Facile Control of the Charge Density and Photocatalytic Activity of an Anionic Indium Porphyrin Framework via in Situ Metalation

Facile Control of the Charge Density and Photocatalytic Activity of an Anionic Indium Porphyrin Framework via in Situ Metalation

An anionic indium porphyrin framework (UNLPF-10) consisting of rare Williams β-tetrakaidecahedral cages was constructed using an octatopic ligand linked with 4-connected [In­(COO)4]− SBUs. Remarkably, the extent of indium metalation of porphyrin macrocycles in UNLPF-10 can be facilely tuned in situ...

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Veröffentlicht in:J. Am. Chem. Soc 2014-11, Vol.136 (45), p.15881-15884
Hauptverfasser: Johnson, Jacob A, Zhang, Xu, Reeson, Tyler C, Chen, Yu-Sheng, Zhang, Jian
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container_title J. Am. Chem. Soc
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creator Johnson, Jacob A
Zhang, Xu
Reeson, Tyler C
Chen, Yu-Sheng
Zhang, Jian
description An anionic indium porphyrin framework (UNLPF-10) consisting of rare Williams β-tetrakaidecahedral cages was constructed using an octatopic ligand linked with 4-connected [In­(COO)4]− SBUs. Remarkably, the extent of indium metalation of porphyrin macrocycles in UNLPF-10 can be facilely tuned in situ depending on the M/L ratio during synthesis, resulting in a controllable framework charge density and photocatalytic activity toward the selective oxygenation of sulfides.
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