Optimization arsenic immobilization in a sandy loam soil using iron-based amendments by response surface methodology

The survey of reports regarding high concentrations of arsenic in soils and groundwater around the world, which refers to increase of arsenic exposure to the living organisms, has been increased. In this research work arsenic immobilization process using three iron amendments (soluble Fe(II), zero-v...

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Veröffentlicht in:Geoderma 2014-11, Vol.232-234, p.547-555
Hauptverfasser: Naseri, Elham, Reyhanitabar, Adel, Oustan, Shahin, Heydari, Ali Akbar, Alidokht, Leila
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Reyhanitabar, Adel
Oustan, Shahin
Heydari, Ali Akbar
Alidokht, Leila
description The survey of reports regarding high concentrations of arsenic in soils and groundwater around the world, which refers to increase of arsenic exposure to the living organisms, has been increased. In this research work arsenic immobilization process using three iron amendments (soluble Fe(II), zero-valent iron (ZVI), and Fe (II)-modified zeolite (Fe-Z)) was modeled and optimized in a spiked soil by response surface methodology (RSM). Three factors including initial concentration of As(III) (20 to 580mgkg−1 of soil), amount of added Fe (0.5 to 2.5wt.% of soil for both Fe(II) and ZVI, 0.05 to 0.2wt.% of soil for loaded Fe on zeolite) and shaking time (15 to 960min) were selected as the independent factors on arsenic immobilization efficiency. The five-level central composite design (CCD) was used for experiment design and optimization model parameters. Variance analysis showed that CCD models were statistically significant for all amendments (p
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In this research work arsenic immobilization process using three iron amendments (soluble Fe(II), zero-valent iron (ZVI), and Fe (II)-modified zeolite (Fe-Z)) was modeled and optimized in a spiked soil by response surface methodology (RSM). Three factors including initial concentration of As(III) (20 to 580mgkg−1 of soil), amount of added Fe (0.5 to 2.5wt.% of soil for both Fe(II) and ZVI, 0.05 to 0.2wt.% of soil for loaded Fe on zeolite) and shaking time (15 to 960min) were selected as the independent factors on arsenic immobilization efficiency. The five-level central composite design (CCD) was used for experiment design and optimization model parameters. Variance analysis showed that CCD models were statistically significant for all amendments (p&lt;0.01) with high accuracy (R2=0.98 for Fe(II), R2=0.89 for ZVI and R2=0.92 for Fe-Z) in predicting As(III) immobilization. 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subjects Agronomy. Soil science and plant productions
Arsenic
Biological and medical sciences
CCD
Charge coupled devices
Earth sciences
Earth, ocean, space
Exact sciences and technology
Fundamental and applied biological sciences. Psychology
Immobilization
Iron
Mathematical models
Optimization
Response surface methodology
Soil (material)
Soil remediation
Soils
Surficial geology
Zeolite
title Optimization arsenic immobilization in a sandy loam soil using iron-based amendments by response surface methodology
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