Selective conversion of alcohols in water to carboxylic acids by in situ generated ruthenium trans dihydrido carbonyl PNP complexes

In this work, we present a mild method for direct conversion of primary alcohols into carboxylic acids with the use of water as an oxygen source. Applying a ruthenium dihydrogen based dehydrogenation catalyst for this cause, we investigated the effect of water on the catalytic dehydrogenation proces...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2014-12, Vol.43 (46), p.17248-17254
Hauptverfasser:	Choi, Jong-Hoo, Heim, Leo E, Ahrens, Mike, Prechtl, Martin H G
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Sprache:	eng
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container_title	Dalton transactions : an international journal of inorganic chemistry
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creator	Choi, Jong-Hoo Heim, Leo E Ahrens, Mike Prechtl, Martin H G
description	In this work, we present a mild method for direct conversion of primary alcohols into carboxylic acids with the use of water as an oxygen source. Applying a ruthenium dihydrogen based dehydrogenation catalyst for this cause, we investigated the effect of water on the catalytic dehydrogenation process of alcohols. Using 1 mol% of the catalyst we report up to high yields. Moreover, we isolated key intermediates which most likely play a role in the catalytic cycle. One of the intermediates was identified as a trans dihydrido carbonyl complex which is generated in situ in the catalytic process.
doi_str_mv	10.1039/c4dt01634c
format	Article
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title	Selective conversion of alcohols in water to carboxylic acids by in situ generated ruthenium trans dihydrido carbonyl PNP complexes
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