Synthesis of Allylarenes via Catalytic Decarboxylation of Allyl Benzoates

A catalyst system consisting of the palladium(0) complex Pd2(dba)3 and tri(p‐tolyl)phosphine was found to efficiently promote the decarboxylation of allyl benzoates with formation of allylarenes. This catalytic CO activation followed by extrusion of carbon dioxide and CC bond formation represents...

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Veröffentlicht in:	Advanced synthesis & catalysis 2014-11, Vol.356 (16), p.3302-3306
Hauptverfasser:	Pfister, Kai F., Grünberg, Matthias F., Gooßen, Lukas J.
Format:	Artikel
Sprache:	eng
Schlagworte:	allylation Benzoates Carbon dioxide Catalysis Catalysts Decarboxylation Esters homogeneous catalysis nickel palladium Synthesis Transformations
Online-Zugang:	Volltext
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