Solubilization of organics in water coupled with sulphite autoxidation
The autoxidation of aqueous SO 2 (HSO − 3, SO 2− 3) was applied to induce the solubilization of organic compounds modelling oil components (toluene, naphthalene, paraffin oil) in water. Experiments were performed in laboratory absorbers, a froth column and a tank reactor with a planar gas-liquid int...
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| Veröffentlicht in: | Water research (Oxford) 1997-07, Vol.31 (7), p.1767-1775 |
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| container_title | Water research (Oxford) |
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| creator | Pasiuk-Bronikowska, Wanda Bronikowski, Tadeusz Ulejczyk, Marek |
| description | The autoxidation of aqueous SO
2 (HSO
−
3, SO
2−
3) was applied to induce the solubilization of organic compounds modelling oil components (toluene, naphthalene, paraffin oil) in water. Experiments were performed in laboratory absorbers, a froth column and a tank reactor with a planar gas-liquid interface, under mild conditions. Basing on the spectrophotometric and chromatographic evidence for the successive substitution of sulphonic acid functions, the route for sulphonation of these compounds was suggested. The results of kinetic measurements related to the formation of S
VI due to oxidation of S
IV and to the decay of the initial organic compound due to its sulphonation were discussed in terms of a chain reaction with competitive inhibition. The possible use of the induced solubilization of oil components for the removal of oil splashes, for instance in sewage management, was put forward. |
| doi_str_mv | 10.1016/S0043-1354(97)00001-8 |
| format | Article |
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2 (HSO
−
3, SO
2−
3) was applied to induce the solubilization of organic compounds modelling oil components (toluene, naphthalene, paraffin oil) in water. Experiments were performed in laboratory absorbers, a froth column and a tank reactor with a planar gas-liquid interface, under mild conditions. Basing on the spectrophotometric and chromatographic evidence for the successive substitution of sulphonic acid functions, the route for sulphonation of these compounds was suggested. The results of kinetic measurements related to the formation of S
VI due to oxidation of S
IV and to the decay of the initial organic compound due to its sulphonation were discussed in terms of a chain reaction with competitive inhibition. The possible use of the induced solubilization of oil components for the removal of oil splashes, for instance in sewage management, was put forward.</description><identifier>ISSN: 0043-1354</identifier><identifier>EISSN: 1879-2448</identifier><identifier>DOI: 10.1016/S0043-1354(97)00001-8</identifier><identifier>CODEN: WATRAG</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; Biological and physicochemical phenomena ; Exact sciences and technology ; homogeneous catalysis ; induced sulphonation ; inhibition ; Natural water pollution ; Pollution ; S IV autoxidation ; solubilization of oil in water ; Water treatment and pollution</subject><ispartof>Water research (Oxford), 1997-07, Vol.31 (7), p.1767-1775</ispartof><rights>1997</rights><rights>1997 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c367t-bcb0ca57bce3348a9c3057b2e0f007c4b2443983aa51349e79f71deedb3b34513</citedby><cites>FETCH-LOGICAL-c367t-bcb0ca57bce3348a9c3057b2e0f007c4b2443983aa51349e79f71deedb3b34513</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0043135497000018$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=2718771$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Pasiuk-Bronikowska, Wanda</creatorcontrib><creatorcontrib>Bronikowski, Tadeusz</creatorcontrib><creatorcontrib>Ulejczyk, Marek</creatorcontrib><title>Solubilization of organics in water coupled with sulphite autoxidation</title><title>Water research (Oxford)</title><description>The autoxidation of aqueous SO
2 (HSO
−
3, SO
2−
3) was applied to induce the solubilization of organic compounds modelling oil components (toluene, naphthalene, paraffin oil) in water. Experiments were performed in laboratory absorbers, a froth column and a tank reactor with a planar gas-liquid interface, under mild conditions. Basing on the spectrophotometric and chromatographic evidence for the successive substitution of sulphonic acid functions, the route for sulphonation of these compounds was suggested. The results of kinetic measurements related to the formation of S
VI due to oxidation of S
