Facile Control of the Charge Density and Photocatalytic Activity of an Anionic Indium Porphyrin Framework via in Situ Metalation

An anionic indium porphyrin framework (UNLPF-10) consisting of rare Williams β-tetrakaidecahedral cages was constructed using an octatopic ligand linked with 4-connected [In­(COO)4]− SBUs. Remarkably, the extent of indium metalation of porphyrin macrocycles in UNLPF-10 can be facilely tuned in situ...

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Veröffentlicht in:	J. Am. Chem. Soc 2014-11, Vol.136 (45), p.15881-15884
Hauptverfasser:	Johnson, Jacob A, Zhang, Xu, Reeson, Tyler C, Chen, Yu-Sheng, Zhang, Jian
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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