Synthesis of PPV-b-PEG block copolymers via CuAAC conjugation
[Display omitted] •PPV polymers with well-defined endgroups and chain length have been synthesized.•Clickable endgroups are embedded in the anionic polymerization initiator.•PPV-PEG block copolymers were synthesized via CuAAC reactions.•The obtained block copolymers show self-assembly behavior. The...
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| Veröffentlicht in: | European polymer journal 2014-06, Vol.55, p.114-122 |
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| container_title | European polymer journal |
| container_volume | 55 |
| creator | Cosemans, Inge Vandenbergh, Joke D’Olieslaeger, Lien Ethirajan, Anitha Lutsen, Laurence Vanderzande, Dirk Junkers, Tanja |
| description | [Display omitted]
•PPV polymers with well-defined endgroups and chain length have been synthesized.•Clickable endgroups are embedded in the anionic polymerization initiator.•PPV-PEG block copolymers were synthesized via CuAAC reactions.•The obtained block copolymers show self-assembly behavior.
The synthesis of amphiphilic rod-coil block copolymers with a poly(p-phenylene vinylene) (PPV) rod-like block using a Click chemistry approach is investigated and a facile reaction pathway towards poly(p-phenylene vinylene)-block-poly(ethylene glycol) (PPV-b-PEG) block copolymers is presented. To reach this aim, an alkyne-functionalized PPV block (synthesized from anionic sulfinyl precursor route polymerization) was synthesized and subsequently coupled to azide-functionalized poly(ethylene glycol) of different lengths. Self-assembly of these materials in aqueous solution demonstrate successful micelle formation with core–shell morphology and different sizes for these PPV-b-PEG block copolymers as is confirmed by TEM and DLS measurements respectively. |
| doi_str_mv | 10.1016/j.eurpolymj.2014.03.016 |
| format | Article |
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•PPV polymers with well-defined endgroups and chain length have been synthesized.•Clickable endgroups are embedded in the anionic polymerization initiator.•PPV-PEG block copolymers were synthesized via CuAAC reactions.•The obtained block copolymers show self-assembly behavior.
The synthesis of amphiphilic rod-coil block copolymers with a poly(p-phenylene vinylene) (PPV) rod-like block using a Click chemistry approach is investigated and a facile reaction pathway towards poly(p-phenylene vinylene)-block-poly(ethylene glycol) (PPV-b-PEG) block copolymers is presented. To reach this aim, an alkyne-functionalized PPV block (synthesized from anionic sulfinyl precursor route polymerization) was synthesized and subsequently coupled to azide-functionalized poly(ethylene glycol) of different lengths. Self-assembly of these materials in aqueous solution demonstrate successful micelle formation with core–shell morphology and different sizes for these PPV-b-PEG block copolymers as is confirmed by TEM and DLS measurements respectively.</description><identifier>ISSN: 0014-3057</identifier><identifier>EISSN: 1873-1945</identifier><identifier>DOI: 10.1016/j.eurpolymj.2014.03.016</identifier><identifier>CODEN: EUPJAG</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Anionic polymerization ; Applied sciences ; Block copolymers ; Blocking ; Conjugation ; CuAAC conjugation ; Exact sciences and technology ; Glycols ; Organic polymers ; Physicochemistry of polymers ; Poly(p-phenylene vinylene) (PPV) ; Polymers with particular properties ; Polyphenylene vinylene ; Precursors ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; Self assembly ; Synthesis</subject><ispartof>European polymer journal, 2014-06, Vol.55, p.114-122</ispartof><rights>2014 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c378t-73a0b7d6bc3683424096ccabafa944b74eb494a032ad4fb744104c56d7421f03</citedby><cites>FETCH-LOGICAL-c378t-73a0b7d6bc3683424096ccabafa944b74eb494a032ad4fb744104c56d7421f03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.eurpolymj.2014.03.016$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>315,781,785,3551,27929,27930,46000</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28472518$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Cosemans, Inge</creatorcontrib><creatorcontrib>Vandenbergh, Joke</creatorcontrib><creatorcontrib>D’Olieslaeger, Lien</creatorcontrib><creatorcontrib>Ethirajan, Anitha</creatorcontrib><creatorcontrib>Lutsen, Laurence</creatorcontrib><creatorcontrib>Vanderzande, Dirk</creatorcontrib><creatorcontrib>Junkers, Tanja</creatorcontrib><title>Synthesis of PPV-b-PEG block copolymers via CuAAC conjugation</title><title>European polymer journal</title><description>[Display omitted]
•PPV polymers with well-defined endgroups and chain length have been synthesized.•Clickable endgroups are embedded in the anionic polymerization initiator.•PPV-PEG block copolymers were synthesized via CuAAC reactions.•The obtained block copolymers show self-assembly behavior.
