Supramolecular Chemistry in the Formation of Self-Assembled Nanostructures from a High-Molecular-Weight Rod-Coil Block Copolymer
The self‐assembled nanostructures of a high‐molecular‐weight rod–coil block copolymer, poly(styrene‐block‐(2,5‐bis[4‐methoxyphenyl]oxycarbonyl)styrene) (PS‐b‐PMPCS), in p‐xylene are studied. The cylindrical micelles, long segmental cylindrical micelle associates, spherical micelles, and spherical mi...
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| Veröffentlicht in: | Macromolecular rapid communications. 2014-10, Vol.35 (20), p.1795-1800 |
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| creator | Tu, Yingfeng Ji, Zhichao Yang, Xiaoming Wan, Xinhua Zhou, Qi-Feng |
| description | The self‐assembled nanostructures of a high‐molecular‐weight rod–coil block copolymer, poly(styrene‐block‐(2,5‐bis[4‐methoxyphenyl]oxycarbonyl)styrene) (PS‐b‐PMPCS), in p‐xylene are studied. The cylindrical micelles, long segmental cylindrical micelle associates, spherical micelles, and spherical micelle associates are observed with increased copolymer concentration. The high molecular weight of PS leads to the entanglement between PS chains from different micelles, which is the force for supramolecular interactions. Short cylindrical micelles are connected end‐to‐end via this supramolecular chemistry to form long segmental cylindrical micelle associates, analogue to the condensation polymerization process, with direction and saturation. On the other hand, spherical micelles assemble via supramolecular chemistry to form spherical micelle associates, yet without any direction due to their isotropic properties.
The self‐assembly of a high‐molecular‐weight rod–coil copolymer, PS620‐b‐PMPCS1000, in p‐xylene is studied. The self‐assembled cylindrical micelles or spherical micelles can undergo supramolecular chemistry to form segmental cylindrical micelle associates or spherical micelles associates. The driving force for this supramolecular chemistry is the chain entanglement between the long polystyrene (PS) coils. |
| doi_str_mv | 10.1002/marc.201400381 |
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The self‐assembly of a high‐molecular‐weight rod–coil copolymer, PS620‐b‐PMPCS1000, in p‐xylene is studied. The self‐assembled cylindrical micelles or spherical micelles can undergo supramolecular chemistry to form segmental cylindrical micelle associates or spherical micelles associates. The driving force for this supramolecular chemistry is the chain entanglement between the long polystyrene (PS) coils.</description><identifier>ISSN: 1022-1336</identifier><identifier>EISSN: 1521-3927</identifier><identifier>DOI: 10.1002/marc.201400381</identifier><identifier>PMID: 25204263</identifier><language>eng</language><publisher>Weinheim: Blackwell Publishing Ltd</publisher><subject>Applied sciences ; Block copolymers ; Chain entanglement ; Copolymers ; Exact sciences and technology ; Micelles ; Molecular weight ; Nanoparticles ; Nanostructure ; Organic polymers ; Physicochemistry of polymers ; Polystyrene resins ; Properties and characterization ; Self assembly ; Solution and gel properties ; supramolecular chemistry</subject><ispartof>Macromolecular rapid communications., 2014-10, Vol.35 (20), p.1795-1800</ispartof><rights>2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2015 INIST-CNRS</rights><rights>2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4741-89f6ca17f834e8eeb34362e79639da0b813de470d23cb2310a5082dec06a23e03</citedby><cites>FETCH-LOGICAL-c4741-89f6ca17f834e8eeb34362e79639da0b813de470d23cb2310a5082dec06a23e03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fmarc.201400381$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fmarc.201400381$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28880512$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/25204263$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Tu, Yingfeng</creatorcontrib><creatorcontrib>Ji, Zhichao</creatorcontrib><creatorcontrib>Yang, Xiaoming</creatorcontrib><creatorcontrib>Wan, Xinhua</creatorcontrib><creatorcontrib>Zhou, Qi-Feng</creatorcontrib><title>Supramolecular Chemistry in the Formation of Self-Assembled Nanostructures from a High-Molecular-Weight Rod-Coil Block Copolymer</title><title>Macromolecular rapid communications.</title><addtitle>Macromol. Rapid Commun</addtitle><description>The self‐assembled nanostructures of a high‐molecular‐weight rod–coil block copolymer, poly(styrene‐block‐(2,5‐bis[4‐methoxyphenyl]oxycarbonyl)styrene) (PS‐b‐PMPCS), in p‐xylene are studied. The cylindrical micelles, long segmental cylindrical micelle associates, spherical micelles, and spherical micelle associates are observed with increased copolymer concentration. The high molecular weight of PS leads to the entanglement between PS chains from different micelles, which is the force for supramolecular interactions. Short cylindrical micelles are connected end‐to‐end via this supramolecular chemistry to form long segmental cylindrical micelle associates, analogue to the condensation polymerization process, with direction and saturation. On the other hand, spherical micelles assemble via supramolecular chemistry to form spherical micelle associates, yet without any direction due to their isotropic properties.
