Electrodeposition of thick palladium coatings from a palladium(II)-containing ionic liquid

The first palladium-containing Liquid Metal Salts (LMS) are presented and shown to be suitable electrolytes for the electrodeposition of palladium. The homoleptic LMS of formula [Pd(MeIm)4][Tf2N]2 or [Pd(EtIm)4][Tf2N]2 (MeIm = N-methylimidazole, EtIm = N-ethylimidazole) have higher melting points th...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2014-01, Vol.50 (71), p.10248-10250
Hauptverfasser:	Schaltin, Stijn, Brooks, Neil R, Sniekers, Jeroen, Van Meervelt, Luc, Binnemans, Koen, Fransaer, Jan
Format:	Artikel
Sprache:	eng
Schlagworte:	Coatings Deposition Electrodeposition Electrolytes Ionic liquids Liquid metals Melting points Palladium
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

container_end_page	10250
container_issue	71
container_start_page	10248
container_title	Chemical communications (Cambridge, England)
container_volume	50
creator	Schaltin, Stijn Brooks, Neil R Sniekers, Jeroen Van Meervelt, Luc Binnemans, Koen Fransaer, Jan
description	The first palladium-containing Liquid Metal Salts (LMS) are presented and shown to be suitable electrolytes for the electrodeposition of palladium. The homoleptic LMS of formula [Pd(MeIm)4][Tf2N]2 or [Pd(EtIm)4][Tf2N]2 (MeIm = N-methylimidazole, EtIm = N-ethylimidazole) have higher melting points than the heteroleptic [Pd(MeIm)2(EtIm)2][Tf2N]2, which is proved to be the most promising electrolyte. The deposition reaction in these LMS was found to be irreversible but smooth and dense palladium layers can be deposited that are crack-free up to a thickness of 10 microns.
doi_str_mv	10.1039/c4cc04079a
format	Article
fullrecord	<record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1620055490</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1552368597</sourcerecordid><originalsourceid>FETCH-LOGICAL-c422t-47a5b45bdea50aee6476cc4db7c4bda3d8e133f9c275c3ca59a0ade9828539313</originalsourceid><addsrcrecordid>eNqFkDFPwzAQhS0EoqWw8AOQx4IUsGM7jscqKlCpEgtIiCVyzg4YkjiNk4F_T0oLjNxyJ913T-8eQueUXFPC1A1wAMKJVPoATSlLeCR4-ny4nYWKJONigk5CeCdjUZEeo0ksiOBKJlP0sqws9J03tvXB9c432Je4f3PwgVtdVdq4ocbgde-a14DLztdY_23mq9VlBL7ptWtGAI_3DnDlNoMzp-io1FWwZ_s-Q0-3y8fsPlo_3K2yxToCHsd9xKUWBReFsVoQbW3CZQLATSGBF0Yzk1rKWKkglgIYaKE00caqNE4FU4yyGZrvdNvObwYb-rx2AezosLF-CDlNYkLE-C_5HxUiZkkqlBzRqx0KnQ-hs2Xedq7W3WdOSb6NPc94ln3Hvhjhi73uUNTW_KI_ObMvO6B96w</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1552368597</pqid></control><display><type>article</type><title>Electrodeposition of thick palladium coatings from a palladium(II)-containing ionic liquid</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Schaltin, Stijn ; Brooks, Neil R ; Sniekers, Jeroen ; Van Meervelt, Luc ; Binnemans, Koen ; Fransaer, Jan</creator><creatorcontrib>Schaltin, Stijn ; Brooks, Neil R ; Sniekers, Jeroen ; Van Meervelt, Luc ; Binnemans, Koen ; Fransaer, Jan</creatorcontrib><description>The first palladium-containing Liquid Metal Salts (LMS) are presented and shown to be suitable electrolytes for the electrodeposition of palladium. The homoleptic LMS of formula [Pd(MeIm)4][Tf2N]2 or [Pd(EtIm)4][Tf2N]2 (MeIm = N-methylimidazole, EtIm = N-ethylimidazole) have higher melting points than the heteroleptic [Pd(MeIm)2(EtIm)2][Tf2N]2, which is proved to be the most promising electrolyte. The deposition reaction in these LMS was found to be irreversible but smooth and dense palladium layers can be deposited that are crack-free up to a thickness of 10 microns.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c4cc04079a</identifier><identifier>PMID: 25054976</identifier><language>eng</language><publisher>England</publisher><subject>Coatings ; Deposition ; Electrodeposition ; Electrolytes ; Ionic liquids ; Liquid metals ; Melting points ; Palladium</subject><ispartof>Chemical communications (Cambridge, England), 2014-01, Vol.50 (71), p.10248-10250</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c422t-47a5b45bdea50aee6476cc4db7c4bda3d8e133f9c275c3ca59a0ade9828539313</citedby><cites>FETCH-LOGICAL-c422t-47a5b45bdea50aee6476cc4db7c4bda3d8e133f9c275c3ca59a0ade9828539313</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/25054976$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Schaltin, Stijn</creatorcontrib><creatorcontrib>Brooks, Neil R</creatorcontrib><creatorcontrib>Sniekers, Jeroen</creatorcontrib><creatorcontrib>Van Meervelt, Luc</creatorcontrib><creatorcontrib>Binnemans, Koen</creatorcontrib><creatorcontrib>Fransaer, Jan</creatorcontrib><title>Electrodeposition of thick palladium coatings from a palladium(II)-containing ionic liquid</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>The first palladium-containing Liquid Metal Salts (LMS) are presented and shown to be suitable electrolytes for the electrodeposition of palladium. The homoleptic LMS of formula [Pd(MeIm)4][Tf2N]2 or [Pd(EtIm)4][Tf2N]2 (MeIm = N-methylimidazole, EtIm = N-ethylimidazole) have higher melting points than the heteroleptic [Pd(MeIm)2(EtIm)2][Tf2N]2, which is proved to be the most promising electrolyte. The deposition reaction in these LMS was found to be irreversible but smooth and dense palladium layers can be deposited that are crack-free up to a thickness of 10 microns.</description><subject>Coatings</subject><subject>Deposition</subject><subject>Electrodeposition</subject><subject>Electrolytes</subject><subject>Ionic liquids</subject><subject>Liquid metals</subject><subject>Melting points</subject><subject>Palladium</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqFkDFPwzAQhS0EoqWw8AOQx4IUsGM7jscqKlCpEgtIiCVyzg4YkjiNk4F_T0oLjNxyJ913T-8eQueUXFPC1A1wAMKJVPoATSlLeCR4-ny4nYWKJONigk5CeCdjUZEeo0ksiOBKJlP0sqws9J03tvXB9c432Je4f3PwgVtdVdq4ocbgde-a14DLztdY_23mq9VlBL7ptWtGAI_3DnDlNoMzp-io1FWwZ_s-Q0-3y8fsPlo_3K2yxToCHsd9xKUWBReFsVoQbW3CZQLATSGBF0Yzk1rKWKkglgIYaKE00caqNE4FU4yyGZrvdNvObwYb-rx2AezosLF-CDlNYkLE-C_5HxUiZkkqlBzRqx0KnQ-hs2Xedq7W3WdOSb6NPc94ln3Hvhjhi73uUNTW_KI_ObMvO6B96w</recordid><startdate>20140101</startdate><enddate>20140101</enddate><creator>Schaltin, Stijn</creator><creator>Brooks, Neil R</creator><creator>Sniekers, Jeroen</creator><creator>Van Meervelt, Luc</creator><creator>Binnemans, Koen</creator><creator>Fransaer, Jan</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SP</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20140101</creationdate><title>Electrodeposition of thick palladium coatings from a palladium(II)-containing ionic liquid</title><author>Schaltin, Stijn ; Brooks, Neil R ; Sniekers, Jeroen ; Van Meervelt, Luc ; Binnemans, Koen ; Fransaer, Jan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c422t-47a5b45bdea50aee6476cc4db7c4bda3d8e133f9c275c3ca59a0ade9828539313</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Coatings</topic><topic>Deposition</topic><topic>Electrodeposition</topic><topic>Electrolytes</topic><topic>Ionic liquids</topic><topic>Liquid metals</topic><topic>Melting points</topic><topic>Palladium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Schaltin, Stijn</creatorcontrib><creatorcontrib>Brooks, Neil R</creatorcontrib><creatorcontrib>Sniekers, Jeroen</creatorcontrib><creatorcontrib>Van Meervelt, Luc</creatorcontrib><creatorcontrib>Binnemans, Koen</creatorcontrib><creatorcontrib>Fransaer, Jan</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Schaltin, Stijn</au><au>Brooks, Neil R</au><au>Sniekers, Jeroen</au><au>Van Meervelt, Luc</au><au>Binnemans, Koen</au><au>Fransaer, Jan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrodeposition of thick palladium coatings from a palladium(II)-containing ionic liquid</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2014-01-01</date><risdate>2014</risdate><volume>50</volume><issue>71</issue><spage>10248</spage><epage>10250</epage><pages>10248-10250</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>The first palladium-containing Liquid Metal Salts (LMS) are presented and shown to be suitable electrolytes for the electrodeposition of palladium. The homoleptic LMS of formula [Pd(MeIm)4][Tf2N]2 or [Pd(EtIm)4][Tf2N]2 (MeIm = N-methylimidazole, EtIm = N-ethylimidazole) have higher melting points than the heteroleptic [Pd(MeIm)2(EtIm)2][Tf2N]2, which is proved to be the most promising electrolyte. The deposition reaction in these LMS was found to be irreversible but smooth and dense palladium layers can be deposited that are crack-free up to a thickness of 10 microns.</abstract><cop>England</cop><pmid>25054976</pmid><doi>10.1039/c4cc04079a</doi><tpages>3</tpages><oa>free_for_read</oa></addata></record>
fulltext	fulltext
identifier	ISSN: 1359-7345
ispartof	Chemical communications (Cambridge, England), 2014-01, Vol.50 (71), p.10248-10250
issn	1359-7345 1364-548X
language	eng
recordid	cdi_proquest_miscellaneous_1620055490
source	Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects	Coatings Deposition Electrodeposition Electrolytes Ionic liquids Liquid metals Melting points Palladium
title	Electrodeposition of thick palladium coatings from a palladium(II)-containing ionic liquid
url	https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-19T18%3A11%3A54IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Electrodeposition%20of%20thick%20palladium%20coatings%20from%20a%20palladium(II)-containing%20ionic%20liquid&rft.jtitle=Chemical%20communications%20(Cambridge,%20England)&rft.au=Schaltin,%20Stijn&rft.date=2014-01-01&rft.volume=50&rft.issue=71&rft.spage=10248&rft.epage=10250&rft.pages=10248-10250&rft.issn=1359-7345&rft.eissn=1364-548X&rft_id=info:doi/10.1039/c4cc04079a&rft_dat=%3Cproquest_cross%3E1552368597%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1552368597&rft_id=info:pmid/25054976&rfr_iscdi=true