Self-Assembly of Subnanometer-Scaled Polyhedral Oligomeric Silsesquioxane (POSS) Macroions in Dilute Solution

Both positively and negatively charged polyhedral oligomeric silsesquioxane (POSS) electrolytes were observed to self‐assemble into blackberry‐type supramolecular structures in water/acetone mixed solvents, driven by the counterion‐mediated attraction. Laser light‐scattering studies reveal that the...

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Veröffentlicht in:	European journal of inorganic chemistry 2014-09, Vol.2014 (27), p.4593-4599
Hauptverfasser:	Zhou, Jing, Yin, Panchao, Hu, Lang, Haso, Fadi, Liu, Tianbo
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetone Charging Dilution Electrolytes Hydrogen bonding Macroions Polarity Polyhedral oligomeric silsesquioxane Self assembly Silsesquioxane Solvent effects Solvents Supramolecular chemistry
Online-Zugang:	Volltext
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