The self‐assembly of a high‐molecular‐weight rod–coil copolymer, PS620‐b‐PMPCS1000, in p‐xylene is studied. The self‐assembled cylindrical micelles or spherical micelles can undergo supramolecular chemistry to form segmental cylindrical micelle associates or spherical micelles associates. The driving force for this supramolecular chemistry is the chain entanglement between the long polystyrene (PS) coils.</description><subject>Applied sciences</subject><subject>Block copolymers</subject><subject>Chain entanglement</subject><subject>Copolymers</subject><subject>Exact sciences and technology</subject><subject>Micelles</subject><subject>Molecular weight</subject><subject>Nanoparticles</subject><subject>Nanostructure</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polystyrene resins</subject><subject>Properties and characterization</subject><subject>Self assembly</subject><subject>Solution and gel properties</subject><subject>supramolecular chemistry</subject><issn>1022-1336</issn><issn>1521-3927</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqF0c9v0zAUB_AIgdgPuHJElhASl5RnO3WcYxexFdEOtIJ6tBznhWZz4mInGr3xp-OpXUFcONmWPu_5PX2T5BWFCQVg7zvtzYQBzQC4pE-SUzplNOUFy5_GOzCWUs7FSXIWwi0AyAzY8-SETRlkTPDT5Ndq3HrdOYtmtNqTcoNdGwa_I21Phg2SS-c7PbSuJ64hK7RNOgsBu8piTa5176IdzTB6DKTxriOazNvvm3T52DFdY3wP5MbVaelaSy6sM3ekdFtndx36F8mzRtuALw_nefLt8sPXcp4uPl99LGeL1GR5RlNZNMJomjeSZygRK55xwTAvBC9qDZWkvMYsh5pxUzFOQU9BshoNCM04Aj9P3u37br37MWIYVNzToLW6RzcGRQUruBCCyUjf_ENv3ej7OF1UNAJR5FlUk70y3oXgsVFb38Y4doqCeshGPWSjjtnEgteHtmPVYX3kj2FE8PYAdDDaNl73pg1_nJQSppRFV-zdfWtx959v1XJ2U_49RLqvjSHjz2Ot9ndK5DyfqvX1lfoE82K9_LJSC_4bQPO3Sg</recordid><startdate>201410</startdate><enddate>201410</enddate><creator>Tu, Yingfeng</creator><creator>Ji, Zhichao</creator><creator>Yang, Xiaoming</creator><creator>Wan, Xinhua</creator><creator>Zhou, Qi-Feng</creator><general>Blackwell Publishing Ltd</general><general>Wiley</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>JQ2</scope><scope>L7M</scope></search><sort><creationdate>201410</creationdate><title>Supramolecular Chemistry in the Formation of Self-Assembled Nanostructures from a High-Molecular-Weight Rod-Coil Block Copolymer</title><author>Tu, Yingfeng ; Ji, Zhichao ; Yang, Xiaoming ; Wan, Xinhua ; Zhou, Qi-Feng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4741-89f6ca17f834e8eeb34362e79639da0b813de470d23cb2310a5082dec06a23e03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Applied sciences</topic><topic>Block copolymers</topic><topic>Chain entanglement</topic><topic>Copolymers</topic><topic>Exact sciences and technology</topic><topic>Micelles</topic><topic>Molecular weight</topic><topic>Nanoparticles</topic><topic>Nanostructure</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polystyrene resins</topic><topic>Properties and characterization</topic><topic>Self assembly</topic><topic>Solution and gel properties</topic><topic>supramolecular chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tu, Yingfeng</creatorcontrib><creatorcontrib>Ji, Zhichao</creatorcontrib><creatorcontrib>Yang, Xiaoming</creatorcontrib><creatorcontrib>Wan, Xinhua</creatorcontrib><creatorcontrib>Zhou, Qi-Feng</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Macromolecular rapid communications.</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tu, Yingfeng</au><au>Ji, Zhichao</au><au>Yang, Xiaoming</au><au>Wan, Xinhua</au><au>Zhou, Qi-Feng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Supramolecular Chemistry in the Formation of Self-Assembled Nanostructures from a High-Molecular-Weight Rod-Coil Block Copolymer</atitle><jtitle>Macromolecular rapid communications.</jtitle><addtitle>Macromol. Rapid Commun</addtitle><date>2014-10</date><risdate>2014</risdate><volume>35</volume><issue>20</issue><spage>1795</spage><epage>1800</epage><pages>1795-1800</pages><issn>1022-1336</issn><eissn>1521-3927</eissn><abstract>The self‐assembled nanostructures of a high‐molecular‐weight rod–coil block copolymer, poly(styrene‐block‐(2,5‐bis[4‐methoxyphenyl]oxycarbonyl)styrene) (PS‐b‐PMPCS), in p‐xylene are studied. The cylindrical micelles, long segmental cylindrical micelle associates, spherical micelles, and spherical micelle associates are observed with increased copolymer concentration. The high molecular weight of PS leads to the entanglement between PS chains from different micelles, which is the force for supramolecular interactions. Short cylindrical micelles are connected end‐to‐end via this supramolecular chemistry to form long segmental cylindrical micelle associates, analogue to the condensation polymerization process, with direction and saturation. On the other hand, spherical micelles assemble via supramolecular chemistry to form spherical micelle associates, yet without any direction due to their isotropic properties.
The self‐assembly of a high‐molecular‐weight rod–coil copolymer, PS620‐b‐PMPCS1000, in p‐xylene is studied. The self‐assembled cylindrical micelles or spherical micelles can undergo supramolecular chemistry to form segmental cylindrical micelle associates or spherical micelles associates. The driving force for this supramolecular chemistry is the chain entanglement between the long polystyrene (PS) coils.</abstract><cop>Weinheim</cop><pub>Blackwell Publishing Ltd</pub><pmid>25204263</pmid><doi>10.1002/marc.201400381</doi><tpages>6</tpages></addata></record> |
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| subjects | Applied sciences Block copolymers Chain entanglement Copolymers Exact sciences and technology Micelles Molecular weight Nanoparticles Nanostructure Organic polymers Physicochemistry of polymers Polystyrene resins Properties and characterization Self assembly Solution and gel properties supramolecular chemistry |
| title | Supramolecular Chemistry in the Formation of Self-Assembled Nanostructures from a High-Molecular-Weight Rod-Coil Block Copolymer |
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