High fill factor polymer solar cells comprising a transparent, low temperature solution processed doped metal oxide/metal nanowire composite electrode
In this paper we report on the replacement for the commonly used ITO electrode material by a low temperature solution processed silver nanowire/(doped) metal oxide composite. Devices employing silver nanowires (AgNWs)/buffer layer electrodes with a photoactive layer of poly(3-hexylthiophene) (P3HT)...
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| Veröffentlicht in: | Solar energy materials and solar cells 2012-12, Vol.107, p.248-251 |
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| container_title | Solar energy materials and solar cells |
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| creator | Stubhan, Tobias Krantz, Johannes Li, Ning Guo, Fei Litzov, Ivan Steidl, Matthias Richter, Moses Matt, Gebhard J. Brabec, Christoph J. |
| description | In this paper we report on the replacement for the commonly used ITO electrode material by a low temperature solution processed silver nanowire/(doped) metal oxide composite. Devices employing silver nanowires (AgNWs)/buffer layer electrodes with a photoactive layer of poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl-C61 butyric acid methyl ester (PCBM) are showing a comparable performance to the ITO reference cell with fill factors (FF) of over 62% and a power conversion efficiency of ∼2.7%. Zinc oxide (ZnO) and highly conductive Al doped ZnO (AZO) are used as buffer layer. AgNW devices without a buffer layer have a high open circuit voltage (VOC) but the FF and the short circuit current density (jSC) are substantially lower. Overall it is demonstrated that AgNWs and the low temperature solution process of the buffer layer are an attractive device concept towards an indium free organic solar cell. |
| doi_str_mv | 10.1016/j.solmat.2012.06.039 |
| format | Article |
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Devices employing silver nanowires (AgNWs)/buffer layer electrodes with a photoactive layer of poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl-C61 butyric acid methyl ester (PCBM) are showing a comparable performance to the ITO reference cell with fill factors (FF) of over 62% and a power conversion efficiency of ∼2.7%. Zinc oxide (ZnO) and highly conductive Al doped ZnO (AZO) are used as buffer layer. AgNW devices without a buffer layer have a high open circuit voltage (VOC) but the FF and the short circuit current density (jSC) are substantially lower. Overall it is demonstrated that AgNWs and the low temperature solution process of the buffer layer are an attractive device concept towards an indium free organic solar cell.</description><identifier>ISSN: 0927-0248</identifier><identifier>EISSN: 1879-3398</identifier><identifier>DOI: 10.1016/j.solmat.2012.06.039</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Aluminum-doped zinc oxide ; Applied sciences ; Buffer layers ; Devices ; Electrical engineering. Electrical power engineering ; Energy ; Exact sciences and technology ; Materials ; Metal nanowires ; Nanocomposites ; Nanomaterials ; Nanostructure ; Nanowires ; Natural energy ; Organic solar cells ; Photovoltaic cells ; Photovoltaic conversion ; Solar cells ; Solar cells. 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Devices employing silver nanowires (AgNWs)/buffer layer electrodes with a photoactive layer of poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl-C61 butyric acid methyl ester (PCBM) are showing a comparable performance to the ITO reference cell with fill factors (FF) of over 62% and a power conversion efficiency of ∼2.7%. Zinc oxide (ZnO) and highly conductive Al doped ZnO (AZO) are used as buffer layer. AgNW devices without a buffer layer have a high open circuit voltage (VOC) but the FF and the short circuit current density (jSC) are substantially lower. Overall it is demonstrated that AgNWs and the low temperature solution process of the buffer layer are an attractive device concept towards an indium free organic solar cell.</description><subject>Aluminum-doped zinc oxide</subject><subject>Applied sciences</subject><subject>Buffer layers</subject><subject>Devices</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>Energy</subject><subject>Exact sciences and technology</subject><subject>Materials</subject><subject>Metal nanowires</subject><subject>Nanocomposites</subject><subject>Nanomaterials</subject><subject>Nanostructure</subject><subject>Nanowires</subject><subject>Natural energy</subject><subject>Organic solar cells</subject><subject>Photovoltaic cells</subject><subject>Photovoltaic conversion</subject><subject>Solar cells</subject><subject>Solar cells. 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| subjects | Aluminum-doped zinc oxide Applied sciences Buffer layers Devices Electrical engineering. Electrical power engineering Energy Exact sciences and technology Materials Metal nanowires Nanocomposites Nanomaterials Nanostructure Nanowires Natural energy Organic solar cells Photovoltaic cells Photovoltaic conversion Solar cells Solar cells. Photoelectrochemical cells Solar energy Solution processed Transparent electrode Zinc oxide |
| title | High fill factor polymer solar cells comprising a transparent, low temperature solution processed doped metal oxide/metal nanowire composite electrode |
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