorcontrib><creatorcontrib>Kong, Xiangxing</creatorcontrib><creatorcontrib>Taya, Minoru</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Meteorological & Geoastrophysical Abstracts</collection><collection>Meteorological & Geoastrophysical Abstracts - Academic</collection><collection>Electronics & Communications Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Solar energy materials and solar cells</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kim, Sooyeun</au><au>Kong, Xiangxing</au><au>Taya, Minoru</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrochromic windows based on anodic electrochromic polymesitylenes containing 9H-carbazole-9-ethanol moieties</atitle><jtitle>Solar energy materials and solar cells</jtitle><date>2013-10-01</date><risdate>2013</risdate><volume>117</volume><spage>183</spage><epage>188</epage><pages>183-188</pages><issn>0927-0248</issn><eissn>1879-3398</eissn><abstract>The anodic monomer 1,3,5-tris(2-(9H-carbazol-9-yl)methyl)benzene, CzE3B, was electropolymerized on the surface of an ITO coated glass. The optical and electrochemical properties of the poly-CzE3B film were investigated by UV/VIS/NIR spectroscopy and cyclic voltammetry. Electrochromic characteristics of the polymer film were examined in continuously cyclic scans between colorlessness and dark green. The poly-CzE3B film functioned as an anodic coloring counter electrode in the electrochromic window and intensified coloration of the window throughout the visible region. The electrochromic window based on poly-3,3-dimethyl-3,4-dihydro-2H-thieno [3,4–b][1,4] dioxepine (PProDOT-Me2) and poly-CzE3B films exhibited a high electrochromic contrast. The large-sized electrochromic window was successfully fabricated. It exhibited optical and electrochemical cyclic stability. Also, the color-switching time of the window was investigated.
•PProDOT-Me2 and poly-CzE3B films based EC windows exhibited a high contrast.•Poly-CzE3B coated counter electrodes intensified coloration of EC windows.•Poly-CzE3B films in oxidized states showed strong absorption in the visible regions.•Poly-CzE3B films showed reversible EC characteristics from colorless to dark green.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.solmat.2013.04.030</doi><tpages>6</tpages></addata></record> |
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| subjects | Anodic Anodic coloring counter electrode Applied sciences Carbazole Electrical engineering. Electrical power engineering Electrochromic contrast Electrochromic window Electrochromism Electrodes Energy Exact sciences and technology Materials Miscellaneous Monomers Natural energy Optical properties PProDOT-Me2 Solar energy Windows (computer programs) Windows (intervals) |
| title | Electrochromic windows based on anodic electrochromic polymesitylenes containing 9H-carbazole-9-ethanol moieties |
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