Regenerated cellulose nanocomposites reinforced with exfoliated graphite nanosheets using BMIMCL ionic liquid
Green nanocomposites of regenerated cellulose/exfoliated graphite nanosheets films with low nanofiller loadings were prepared using environmentally benign 1-butyl-3-methylimidazolium chloride (BMIMCl) ionic liquid. X-ray diffraction revealed well developed intercalated nanocomposites. The tensile st...
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| Veröffentlicht in: | Polymer (Guilford) 2014-06, Vol.55 (14), p.3130-3138 |
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| creator | Soheilmoghaddam, Mohammad Pasbakhsh, Pooria Wahit, Mat Uzir Bidsorkhi, Hossein Cheraghi Pour, Raheleh Heidar Whye, Wong Tuck De Silva, R.T. |
| description | Green nanocomposites of regenerated cellulose/exfoliated graphite nanosheets films with low nanofiller loadings were prepared using environmentally benign 1-butyl-3-methylimidazolium chloride (BMIMCl) ionic liquid. X-ray diffraction revealed well developed intercalated nanocomposites. The tensile strength and Young's modulus of the prepared nanocomposites were increased by 97.5% and 172% respectively when 0.75 wt.% and 1 wt.% exfoliated graphite nanosheets were added. The results were validated using the Halpin–Tsai model. The exfoliated graphite nanosheets were unidirectionally aligned in the regenerated cellulose parallel to the surface of the nanocomposites as revealed by transmission electron microscopy (TEM) and field emission scanning electron microscopy (FESEM). Also, the TEM and FESEM revealed uniform dispersion of the exfoliated graphite nanosheets and good interaction between the nanofillers and the matrix. The addition of the exfoliated graphite nanosheets enhanced the thermal stability and reduced the water absorption and diffusivity of the nanocomposites.
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| doi_str_mv | 10.1016/j.polymer.2014.05.021 |
| format | Article |
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X-ray diffraction revealed well developed intercalated nanocomposites. The tensile strength and Young's modulus of the prepared nanocomposites were increased by 97.5% and 172% respectively when 0.75 wt.% and 1 wt.% exfoliated graphite nanosheets were added. The results were validated using the Halpin–Tsai model. The exfoliated graphite nanosheets were unidirectionally aligned in the regenerated cellulose parallel to the surface of the nanocomposites as revealed by transmission electron microscopy (TEM) and field emission scanning electron microscopy (FESEM). Also, the TEM and FESEM revealed uniform dispersion of the exfoliated graphite nanosheets and good interaction between the nanofillers and the matrix. The addition of the exfoliated graphite nanosheets enhanced the thermal stability and reduced the water absorption and diffusivity of the nanocomposites.
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| subjects | Applied sciences Cellulose Composites Exact sciences and technology Exfoliated graphite nanosheets Exfoliation Forms of application and semi-finished materials Graphite Ionic liquid Ionic liquids Nanocomposites Nanostructure Polymer industry, paints, wood Regenerated cellulose Scanning electron microscopy Technology of polymers Transmission electron microscopy |
| title | Regenerated cellulose nanocomposites reinforced with exfoliated graphite nanosheets using BMIMCL ionic liquid |
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