Coherent two-dimensional electronic spectroscopy in the Soret band of a chiral porphyrin dimer

Using coherent two-dimensional (2D) electronic spectroscopy in fully noncollinear geometry, we observe the excitonic coupling of β,β′-linked bis[tetraphenylporphyrinato-zinc(II)] on an ultrafast timescale in the excited state. The results for two states in the Soret band originating from an excitoni...

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Veröffentlicht in:	New journal of physics 2013-02, Vol.15 (2), p.25006-12
Hauptverfasser:	Koch, Federico, Kullmann, Martin, Selig, Ulrike, Nuernberger, Patrick, Götz, Daniel C G, Bringmann, Gerhard, Brixner, Tobias
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Sprache:	eng
Schlagworte:	Coherence Electronics Excitation Excitation spectra Joining Spectra Spectroscopy Two dimensional
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creator	Koch, Federico Kullmann, Martin Selig, Ulrike Nuernberger, Patrick Götz, Daniel C G Bringmann, Gerhard Brixner, Tobias
description	Using coherent two-dimensional (2D) electronic spectroscopy in fully noncollinear geometry, we observe the excitonic coupling of β,β′-linked bis[tetraphenylporphyrinato-zinc(II)] on an ultrafast timescale in the excited state. The results for two states in the Soret band originating from an excitonic splitting are explained by population transfer with approximately 100 fs from the energetically higher to the lower excitonic state. This interpretation is consistent with exemplary calculations of 2D spectra for a model four-level system with coupling.
doi_str_mv	10.1088/1367-2630/15/2/025006
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subjects	Coherence Electronics Excitation Excitation spectra Joining Spectra Spectroscopy Two dimensional
title	Coherent two-dimensional electronic spectroscopy in the Soret band of a chiral porphyrin dimer
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