The 1:1-adduct of chlorotriphenyltin with 2',6'-dimethoxyflavone : a potential fungicide
The 1:1 adduct of chlorotriphenyltin with 2',6'-dimethoxyflavone, (C sub(35)H sub(29)O sub(4)ClSn) Mr = 667.78, crystallizes in the triclinic space group P1avg with the following data: a = 9.094(2), b = 12.369(3), c = 14.674(3) Angstrom, alpha = 74.78(2), beta = 77.00(2), gamma = 73.06(3)...
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Veröffentlicht in: | Journal of chemical crystallography 1996-10, Vol.26 (10), p.691-694 |
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creator | MANIUKIEWICZ, W MOLINS, E MIRAVITLLES, C WALLET, J.-C GAYDOU, E. M |
description | The 1:1 adduct of chlorotriphenyltin with 2',6'-dimethoxyflavone, (C sub(35)H sub(29)O sub(4)ClSn) Mr = 667.78, crystallizes in the triclinic space group P1avg with the following data: a = 9.094(2), b = 12.369(3), c = 14.674(3) Angstrom, alpha = 74.78(2), beta = 77.00(2), gamma = 73.06(3) degree , V = 1503.8(4) Angstrom super(3), Z = 2, Mo-K alpha , mu = 9, 8 cm super(-1), Dc = 1.475 g cm super(-3), F(000) = 676, T = 293K. The structure was solved by direct-methods and has been refined to a final R value (I > 3 sigma (I)) of 0.0301. The flavone coordinates to the tin atom through the carbonyl oxygen atom. The metal center exhibits a trigonal bipyramidal configuration with the three phenyl groups in equatorial positions. |
doi_str_mv | 10.1007/BF01991965 |
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M</creator><creatorcontrib>MANIUKIEWICZ, W ; MOLINS, E ; MIRAVITLLES, C ; WALLET, J.-C ; GAYDOU, E. M</creatorcontrib><description>The 1:1 adduct of chlorotriphenyltin with 2',6'-dimethoxyflavone, (C sub(35)H sub(29)O sub(4)ClSn) Mr = 667.78, crystallizes in the triclinic space group P1avg with the following data: a = 9.094(2), b = 12.369(3), c = 14.674(3) Angstrom, alpha = 74.78(2), beta = 77.00(2), gamma = 73.06(3) degree , V = 1503.8(4) Angstrom super(3), Z = 2, Mo-K alpha , mu = 9, 8 cm super(-1), Dc = 1.475 g cm super(-3), F(000) = 676, T = 293K. The structure was solved by direct-methods and has been refined to a final R value (I > 3 sigma (I)) of 0.0301. The flavone coordinates to the tin atom through the carbonyl oxygen atom. The metal center exhibits a trigonal bipyramidal configuration with the three phenyl groups in equatorial positions.</description><identifier>ISSN: 1074-1542</identifier><identifier>EISSN: 1572-8854</identifier><identifier>DOI: 10.1007/BF01991965</identifier><identifier>CODEN: JCCYEV</identifier><language>eng</language><publisher>New York, NY: Plenum</publisher><subject>Antibiotics. Antiinfectious agents. Antiparasitic agents ; Antifungal agents ; Biological and medical sciences ; Condensed matter: structure, mechanical and thermal properties ; Exact sciences and technology ; Inorganic compounds ; Medical sciences ; Metal complexes ; Organic compounds ; Organometalloidal and organometallic compounds ; Pharmacology. 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M</creatorcontrib><title>The 1:1-adduct of chlorotriphenyltin with 2',6'-dimethoxyflavone : a potential fungicide</title><title>Journal of chemical crystallography</title><description>The 1:1 adduct of chlorotriphenyltin with 2',6'-dimethoxyflavone, (C sub(35)H sub(29)O sub(4)ClSn) Mr = 667.78, crystallizes in the triclinic space group P1avg with the following data: a = 9.094(2), b = 12.369(3), c = 14.674(3) Angstrom, alpha = 74.78(2), beta = 77.00(2), gamma = 73.06(3) degree , V = 1503.8(4) Angstrom super(3), Z = 2, Mo-K alpha , mu = 9, 8 cm super(-1), Dc = 1.475 g cm super(-3), F(000) = 676, T = 293K. The structure was solved by direct-methods and has been refined to a final R value (I > 3 sigma (I)) of 0.0301. The flavone coordinates to the tin atom through the carbonyl oxygen atom. The metal center exhibits a trigonal bipyramidal configuration with the three phenyl groups in equatorial positions.