A "Systematic Approach" to TD-GPC Data Processing with Band Broadening Correction
Summary The application of the systematic approach during detector offset determination in triple detector GPC polymer analysis has been shown to result in improvements in terms of the variations observed among the methods for molecular weight distribution determination. More importantly, the remain...
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| Veröffentlicht in: | Macromolecular symposia. 2013-08, Vol.330 (1), p.53-62 |
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| container_title | Macromolecular symposia. |
| container_volume | 330 |
| creator | Yau, Wallace Brown, Ray Tyler, Phillip Huang, Tianzi Cong, Rongjuan Klinker, Chanda Hazlitt, Lonnie |
| description | Summary
The application of the systematic approach during detector offset determination in triple detector GPC polymer analysis has been shown to result in improvements in terms of the variations observed among the methods for molecular weight distribution determination. More importantly, the remaining, reduced variations are theoretically consistent with axial dispersion corrections proposed in the past. The use of the systematic approach for offset determination coupled with a robust axial dispersion correction offers the potential for completely reconciling the molecular weight results obtained from the three available methods of molecular weight determination in triple detector GPC. |
| doi_str_mv | 10.1002/masy.201300029 |
| format | Article |
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The application of the systematic approach during detector offset determination in triple detector GPC polymer analysis has been shown to result in improvements in terms of the variations observed among the methods for molecular weight distribution determination. More importantly, the remaining, reduced variations are theoretically consistent with axial dispersion corrections proposed in the past. The use of the systematic approach for offset determination coupled with a robust axial dispersion correction offers the potential for completely reconciling the molecular weight results obtained from the three available methods of molecular weight determination in triple detector GPC.</description><identifier>ISSN: 1022-1360</identifier><identifier>EISSN: 1521-3900</identifier><identifier>DOI: 10.1002/masy.201300029</identifier><language>eng</language><publisher>Blackwell Publishing Ltd</publisher><subject>axial dispersion ; band broadening ; Coupling (molecular) ; Data processing ; Dispersions ; gel permeation chromatography ; GPC ; intrinsic viscosity ; LALLS ; low angel laser light scattering ; Molecular weight ; Molecular weight distribution ; Offsets ; SEC ; size exclusion chromatography</subject><ispartof>Macromolecular symposia., 2013-08, Vol.330 (1), p.53-62</ispartof><rights>2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fmasy.201300029$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fmasy.201300029$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Yau, Wallace</creatorcontrib><creatorcontrib>Brown, Ray</creatorcontrib><creatorcontrib>Tyler, Phillip</creatorcontrib><creatorcontrib>Huang, Tianzi</creatorcontrib><creatorcontrib>Cong, Rongjuan</creatorcontrib><creatorcontrib>Klinker, Chanda</creatorcontrib><creatorcontrib>Hazlitt, Lonnie</creatorcontrib><title>A "Systematic Approach" to TD-GPC Data Processing with Band Broadening Correction</title><title>Macromolecular symposia.</title><addtitle>Macromol. Symp</addtitle><description>Summary
The application of the systematic approach during detector offset determination in triple detector GPC polymer analysis has been shown to result in improvements in terms of the variations observed among the methods for molecular weight distribution determination. More importantly, the remaining, reduced variations are theoretically consistent with axial dispersion corrections proposed in the past. The use of the systematic approach for offset determination coupled with a robust axial dispersion correction offers the potential for completely reconciling the molecular weight results obtained from the three available methods of molecular weight determination in triple detector GPC.