New iminophosphine-Ru(II) complexes and their application in hydrogenation and transfer hydrogenation
Ruthenium complexes [RuCl2L2] were prepared by treating [RuCl2(p‐cymene)]2 with structurally similar N‐(2‐(diphenylphosphino)benzylidene)‐3‐methylpyridin‐2‐amine, 4‐(2‐(diphenylphosphino)benzylideneamino)‐3‐methylphenol and 4‐(2‐(2‐(diphenylphosphino)benzylideneamino)ethyl)phenol refluxed in toluene...
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| Veröffentlicht in: | Applied organometallic chemistry 2014-10, Vol.28 (10), p.768-772 |
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| container_title | Applied organometallic chemistry |
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| creator | Keleş, Mustafa Şahinoğlu, Coşkun Emir, Duygu M. Mart, Mehmet |
| description | Ruthenium complexes [RuCl2L2] were prepared by treating [RuCl2(p‐cymene)]2 with structurally similar N‐(2‐(diphenylphosphino)benzylidene)‐3‐methylpyridin‐2‐amine, 4‐(2‐(diphenylphosphino)benzylideneamino)‐3‐methylphenol and 4‐(2‐(2‐(diphenylphosphino)benzylideneamino)ethyl)phenol refluxed in toluene. These complexes were used as catalysts for the transfer hydrogenation of acetophenones in 2‐propanol and for the direct hydrogenation of styrenes under hydrogen pressure. The results of the catalytic studies provide evidence that these complexes function as excellent catalysts for hydrogenation and transfer hydrogenation. Copyright © 2014 John Wiley & Sons, Ltd.
Iminophosphine–Ru(II) complexes have been synthesized, characterized and tested as catalysts for the transfer hydrogenation of acetophenones in 2‐propanol and for the direct hydrogenation of styrenes under hydrogen pressure. The studies demonstrate that these complexes act as excellent catalysts for hydrogenation and transfer hydrogenation. |
| doi_str_mv | 10.1002/aoc.3196 |
| format | Article |
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Iminophosphine–Ru(II) complexes have been synthesized, characterized and tested as catalysts for the transfer hydrogenation of acetophenones in 2‐propanol and for the direct hydrogenation of styrenes under hydrogen pressure. The studies demonstrate that these complexes act as excellent catalysts for hydrogenation and transfer hydrogenation.</description><identifier>ISSN: 0268-2605</identifier><identifier>EISSN: 1099-0739</identifier><identifier>DOI: 10.1002/aoc.3196</identifier><language>eng</language><publisher>Blackwell Publishing Ltd</publisher><subject>Acetophenone ; Catalysis ; Catalysts ; Hydrogen storage ; Hydrogenation ; iminophosphine ; Ruthenium ; ruthenium complexes ; Styrenes ; Toluene ; transfer hydrogenation</subject><ispartof>Applied organometallic chemistry, 2014-10, Vol.28 (10), p.768-772</ispartof><rights>Copyright © 2014 John Wiley & Sons, Ltd.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4066-33ab1833d7b60f79b50b50cc04cc39da174581d52eb4daebf61ad93166b99f03</citedby><cites>FETCH-LOGICAL-c4066-33ab1833d7b60f79b50b50cc04cc39da174581d52eb4daebf61ad93166b99f03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Faoc.3196$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Faoc.3196$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Keleş, Mustafa</creatorcontrib><creatorcontrib>Şahinoğlu, Coşkun</creatorcontrib><creatorcontrib>Emir, Duygu M.</creatorcontrib><creatorcontrib>Mart, Mehmet</creatorcontrib><title>New iminophosphine-Ru(II) complexes and their application in hydrogenation and transfer hydrogenation</title><title>Applied organometallic chemistry</title><addtitle>Appl. Organometal. Chem</addtitle><description>Ruthenium complexes [RuCl2L2] were prepared by treating [RuCl2(p‐cymene)]2 with structurally similar N‐(2‐(diphenylphosphino)benzylidene)‐3‐methylpyridin‐2‐amine, 4‐(2‐(diphenylphosphino)benzylideneamino)‐3‐methylphenol and 4‐(2‐(2‐(diphenylphosphino)benzylideneamino)ethyl)phenol refluxed in toluene. These complexes were used as catalysts for the transfer hydrogenation of acetophenones in 2‐propanol and for the direct hydrogenation of styrenes under hydrogen pressure. The results of the catalytic studies provide evidence that these complexes function as excellent catalysts for hydrogenation and transfer hydrogenation. Copyright © 2014 John Wiley & Sons, Ltd.