The synthesis of amphiphilic rod-coil block copolymers with a poly(p-phenylene vinylene) (PPV) rod-like block using a Click chemistry approach is investigated and a facile reaction pathway towards poly(p-phenylene vinylene)-block-poly(ethylene glycol) (PPV-b-PEG) block copolymers is presented. To reach this aim, an alkyne-functionalized PPV block (synthesized from anionic sulfinyl precursor route polymerization) was synthesized and subsequently coupled to azide-functionalized poly(ethylene glycol) of different lengths. Self-assembly of these materials in aqueous solution demonstrate successful micelle formation with core–shell morphology and different sizes for these PPV-b-PEG block copolymers as is confirmed by TEM and DLS measurements respectively.</description><subject>Anionic polymerization</subject><subject>Applied sciences</subject><subject>Block copolymers</subject><subject>Blocking</subject><subject>Conjugation</subject><subject>CuAAC conjugation</subject><subject>Exact sciences and technology</subject><subject>Glycols</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Poly(p-phenylene vinylene) (PPV)</subject><subject>Polymers with particular properties</subject><subject>Polyphenylene vinylene</subject><subject>Precursors</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Self assembly</subject><subject>Synthesis</subject><issn>0014-3057</issn><issn>1873-1945</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqFUE1Lw0AQXUTBWv0N5iJ4SZz9SDY5eAilVqFgweJ12Ww2ujHN1t2k0H_v1havnoZ58z6Yh9AthgQDzh7aRI9ua7v9pk0IYJYATQJ-hiY45zTGBUvP0QTCJaaQ8kt05X0LAJxmdIIe3_b98Km98ZFtotXqPa7i1XwRVZ1VX5Gyv8ba-WhnZDQby3IWwL4dP-RgbH-NLhrZeX1zmlO0fpqvZ8_x8nXxMiuXsaI8H2JOJVS8zipFs5wywqDIlJKVbGTBWMWZrljBJFAia9aEnWFgKs1qzghugE7R_dF26-z3qP0gNsYr3XWy13b0AmekoBkjnAQqP1KVs9473YitMxvp9gKDOPQlWvHXlzj0JYCKgAfl3SlEeiW7xsleGf8nJznjJMV54JVHng4P74x2wiuje6Vr47QaRG3Nv1k_7BaD2w</recordid><startdate>20140601</startdate><enddate>20140601</enddate><creator>Cosemans, Inge</creator><creator>Vandenbergh, Joke</creator><creator>D’Olieslaeger, Lien</creator><creator>Ethirajan, Anitha</creator><creator>Lutsen, Laurence</creator><creator>Vanderzande, Dirk</creator><creator>Junkers, Tanja</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20140601</creationdate><title>Synthesis of PPV-b-PEG block copolymers via CuAAC conjugation</title><author>Cosemans, Inge ; Vandenbergh, Joke ; D’Olieslaeger, Lien ; Ethirajan, Anitha ; Lutsen, Laurence ; Vanderzande, Dirk ; Junkers, Tanja</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c378t-73a0b7d6bc3683424096ccabafa944b74eb494a032ad4fb744104c56d7421f03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Anionic polymerization</topic><topic>Applied sciences</topic><topic>Block copolymers</topic><topic>Blocking</topic><topic>Conjugation</topic><topic>CuAAC conjugation</topic><topic>Exact sciences and technology</topic><topic>Glycols</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Poly(p-phenylene vinylene) (PPV)</topic><topic>Polymers with particular properties</topic><topic>Polyphenylene vinylene</topic><topic>Precursors</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>Self assembly</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cosemans, Inge</creatorcontrib><creatorcontrib>Vandenbergh, Joke</creatorcontrib><creatorcontrib>D’Olieslaeger, Lien</creatorcontrib><creatorcontrib>Ethirajan, Anitha</creatorcontrib><creatorcontrib>Lutsen, Laurence</creatorcontrib><creatorcontrib>Vanderzande, Dirk</creatorcontrib><creatorcontrib>Junkers, Tanja</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>European polymer journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cosemans, Inge</au><au>Vandenbergh, Joke</au><au>D’Olieslaeger, Lien</au><au>Ethirajan, Anitha</au><au>Lutsen, Laurence</au><au>Vanderzande, Dirk</au><au>Junkers, Tanja</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of PPV-b-PEG block copolymers via CuAAC conjugation</atitle><jtitle>European polymer journal</jtitle><date>2014-06-01</date><risdate>2014</risdate><volume>55</volume><spage>114</spage><epage>122</epage><pages>114-122</pages><issn>0014-3057</issn><eissn>1873-1945</eissn><coden>EUPJAG</coden><abstract>[Display omitted]
•PPV polymers with well-defined endgroups and chain length have been synthesized.•Clickable endgroups are embedded in the anionic polymerization initiator.•PPV-PEG block copolymers were synthesized via CuAAC reactions.•The obtained block copolymers show self-assembly behavior.
The synthesis of amphiphilic rod-coil block copolymers with a poly(p-phenylene vinylene) (PPV) rod-like block using a Click chemistry approach is investigated and a facile reaction pathway towards poly(p-phenylene vinylene)-block-poly(ethylene glycol) (PPV-b-PEG) block copolymers is presented. To reach this aim, an alkyne-functionalized PPV block (synthesized from anionic sulfinyl precursor route polymerization) was synthesized and subsequently coupled to azide-functionalized poly(ethylene glycol) of different lengths. Self-assembly of these materials in aqueous solution demonstrate successful micelle formation with core–shell morphology and different sizes for these PPV-b-PEG block copolymers as is confirmed by TEM and DLS measurements respectively.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.eurpolymj.2014.03.016</doi><tpages>9</tpages></addata></record> |
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| ispartof | European polymer journal, 2014-06, Vol.55, p.114-122 |
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| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Anionic polymerization Applied sciences Block copolymers Blocking Conjugation CuAAC conjugation Exact sciences and technology Glycols Organic polymers Physicochemistry of polymers Poly(p-phenylene vinylene) (PPV) Polymers with particular properties Polyphenylene vinylene Precursors Preparation, kinetics, thermodynamics, mechanism and catalysts Self assembly Synthesis |
| title | Synthesis of PPV-b-PEG block copolymers via CuAAC conjugation |
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