IV and to the decay of the initial organic compound due to its sulphonation were discussed in terms of a chain reaction with competitive inhibition. The possible use of the induced solubilization of oil components for the removal of oil splashes, for instance in sewage management, was put forward.</description><subject>Applied sciences</subject><subject>Biological and physicochemical phenomena</subject><subject>Exact sciences and technology</subject><subject>homogeneous catalysis</subject><subject>induced sulphonation</subject><subject>inhibition</subject><subject>Natural water pollution</subject><subject>Pollution</subject><subject>S IV autoxidation</subject><subject>solubilization of oil in water</subject><subject>Water treatment and pollution</subject><issn>0043-1354</issn><issn>1879-2448</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1997</creationdate><recordtype>article</recordtype><recordid>eNqFkE1PAyEQhonRxFr9CSYcjNHDKixs2T0Z01g1aeKheiYsO2sxdKnAWvXXSz_Sq1wIk-dlZh6Ezim5oYSObmeEcJZRVvCrSlyTdGhWHqABLUWV5ZyXh2iwR47RSQgficlzVg3QZOZsXxtrflU0rsOuxc6_q87ogE2HVyqCx9r1SwsNXpk4x6G3y7mJgFUf3bdpNrlTdNQqG-Bsdw_R2-ThdfyUTV8en8f300yzkYhZrWuiVSFqDYzxUlWakfTKgbSECM3rNC2rSqZUQRmvQFStoA1AU7Oa8VQbosvtv0vvPnsIUS5M0GCt6sD1QdJRzggTLIHFFtTeheChlUtvFsr_SErk2prcWJNrJbIScmNNlil3sWuggla29arTJuzDuUhSxXqOuy0GadkvA14GbaDT0BgPOsrGmX8a_QHvGYF1</recordid><startdate>19970701</startdate><enddate>19970701</enddate><creator>Pasiuk-Bronikowska, Wanda</creator><creator>Bronikowski, Tadeusz</creator><creator>Ulejczyk, Marek</creator><general>Elsevier Ltd</general><general>Elsevier Science</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7UA</scope><scope>C1K</scope></search><sort><creationdate>19970701</creationdate><title>Solubilization of organics in water coupled with sulphite autoxidation</title><author>Pasiuk-Bronikowska, Wanda ; Bronikowski, Tadeusz ; Ulejczyk, Marek</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c367t-bcb0ca57bce3348a9c3057b2e0f007c4b2443983aa51349e79f71deedb3b34513</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1997</creationdate><topic>Applied sciences</topic><topic>Biological and physicochemical phenomena</topic><topic>Exact sciences and technology</topic><topic>homogeneous catalysis</topic><topic>induced sulphonation</topic><topic>inhibition</topic><topic>Natural water pollution</topic><topic>Pollution</topic><topic>S IV autoxidation</topic><topic>solubilization of oil in water</topic><topic>Water treatment and pollution</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pasiuk-Bronikowska, Wanda</creatorcontrib><creatorcontrib>Bronikowski, Tadeusz</creatorcontrib><creatorcontrib>Ulejczyk, Marek</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Water Resources Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><jtitle>Water research (Oxford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pasiuk-Bronikowska, Wanda</au><au>Bronikowski, Tadeusz</au><au>Ulejczyk, Marek</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Solubilization of organics in water coupled with sulphite autoxidation</atitle><jtitle>Water research (Oxford)</jtitle><date>1997-07-01</date><risdate>1997</risdate><volume>31</volume><issue>7</issue><spage>1767</spage><epage>1775</epage><pages>1767-1775</pages><issn>0043-1354</issn><eissn>1879-2448</eissn><coden>WATRAG</coden><abstract>The autoxidation of aqueous SO
2 (HSO
−
3, SO
2−
3) was applied to induce the solubilization of organic compounds modelling oil components (toluene, naphthalene, paraffin oil) in water. Experiments were performed in laboratory absorbers, a froth column and a tank reactor with a planar gas-liquid interface, under mild conditions. Basing on the spectrophotometric and chromatographic evidence for the successive substitution of sulphonic acid functions, the route for sulphonation of these compounds was suggested. The results of kinetic measurements related to the formation of S
VI due to oxidation of S
IV and to the decay of the initial organic compound due to its sulphonation were discussed in terms of a chain reaction with competitive inhibition. The possible use of the induced solubilization of oil components for the removal of oil splashes, for instance in sewage management, was put forward.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/S0043-1354(97)00001-8</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
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| ispartof | Water research (Oxford), 1997-07, Vol.31 (7), p.1767-1775 |
| issn | 0043-1354 1879-2448 |
| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | Applied sciences Biological and physicochemical phenomena Exact sciences and technology homogeneous catalysis induced sulphonation inhibition Natural water pollution Pollution S IV autoxidation solubilization of oil in water Water treatment and pollution |
| title | Solubilization of organics in water coupled with sulphite autoxidation |
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