Molecular Bridge Enables Anomalous Enhancement in Thermal Transport across Hard-Soft Material Interfaces
Conventional wisdom tells us that interfacial thermal transport is more efficient when the interface adhesion energy is enhanced. In this study, it is demonstrated that molecular bridges consisting of small molecules chemically absorbed on solid surfaces can enhance the thermal transport across hard...
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Veröffentlicht in: | Advanced materials (Weinheim) 2014-09, Vol.26 (35), p.6093-6099 |
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container_title | Advanced materials (Weinheim) |
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creator | Sun, Fangyuan Zhang, Teng Jobbins, Matthew M. Guo, Zhi Zhang, Xueqiang Zheng, Zhongli Tang, Dawei Ptasinska, Sylwia Luo, Tengfei |
description | Conventional wisdom tells us that interfacial thermal transport is more efficient when the interface adhesion energy is enhanced. In this study, it is demonstrated that molecular bridges consisting of small molecules chemically absorbed on solid surfaces can enhance the thermal transport across hard–soft material interfaces by as much as 7‐fold despite a significant decrease in the interface adhesion energy. This work provides an unconventional strategy to improve thermal transport across material interfaces. |
doi_str_mv | 10.1002/adma.201400954 |
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In this study, it is demonstrated that molecular bridges consisting of small molecules chemically absorbed on solid surfaces can enhance the thermal transport across hard–soft material interfaces by as much as 7‐fold despite a significant decrease in the interface adhesion energy. This work provides an unconventional strategy to improve thermal transport across material interfaces.</description><identifier>ISSN: 0935-9648</identifier><identifier>EISSN: 1521-4095</identifier><identifier>DOI: 10.1002/adma.201400954</identifier><identifier>PMID: 24841621</identifier><language>eng</language><publisher>Germany: Blackwell Publishing Ltd</publisher><subject>Adhesion ; Bridges (structures) ; Energy management ; interface ; nanocomposite ; polymer ; self-assembled monolayer ; Solid surfaces ; Strategy ; thermal transport ; Transport</subject><ispartof>Advanced materials (Weinheim), 2014-09, Vol.26 (35), p.6093-6099</ispartof><rights>2014 WILEY‐VCH Verlag GmbH & Co. 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Mater</addtitle><description>Conventional wisdom tells us that interfacial thermal transport is more efficient when the interface adhesion energy is enhanced. In this study, it is demonstrated that molecular bridges consisting of small molecules chemically absorbed on solid surfaces can enhance the thermal transport across hard–soft material interfaces by as much as 7‐fold despite a significant decrease in the interface adhesion energy. 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source | Wiley Online Library Journals Frontfile Complete |
subjects | Adhesion Bridges (structures) Energy management interface nanocomposite polymer self-assembled monolayer Solid surfaces Strategy thermal transport Transport |
title | Molecular Bridge Enables Anomalous Enhancement in Thermal Transport across Hard-Soft Material Interfaces |
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