</description><subject>axial dispersion</subject><subject>band broadening</subject><subject>Coupling (molecular)</subject><subject>Data processing</subject><subject>Dispersions</subject><subject>gel permeation chromatography</subject><subject>GPC</subject><subject>intrinsic viscosity</subject><subject>LALLS</subject><subject>low angel laser light scattering</subject><subject>Molecular weight</subject><subject>Molecular weight distribution</subject><subject>Offsets</subject><subject>SEC</subject><subject>size exclusion chromatography</subject><issn>1022-1360</issn><issn>1521-3900</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNo9kM9PwjAUxxujiYhePTecvAzbdVvX45iKRlQIGCOXpu06qO4HriO4_94SDKf3vi_f78t7HwCuMRpihPzbUthu6CNMkFPsBPRw6GOPMIROXY9838MkQufgwtovZ2GM4h6YJXAw72yrS9EaBZPNpqmFWg9gW8PFnTeepvBOtAJOm1ppa021gjvTruFIVBkcOW-mq_0wrZtGq9bU1SU4y0Vh9dV_7YP3h_tF-uhN3sZPaTLxVgQT5ikS55hmiAqpYhXTTFLtM5lHYUxEjmSkFAkjFQVaYoERkYTIIA9zxLAWWErSBzeHve7in622LS-NVbooRKXrreU48t2TIWLUWdnBujOF7vimMaVoOo4R34Pje3D8CI6_JPPPo3JZ75A1DtLvMSuabx5RQkP-8TrmyyB4Xk7IjGPyBy22cpc</recordid><startdate>201308</startdate><enddate>201308</enddate><creator>Yau, Wallace</creator><creator>Brown, Ray</creator><creator>Tyler, Phillip</creator><creator>Huang, Tianzi</creator><creator>Cong, Rongjuan</creator><creator>Klinker, Chanda</creator><creator>Hazlitt, Lonnie</creator><general>Blackwell Publishing Ltd</general><scope>BSCLL</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>201308</creationdate><title>A "Systematic Approach" to TD-GPC Data Processing with Band Broadening Correction</title><author>Yau, Wallace ; Brown, Ray ; Tyler, Phillip ; Huang, Tianzi ; Cong, Rongjuan ; Klinker, Chanda ; Hazlitt, Lonnie</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-g3139-c38f17d07abc8c87db7e29bf6583af0b6cc356c64eb1a103b33b4f5f091ea1bb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>axial dispersion</topic><topic>band broadening</topic><topic>Coupling (molecular)</topic><topic>Data processing</topic><topic>Dispersions</topic><topic>gel permeation chromatography</topic><topic>GPC</topic><topic>intrinsic viscosity</topic><topic>LALLS</topic><topic>low angel laser light scattering</topic><topic>Molecular weight</topic><topic>Molecular weight distribution</topic><topic>Offsets</topic><topic>SEC</topic><topic>size exclusion chromatography</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yau, Wallace</creatorcontrib><creatorcontrib>Brown, Ray</creatorcontrib><creatorcontrib>Tyler, Phillip</creatorcontrib><creatorcontrib>Huang, Tianzi</creatorcontrib><creatorcontrib>Cong, Rongjuan</creatorcontrib><creatorcontrib>Klinker, Chanda</creatorcontrib><creatorcontrib>Hazlitt, Lonnie</creatorcontrib><collection>Istex</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Macromolecular symposia.</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yau, Wallace</au><au>Brown, Ray</au><au>Tyler, Phillip</au><au>Huang, Tianzi</au><au>Cong, Rongjuan</au><au>Klinker, Chanda</au><au>Hazlitt, Lonnie</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A "Systematic Approach" to TD-GPC Data Processing with Band Broadening Correction</atitle><jtitle>Macromolecular symposia.</jtitle><addtitle>Macromol. Symp</addtitle><date>2013-08</date><risdate>2013</risdate><volume>330</volume><issue>1</issue><spage>53</spage><epage>62</epage><pages>53-62</pages><issn>1022-1360</issn><eissn>1521-3900</eissn><abstract>Summary
The application of the systematic approach during detector offset determination in triple detector GPC polymer analysis has been shown to result in improvements in terms of the variations observed among the methods for molecular weight distribution determination. More importantly, the remaining, reduced variations are theoretically consistent with axial dispersion corrections proposed in the past. The use of the systematic approach for offset determination coupled with a robust axial dispersion correction offers the potential for completely reconciling the molecular weight results obtained from the three available methods of molecular weight determination in triple detector GPC.</abstract><pub>Blackwell Publishing Ltd</pub><doi>10.1002/masy.201300029</doi><tpages>10</tpages></addata></record> |
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| ispartof | Macromolecular symposia., 2013-08, Vol.330 (1), p.53-62 |
| issn | 1022-1360 1521-3900 |
| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | axial dispersion band broadening Coupling (molecular) Data processing Dispersions gel permeation chromatography GPC intrinsic viscosity LALLS low angel laser light scattering Molecular weight Molecular weight distribution Offsets SEC size exclusion chromatography |
| title | A "Systematic Approach" to TD-GPC Data Processing with Band Broadening Correction |
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