A General Strategy to Layered Transition-Metal Hydroxide Nanocones: Tuning the Composition for High Electrochemical Performance
A general and facile strategy for the synthesis of a large family of monometallic (Co, Ni) and bimetallic (Co‐Ni, Co‐Cu and Co‐Zn) hydroxide nanocones (NCs) intercalated with DS ions is demonstrated. The basal spacing of the NCs can be varied by adjusting the intercalated DS amount. Especially, elec...
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| Veröffentlicht in: | Advanced materials (Weinheim) 2012-04, Vol.24 (16), p.2148-2153 |
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| container_title | Advanced materials (Weinheim) |
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| creator | Liu, Xiaohe Ma, Renzhi Bando, Yoshio Sasaki, Takayoshi |
| description | A general and facile strategy for the synthesis of a large family of monometallic (Co, Ni) and bimetallic (Co‐Ni, Co‐Cu and Co‐Zn) hydroxide nanocones (NCs) intercalated with DS ions is demonstrated. The basal spacing of the NCs can be varied by adjusting the intercalated DS amount. Especially, electrochemical characterizations reveal that bimetallic Co‐Ni hydroxide NCs have a higher specific capacitance than their monometallic counterpart. These results suggest the importance of rational designing layered hydroxide NCs with tuned transition‐metal composition for high‐performance energy storage devices. |
| doi_str_mv | 10.1002/adma.201104753 |
| format | Article |
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The basal spacing of the NCs can be varied by adjusting the intercalated DS amount. Especially, electrochemical characterizations reveal that bimetallic Co‐Ni hydroxide NCs have a higher specific capacitance than their monometallic counterpart. These results suggest the importance of rational designing layered hydroxide NCs with tuned transition‐metal composition for high‐performance energy storage devices.</description><identifier>ISSN: 0935-9648</identifier><identifier>EISSN: 1521-4095</identifier><identifier>DOI: 10.1002/adma.201104753</identifier><identifier>PMID: 22447334</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Bimetals ; Electrochemical analysis ; electrochemical performance ; Electrochemistry ; Energy storage ; Hydroxides ; Hydroxides - chemistry ; layered nanomaterials ; nanocones ; nanosheets ; Nanostructure ; Nanostructures - chemistry ; Nanotechnology - methods ; Nickel ; Strategy ; Transition Elements - chemistry ; transition-metal hydroxide ; Tuning ; Urea - chemistry</subject><ispartof>Advanced materials (Weinheim), 2012-04, Vol.24 (16), p.2148-2153</ispartof><rights>Copyright © 2012 WILEY‐VCH Verlag GmbH & Co. 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KGaA, Weinheim.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4823-601cd67391dae64a1bb0de1500f69780af374b4233b3a1cbdd7b15cf64e36abb3</citedby><cites>FETCH-LOGICAL-c4823-601cd67391dae64a1bb0de1500f69780af374b4233b3a1cbdd7b15cf64e36abb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fadma.201104753$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fadma.201104753$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/22447334$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Liu, Xiaohe</creatorcontrib><creatorcontrib>Ma, Renzhi</creatorcontrib><creatorcontrib>Bando, Yoshio</creatorcontrib><creatorcontrib>Sasaki, Takayoshi</creatorcontrib><title>A General Strategy to Layered Transition-Metal Hydroxide Nanocones: Tuning the Composition for High Electrochemical Performance</title><title>Advanced materials (Weinheim)</title><addtitle>Adv. Mater</addtitle><description>A general and facile strategy for the synthesis of a large family of monometallic (Co, Ni) and bimetallic (Co‐Ni, Co‐Cu and Co‐Zn) hydroxide nanocones (NCs) intercalated with DS ions is demonstrated. The basal spacing of the NCs can be varied by adjusting the intercalated DS amount. Especially, electrochemical characterizations reveal that bimetallic Co‐Ni hydroxide NCs have a higher specific capacitance than their monometallic counterpart. These results suggest the importance of rational designing layered hydroxide NCs with tuned transition‐metal composition for high‐performance energy storage devices.