</description><subject>Antibiotics. Antiinfectious agents. Antiparasitic agents</subject><subject>Antifungal agents</subject><subject>Biological and medical sciences</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Exact sciences and technology</subject><subject>Inorganic compounds</subject><subject>Medical sciences</subject><subject>Metal complexes</subject><subject>Organic compounds</subject><subject>Organometalloidal and organometallic compounds</subject><subject>Pharmacology. 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Antiparasitic agents</topic><topic>Antifungal agents</topic><topic>Biological and medical sciences</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Exact sciences and technology</topic><topic>Inorganic compounds</topic><topic>Medical sciences</topic><topic>Metal complexes</topic><topic>Organic compounds</topic><topic>Organometalloidal and organometallic compounds</topic><topic>Pharmacology. Drug treatments</topic><topic>Physics</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>MANIUKIEWICZ, W</creatorcontrib><creatorcontrib>MOLINS, E</creatorcontrib><creatorcontrib>MIRAVITLLES, C</creatorcontrib><creatorcontrib>WALLET, J.-C</creatorcontrib><creatorcontrib>GAYDOU, E. M</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Algology Mycology and Protozoology Abstracts (Microbiology C)</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Journal of chemical crystallography</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>MANIUKIEWICZ, W</au><au>MOLINS, E</au><au>MIRAVITLLES, C</au><au>WALLET, J.-C</au><au>GAYDOU, E. M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The 1:1-adduct of chlorotriphenyltin with 2',6'-dimethoxyflavone : a potential fungicide</atitle><jtitle>Journal of chemical crystallography</jtitle><date>1996-10-01</date><risdate>1996</risdate><volume>26</volume><issue>10</issue><spage>691</spage><epage>694</epage><pages>691-694</pages><issn>1074-1542</issn><eissn>1572-8854</eissn><coden>JCCYEV</coden><abstract>The 1:1 adduct of chlorotriphenyltin with 2',6'-dimethoxyflavone, (C sub(35)H sub(29)O sub(4)ClSn) Mr = 667.78, crystallizes in the triclinic space group P1avg with the following data: a = 9.094(2), b = 12.369(3), c = 14.674(3) Angstrom, alpha = 74.78(2), beta = 77.00(2), gamma = 73.06(3) degree , V = 1503.8(4) Angstrom super(3), Z = 2, Mo-K alpha , mu = 9, 8 cm super(-1), Dc = 1.475 g cm super(-3), F(000) = 676, T = 293K. The structure was solved by direct-methods and has been refined to a final R value (I > 3 sigma (I)) of 0.0301. The flavone coordinates to the tin atom through the carbonyl oxygen atom. The metal center exhibits a trigonal bipyramidal configuration with the three phenyl groups in equatorial positions.</abstract><cop>New York, NY</cop><pub>Plenum</pub><doi>10.1007/BF01991965</doi><tpages>4</tpages></addata></record> |
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subjects | Antibiotics. Antiinfectious agents. Antiparasitic agents Antifungal agents Biological and medical sciences Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Inorganic compounds Medical sciences Metal complexes Organic compounds Organometalloidal and organometallic compounds Pharmacology. Drug treatments Physics Structure of solids and liquids crystallography Structure of specific crystalline solids |
title | The 1:1-adduct of chlorotriphenyltin with 2',6'-dimethoxyflavone : a potential fungicide |
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