The 1:1-adduct of chlorotriphenyltin with 2',6'-dimethoxyflavone : a potential fungicide

The 1:1 adduct of chlorotriphenyltin with 2',6'-dimethoxyflavone, (C sub(35)H sub(29)O sub(4)ClSn) Mr = 667.78, crystallizes in the triclinic space group P1avg with the following data: a = 9.094(2), b = 12.369(3), c = 14.674(3) Angstrom, alpha = 74.78(2), beta = 77.00(2), gamma = 73.06(3)...

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Veröffentlicht in:Journal of chemical crystallography 1996-10, Vol.26 (10), p.691-694
Hauptverfasser: MANIUKIEWICZ, W, MOLINS, E, MIRAVITLLES, C, WALLET, J.-C, GAYDOU, E. M
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container_end_page 694
container_issue 10
container_start_page 691
container_title Journal of chemical crystallography
container_volume 26
creator MANIUKIEWICZ, W
MOLINS, E
MIRAVITLLES, C
WALLET, J.-C
GAYDOU, E. M
description The 1:1 adduct of chlorotriphenyltin with 2',6'-dimethoxyflavone, (C sub(35)H sub(29)O sub(4)ClSn) Mr = 667.78, crystallizes in the triclinic space group P1avg with the following data: a = 9.094(2), b = 12.369(3), c = 14.674(3) Angstrom, alpha = 74.78(2), beta = 77.00(2), gamma = 73.06(3) degree , V = 1503.8(4) Angstrom super(3), Z = 2, Mo-K alpha , mu = 9, 8 cm super(-1), Dc = 1.475 g cm super(-3), F(000) = 676, T = 293K. The structure was solved by direct-methods and has been refined to a final R value (I > 3 sigma (I)) of 0.0301. The flavone coordinates to the tin atom through the carbonyl oxygen atom. The metal center exhibits a trigonal bipyramidal configuration with the three phenyl groups in equatorial positions.
doi_str_mv 10.1007/BF01991965
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Antiparasitic agents</topic><topic>Antifungal agents</topic><topic>Biological and medical sciences</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Exact sciences and technology</topic><topic>Inorganic compounds</topic><topic>Medical sciences</topic><topic>Metal complexes</topic><topic>Organic compounds</topic><topic>Organometalloidal and organometallic compounds</topic><topic>Pharmacology. Drug treatments</topic><topic>Physics</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>MANIUKIEWICZ, W</creatorcontrib><creatorcontrib>MOLINS, E</creatorcontrib><creatorcontrib>MIRAVITLLES, C</creatorcontrib><creatorcontrib>WALLET, J.-C</creatorcontrib><creatorcontrib>GAYDOU, E. 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M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The 1:1-adduct of chlorotriphenyltin with 2',6'-dimethoxyflavone : a potential fungicide</atitle><jtitle>Journal of chemical crystallography</jtitle><date>1996-10-01</date><risdate>1996</risdate><volume>26</volume><issue>10</issue><spage>691</spage><epage>694</epage><pages>691-694</pages><issn>1074-1542</issn><eissn>1572-8854</eissn><coden>JCCYEV</coden><abstract>The 1:1 adduct of chlorotriphenyltin with 2',6'-dimethoxyflavone, (C sub(35)H sub(29)O sub(4)ClSn) Mr = 667.78, crystallizes in the triclinic space group P1avg with the following data: a = 9.094(2), b = 12.369(3), c = 14.674(3) Angstrom, alpha = 74.78(2), beta = 77.00(2), gamma = 73.06(3) degree , V = 1503.8(4) Angstrom super(3), Z = 2, Mo-K alpha , mu = 9, 8 cm super(-1), Dc = 1.475 g cm super(-3), F(000) = 676, T = 293K. The structure was solved by direct-methods and has been refined to a final R value (I &gt; 3 sigma (I)) of 0.0301. The flavone coordinates to the tin atom through the carbonyl oxygen atom. The metal center exhibits a trigonal bipyramidal configuration with the three phenyl groups in equatorial positions.</abstract><cop>New York, NY</cop><pub>Plenum</pub><doi>10.1007/BF01991965</doi><tpages>4</tpages></addata></record>
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subjects Antibiotics. Antiinfectious agents. Antiparasitic agents
Antifungal agents
Biological and medical sciences
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Inorganic compounds
Medical sciences
Metal complexes
Organic compounds
Organometalloidal and organometallic compounds
Pharmacology. Drug treatments
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
title The 1:1-adduct of chlorotriphenyltin with 2',6'-dimethoxyflavone : a potential fungicide
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