Molecular Bridge Enables Anomalous Enhancement in Thermal Transport across Hard-Soft Material Interfaces

Conventional wisdom tells us that interfacial thermal transport is more efficient when the interface adhesion energy is enhanced. In this study, it is demonstrated that molecular bridges consisting of small molecules chemically absorbed on solid surfaces can enhance the thermal transport across hard...

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Veröffentlicht in:Advanced materials (Weinheim) 2014-09, Vol.26 (35), p.6093-6099
Hauptverfasser: Sun, Fangyuan, Zhang, Teng, Jobbins, Matthew M., Guo, Zhi, Zhang, Xueqiang, Zheng, Zhongli, Tang, Dawei, Ptasinska, Sylwia, Luo, Tengfei
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container_end_page 6099
container_issue 35
container_start_page 6093
container_title Advanced materials (Weinheim)
container_volume 26
creator Sun, Fangyuan
Zhang, Teng
Jobbins, Matthew M.
Guo, Zhi
Zhang, Xueqiang
Zheng, Zhongli
Tang, Dawei
Ptasinska, Sylwia
Luo, Tengfei
description Conventional wisdom tells us that interfacial thermal transport is more efficient when the interface adhesion energy is enhanced. In this study, it is demonstrated that molecular bridges consisting of small molecules chemically absorbed on solid surfaces can enhance the thermal transport across hard–soft material interfaces by as much as 7‐fold despite a significant decrease in the interface adhesion energy. This work provides an unconventional strategy to improve thermal transport across material interfaces.
doi_str_mv 10.1002/adma.201400954
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source Wiley Online Library Journals Frontfile Complete
subjects Adhesion
Bridges (structures)
Energy management
interface
nanocomposite
polymer
self-assembled monolayer
Solid surfaces
Strategy
thermal transport
Transport
title Molecular Bridge Enables Anomalous Enhancement in Thermal Transport across Hard-Soft Material Interfaces
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