Ring Opening Polymerization of Organic Carbonates Using CO sub(2) - Carbene Adducts as Effective Organo Catalyst

In this study we successfully synthesized Poly(trimethylene carbonate) (PTMC) through carbene-catalysed ring opening polymerization. The use of CO sub(2)-adducts decreases the air and moisture sensitivity of the carbene and improves the controllability of the reaction. The carbene is freed through d...

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Veröffentlicht in:	Macromolecular symposia. 2013-12, Vol.334 (1), p.92-97
Hauptverfasser:	Reitz, A, Wilhelm, R, Kuckling, D
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbenes Carbon dioxide Carbonates Controllability Heating Ring opening polymerization Solvents Synthesis
Online-Zugang:	Volltext
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