Iminophosphine–Ru(II) complexes have been synthesized, characterized and tested as catalysts for the transfer hydrogenation of acetophenones in 2‐propanol and for the direct hydrogenation of styrenes under hydrogen pressure. The studies demonstrate that these complexes act as excellent catalysts for hydrogenation and transfer hydrogenation.</description><subject>Acetophenone</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Hydrogen storage</subject><subject>Hydrogenation</subject><subject>iminophosphine</subject><subject>Ruthenium</subject><subject>ruthenium complexes</subject><subject>Styrenes</subject><subject>Toluene</subject><subject>transfer hydrogenation</subject><issn>0268-2605</issn><issn>1099-0739</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNp10FFLAkEQB_AlCjIL-gj3aA9ns7d3u-6jSJlgKiH0uOztzeXWeXvtKuq3TzMKH4KBgfn_mIc_IbcUuhQgudfOdBmV_Iy0KEgZg2DynLQg4b044ZBdkqsQ3gFAcpq2CE5wE9mlrV2zcKFZ2Brjl3VnNLqLjFs2FW4xRLouotUCrY9001TW6JV1dWTraLErvHvD-nj4Zl7XoUR_Gl2Ti1JXAW9-dpvMHx_mg6d4PB2OBv1xbFLgPGZM57THWCFyDqWQeQb7MQZSY5gsNBVp1qNFlmCeFhrzklNdSEY5z6UsgbVJ5_i28e5zjWGlljYYrCpdo1sHRXkCIARn6R813oXgsVSNt0vtd4qCOhSp9kWqQ5F7Gh_pxla4-9ep_nRw6m1Y4fbXa_-huGAiU6-ToXoW8xmbSap67Auap4Sa</recordid><startdate>201410</startdate><enddate>201410</enddate><creator>Keleş, Mustafa</creator><creator>Şahinoğlu, Coşkun</creator><creator>Emir, Duygu M.</creator><creator>Mart, Mehmet</creator><general>Blackwell Publishing Ltd</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>201410</creationdate><title>New iminophosphine-Ru(II) complexes and their application in hydrogenation and transfer hydrogenation</title><author>Keleş, Mustafa ; Şahinoğlu, Coşkun ; Emir, Duygu M. ; Mart, Mehmet</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4066-33ab1833d7b60f79b50b50cc04cc39da174581d52eb4daebf61ad93166b99f03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Acetophenone</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Hydrogen storage</topic><topic>Hydrogenation</topic><topic>iminophosphine</topic><topic>Ruthenium</topic><topic>ruthenium complexes</topic><topic>Styrenes</topic><topic>Toluene</topic><topic>transfer hydrogenation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Keleş, Mustafa</creatorcontrib><creatorcontrib>Şahinoğlu, Coşkun</creatorcontrib><creatorcontrib>Emir, Duygu M.</creatorcontrib><creatorcontrib>Mart, Mehmet</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied organometallic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Keleş, Mustafa</au><au>Şahinoğlu, Coşkun</au><au>Emir, Duygu M.</au><au>Mart, Mehmet</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>New iminophosphine-Ru(II) complexes and their application in hydrogenation and transfer hydrogenation</atitle><jtitle>Applied organometallic chemistry</jtitle><addtitle>Appl. Organometal. Chem</addtitle><date>2014-10</date><risdate>2014</risdate><volume>28</volume><issue>10</issue><spage>768</spage><epage>772</epage><pages>768-772</pages><issn>0268-2605</issn><eissn>1099-0739</eissn><abstract>Ruthenium complexes [RuCl2L2] were prepared by treating [RuCl2(p‐cymene)]2 with structurally similar N‐(2‐(diphenylphosphino)benzylidene)‐3‐methylpyridin‐2‐amine, 4‐(2‐(diphenylphosphino)benzylideneamino)‐3‐methylphenol and 4‐(2‐(2‐(diphenylphosphino)benzylideneamino)ethyl)phenol refluxed in toluene. These complexes were used as catalysts for the transfer hydrogenation of acetophenones in 2‐propanol and for the direct hydrogenation of styrenes under hydrogen pressure. The results of the catalytic studies provide evidence that these complexes function as excellent catalysts for hydrogenation and transfer hydrogenation. Copyright © 2014 John Wiley & Sons, Ltd.
Iminophosphine–Ru(II) complexes have been synthesized, characterized and tested as catalysts for the transfer hydrogenation of acetophenones in 2‐propanol and for the direct hydrogenation of styrenes under hydrogen pressure. The studies demonstrate that these complexes act as excellent catalysts for hydrogenation and transfer hydrogenation.</abstract><pub>Blackwell Publishing Ltd</pub><doi>10.1002/aoc.3196</doi><tpages>5</tpages></addata></record> |
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| subjects | Acetophenone Catalysis Catalysts Hydrogen storage Hydrogenation iminophosphine Ruthenium ruthenium complexes Styrenes Toluene transfer hydrogenation |
| title | New iminophosphine-Ru(II) complexes and their application in hydrogenation and transfer hydrogenation |
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