</description><subject>Bimetals</subject><subject>Electrochemical analysis</subject><subject>electrochemical performance</subject><subject>Electrochemistry</subject><subject>Energy storage</subject><subject>Hydroxides</subject><subject>Hydroxides - chemistry</subject><subject>layered nanomaterials</subject><subject>nanocones</subject><subject>nanosheets</subject><subject>Nanostructure</subject><subject>Nanostructures - chemistry</subject><subject>Nanotechnology - methods</subject><subject>Nickel</subject><subject>Strategy</subject><subject>Transition Elements - chemistry</subject><subject>transition-metal hydroxide</subject><subject>Tuning</subject><subject>Urea - chemistry</subject><issn>0935-9648</issn><issn>1521-4095</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkb9z0zAYhnUcPRoKKyOnkcVBsn7YZguhTbhLW66YY9TJ0udEYFtBco566r9eg9tct07f8D3vM7wvQu8omVNC0o_atnqeEkoJzwR7gWZUpDThpBAv0YwUTCSF5Pkpeh3jL0JIIYl8hU7TlPOMMT5Ddwu8gg6CbvD3PugetgPuPd7oAQJYXAbdRdc73yWX0I_QerDB3zoL-Ep33vgO4idcHjrXbXG_A7z07d5PCVz7gNduu8PnDZg-eLOD1plR8g3C-Gt1Z-ANOql1E-Htwz1DPy7Oy-U62Vyvvi4Xm8TwPGWJJNRYmbGCWg2Sa1pVxAIVhNSyyHKia5bxiqeMVUxTU1mbVVSYWnJgUlcVO0MfJu8--D8HiL1qXTTQNLoDf4iKypQQkUvKnkfH3gXJRSpHdD6hJvgYA9RqH1yrwzBC_zn1bx913GcMvH9wH6oW7BF_HGQEign46xoYntGpxZfLxVN5MmVd7OH2mNXhtxqry4T6ebVS5c0Fz-nNZ1Wye8EtrKU</recordid><startdate>20120424</startdate><enddate>20120424</enddate><creator>Liu, Xiaohe</creator><creator>Ma, Renzhi</creator><creator>Bando, Yoshio</creator><creator>Sasaki, Takayoshi</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20120424</creationdate><title>A General Strategy to Layered Transition-Metal Hydroxide Nanocones: Tuning the Composition for High Electrochemical Performance</title><author>Liu, Xiaohe ; Ma, Renzhi ; Bando, Yoshio ; Sasaki, Takayoshi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4823-601cd67391dae64a1bb0de1500f69780af374b4233b3a1cbdd7b15cf64e36abb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Bimetals</topic><topic>Electrochemical analysis</topic><topic>electrochemical performance</topic><topic>Electrochemistry</topic><topic>Energy storage</topic><topic>Hydroxides</topic><topic>Hydroxides - chemistry</topic><topic>layered nanomaterials</topic><topic>nanocones</topic><topic>nanosheets</topic><topic>Nanostructure</topic><topic>Nanostructures - chemistry</topic><topic>Nanotechnology - methods</topic><topic>Nickel</topic><topic>Strategy</topic><topic>Transition Elements - chemistry</topic><topic>transition-metal hydroxide</topic><topic>Tuning</topic><topic>Urea - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Xiaohe</creatorcontrib><creatorcontrib>Ma, Renzhi</creatorcontrib><creatorcontrib>Bando, Yoshio</creatorcontrib><creatorcontrib>Sasaki, Takayoshi</creatorcontrib><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Advanced materials (Weinheim)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Xiaohe</au><au>Ma, Renzhi</au><au>Bando, Yoshio</au><au>Sasaki, Takayoshi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A General Strategy to Layered Transition-Metal Hydroxide Nanocones: Tuning the Composition for High Electrochemical Performance</atitle><jtitle>Advanced materials (Weinheim)</jtitle><addtitle>Adv. Mater</addtitle><date>2012-04-24</date><risdate>2012</risdate><volume>24</volume><issue>16</issue><spage>2148</spage><epage>2153</epage><pages>2148-2153</pages><issn>0935-9648</issn><eissn>1521-4095</eissn><abstract>A general and facile strategy for the synthesis of a large family of monometallic (Co, Ni) and bimetallic (Co‐Ni, Co‐Cu and Co‐Zn) hydroxide nanocones (NCs) intercalated with DS ions is demonstrated. The basal spacing of the NCs can be varied by adjusting the intercalated DS amount. Especially, electrochemical characterizations reveal that bimetallic Co‐Ni hydroxide NCs have a higher specific capacitance than their monometallic counterpart. These results suggest the importance of rational designing layered hydroxide NCs with tuned transition‐metal composition for high‐performance energy storage devices.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>22447334</pmid><doi>10.1002/adma.201104753</doi><tpages>6</tpages></addata></record> |
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| ispartof | Advanced materials (Weinheim), 2012-04, Vol.24 (16), p.2148-2153 |
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| source | Wiley-Blackwell Journals; MEDLINE |
| subjects | Bimetals Electrochemical analysis electrochemical performance Electrochemistry Energy storage Hydroxides Hydroxides - chemistry layered nanomaterials nanocones nanosheets Nanostructure Nanostructures - chemistry Nanotechnology - methods Nickel Strategy Transition Elements - chemistry transition-metal hydroxide Tuning Urea - chemistry |
| title | A General Strategy to Layered Transition-Metal Hydroxide Nanocones: Tuning the Composition for High Electrochemical Performance |
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