Acidic ionic liquid supported on silica-coated magnetite nanoparticles as a green catalyst for one-pot diazotization–halogenation of the aromatic amines
Acidic ionic liquid was immobilized on silica-coated magnetite nanoparticles (Fe 3 O 4 @SILnP) and used as an efficient heterogeneous catalyst for the diazotization–iodination reaction of different aromatic amines under solvent-free conditions at room temperature. The diazonium salts that are formed...
Gespeichert in:
| Veröffentlicht in: | RSC advances 2014-01, Vol.4 (90), p.49333-49341 |
|---|---|
| 1. Verfasser: | |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 49341 |
|---|---|
| container_issue | 90 |
| container_start_page | 49333 |
| container_title | RSC advances |
| container_volume | 4 |
| creator | Isaad, Jalal |
| description | Acidic ionic liquid was immobilized on silica-coated magnetite nanoparticles (Fe
3
O
4
@SILnP) and used as an efficient heterogeneous catalyst for the diazotization–iodination reaction of different aromatic amines under solvent-free conditions at room temperature. The diazonium salts that are formed by this catalyst are stable at room temperature and react rapidly with sodium iodide to produce aryl iodides in good to excellent yields. This method has some advantages such as low pollution, rapid access to products, simple work-up and easy separation of catalyst from the reaction mixture. |
| doi_str_mv | 10.1039/C4RA05705H |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1629341074</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1629341074</sourcerecordid><originalsourceid>FETCH-LOGICAL-c330t-b528ba6f625c8094f577423b3eefffe9f596f83f5be2b604abd061385dcd8cfb3</originalsourceid><addsrcrecordid>eNpNUcFKw0AQDaJgqb34BXsUIbrJZjfJsRS1QkEQPYfJZrZdSXbT3c2hPfkP3vw8v8TUCjoM82YejzeHF0WXCb1JKCtvF9nznPKc8uVJNElpJuKUivL0334ezbx_o2MJnqQimUSfc6kbLYm2Zpyt3g66IX7oe-sCNsQa4nWrJcTSwoHoYG0w6IDEgLE9uKBli57A2GTtEA2REKDd-UCUdaMBxr0NpNGwt0HvIYyfvt4_NtDaNZqfk1hFwgYJONuNhCTQaYP-IjpT0Hqc_eI0er2_e1ks49XTw-NivoolYzTENU-LGoQSKZcFLTPF8zxLWc0QlVJYKl4KVTDFa0xrQTOoGyoSVvBGNoVUNZtGV0ff3tntgD5UnfYS2xYM2sFXiUhLliU0z0bp9VEqnfXeoap6pztwuyqh1SGD6i8D9g1mfH5l</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1629341074</pqid></control><display><type>article</type><title>Acidic ionic liquid supported on silica-coated magnetite nanoparticles as a green catalyst for one-pot diazotization–halogenation of the aromatic amines</title><source>Royal Society Of Chemistry Journals</source><creator>Isaad, Jalal</creator><creatorcontrib>Isaad, Jalal</creatorcontrib><description>Acidic ionic liquid was immobilized on silica-coated magnetite nanoparticles (Fe
3
O
4
@SILnP) and used as an efficient heterogeneous catalyst for the diazotization–iodination reaction of different aromatic amines under solvent-free conditions at room temperature. The diazonium salts that are formed by this catalyst are stable at room temperature and react rapidly with sodium iodide to produce aryl iodides in good to excellent yields. This method has some advantages such as low pollution, rapid access to products, simple work-up and easy separation of catalyst from the reaction mixture.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/C4RA05705H</identifier><language>eng</language><subject>Amines ; Aromatic compounds ; Catalysts ; Iodides ; Ionic liquids ; Magnetite ; Nanoparticles ; Pollution abatement</subject><ispartof>RSC advances, 2014-01, Vol.4 (90), p.49333-49341</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c330t-b528ba6f625c8094f577423b3eefffe9f596f83f5be2b604abd061385dcd8cfb3</citedby><cites>FETCH-LOGICAL-c330t-b528ba6f625c8094f577423b3eefffe9f596f83f5be2b604abd061385dcd8cfb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,27929,27930</link.rule.ids></links><search><creatorcontrib>Isaad, Jalal</creatorcontrib><title>Acidic ionic liquid supported on silica-coated magnetite nanoparticles as a green catalyst for one-pot diazotization–halogenation of the aromatic amines</title><title>RSC advances</title><description>Acidic ionic liquid was immobilized on silica-coated magnetite nanoparticles (Fe
3
O
4
@SILnP) and used as an efficient heterogeneous catalyst for the diazotization–iodination reaction of different aromatic amines under solvent-free conditions at room temperature. The diazonium salts that are formed by this catalyst are stable at room temperature and react rapidly with sodium iodide to produce aryl iodides in good to excellent yields. This method has some advantages such as low pollution, rapid access to products, simple work-up and easy separation of catalyst from the reaction mixture.</description><subject>Amines</subject><subject>Aromatic compounds</subject><subject>Catalysts</subject><subject>Iodides</subject><subject>Ionic liquids</subject><subject>Magnetite</subject><subject>Nanoparticles</subject><subject>Pollution abatement</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNpNUcFKw0AQDaJgqb34BXsUIbrJZjfJsRS1QkEQPYfJZrZdSXbT3c2hPfkP3vw8v8TUCjoM82YejzeHF0WXCb1JKCtvF9nznPKc8uVJNElpJuKUivL0334ezbx_o2MJnqQimUSfc6kbLYm2Zpyt3g66IX7oe-sCNsQa4nWrJcTSwoHoYG0w6IDEgLE9uKBli57A2GTtEA2REKDd-UCUdaMBxr0NpNGwt0HvIYyfvt4_NtDaNZqfk1hFwgYJONuNhCTQaYP-IjpT0Hqc_eI0er2_e1ks49XTw-NivoolYzTENU-LGoQSKZcFLTPF8zxLWc0QlVJYKl4KVTDFa0xrQTOoGyoSVvBGNoVUNZtGV0ff3tntgD5UnfYS2xYM2sFXiUhLliU0z0bp9VEqnfXeoap6pztwuyqh1SGD6i8D9g1mfH5l</recordid><startdate>20140101</startdate><enddate>20140101</enddate><creator>Isaad, Jalal</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20140101</creationdate><title>Acidic ionic liquid supported on silica-coated magnetite nanoparticles as a green catalyst for one-pot diazotization–halogenation of the aromatic amines</title><author>Isaad, Jalal</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c330t-b528ba6f625c8094f577423b3eefffe9f596f83f5be2b604abd061385dcd8cfb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Amines</topic><topic>Aromatic compounds</topic><topic>Catalysts</topic><topic>Iodides</topic><topic>Ionic liquids</topic><topic>Magnetite</topic><topic>Nanoparticles</topic><topic>Pollution abatement</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Isaad, Jalal</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Isaad, Jalal</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Acidic ionic liquid supported on silica-coated magnetite nanoparticles as a green catalyst for one-pot diazotization–halogenation of the aromatic amines</atitle><jtitle>RSC advances</jtitle><date>2014-01-01</date><risdate>2014</risdate><volume>4</volume><issue>90</issue><spage>49333</spage><epage>49341</epage><pages>49333-49341</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>Acidic ionic liquid was immobilized on silica-coated magnetite nanoparticles (Fe
3
O
4
@SILnP) and used as an efficient heterogeneous catalyst for the diazotization–iodination reaction of different aromatic amines under solvent-free conditions at room temperature. The diazonium salts that are formed by this catalyst are stable at room temperature and react rapidly with sodium iodide to produce aryl iodides in good to excellent yields. This method has some advantages such as low pollution, rapid access to products, simple work-up and easy separation of catalyst from the reaction mixture.</abstract><doi>10.1039/C4RA05705H</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2046-2069 |
| ispartof | RSC advances, 2014-01, Vol.4 (90), p.49333-49341 |
| issn | 2046-2069 2046-2069 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1629341074 |
| source | Royal Society Of Chemistry Journals |
| subjects | Amines Aromatic compounds Catalysts Iodides Ionic liquids Magnetite Nanoparticles Pollution abatement |
| title | Acidic ionic liquid supported on silica-coated magnetite nanoparticles as a green catalyst for one-pot diazotization–halogenation of the aromatic amines |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-13T04%3A41%3A58IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Acidic%20ionic%20liquid%20supported%20on%20silica-coated%20magnetite%20nanoparticles%20as%20a%20green%20catalyst%20for%20one-pot%20diazotization%E2%80%93halogenation%20of%20the%20aromatic%20amines&rft.jtitle=RSC%20advances&rft.au=Isaad,%20Jalal&rft.date=2014-01-01&rft.volume=4&rft.issue=90&rft.spage=49333&rft.epage=49341&rft.pages=49333-49341&rft.issn=2046-2069&rft.eissn=2046-2069&rft_id=info:doi/10.1039/C4RA05705H&rft_dat=%3Cproquest_cross%3E1629341074%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1629341074&rft_id=info:pmid/&rfr_iscdi=true |