Improvement of hydrothermal stability of zeolitic imidazolate frameworks

Improvement of hydrothermal stability of zeolitic imidazolate frameworks

The metal-organic framework ZIF-8, which undergoes hydrolysis under hydrothermal conditions, is endowed with high water-resistance after a shell-ligand-exchange-reaction. The stabilized ZIF-8 retains its structural characteristics with improved application performances in adsorption and membrane sep...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (80), p.9140-9142
Hauptverfasser: Liu, Xinlei, Li, