Peptide-catalyzed kinetic resolution of planar-chiral metallocenes

Kinetic resolution of racemic planar-chiral metallocenes was performed through the conjugate addition of a nucleophile to the enal part of substrates. While no enantiomeric discrimination was found with low-molecular-weight organocatalysts, a properly designed resin-supported peptide catalyzed the r...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2014-01, Vol.50 (58), p.7893-7896
Hauptverfasser:	Akiyama, Midori, Akagawa, Kengo, Seino, Hidetake, Kudo, Kazuaki
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Conjugates Discrimination Kinetics Metallocenes Nucleophiles Organometallic Compounds - chemistry Peptides Peptides - chemistry Reaction kinetics Stereoisomerism
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