Applications of ionic liquids in organic synthesis and catalysis
In recent years, various novel and greener methodologies have been developed using ionic liquids (ILs). In these reactions, IL has played multiple roles like catalyst, solvent, and catalyst support. In some cases, it was observed that IL enables efficient catalytic reactions in comparison with conve...
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| Veröffentlicht in: | Clean technologies and environmental policy 2014-12, Vol.16 (8), p.1487-1513 |
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| creator | Qureshi, Ziyauddin S. Deshmukh, Krishna M. Bhanage, Bhalchandra M. |
| description | In recent years, various novel and greener methodologies have been developed using ionic liquids (ILs). In these reactions, IL has played multiple roles like catalyst, solvent, and catalyst support. In some cases, it was observed that IL enables efficient catalytic reactions in comparison with conventional molecular solvents. On the other hand, although a number of catalytic reaction processes in which ILs are used have been established in industry, there were also some unexpected problems, such as unintelligible aberrance or degradation of so-called task-specific ILs occurring in reaction processes and on the pilot plant scale. Also, several urgent questions regarding the fundamental aspects of ILs particularly toxicity and greener preparation methods need to be clarified. Several industrial applications of ILs are also discussed. |
| doi_str_mv | 10.1007/s10098-013-0660-0 |
| format | Article |
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In these reactions, IL has played multiple roles like catalyst, solvent, and catalyst support. In some cases, it was observed that IL enables efficient catalytic reactions in comparison with conventional molecular solvents. On the other hand, although a number of catalytic reaction processes in which ILs are used have been established in industry, there were also some unexpected problems, such as unintelligible aberrance or degradation of so-called task-specific ILs occurring in reaction processes and on the pilot plant scale. Also, several urgent questions regarding the fundamental aspects of ILs particularly toxicity and greener preparation methods need to be clarified. 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| subjects | Catalysis Catalysts Cellulose Chemical synthesis Chemistry Chloride Cleaning Earth and Environmental Science Environment Environmental Economics Environmental Engineering/Biotechnology Environmental policy Hydrocarbons Industrial and Production Engineering Industrial Chemistry/Chemical Engineering Ionic liquids Ions Liquids Organic chemicals Pilot plants Review Solvents Sustainable Development Synthesis Toxicity |
| title | Applications of ionic liquids in organic synthesis and catalysis |
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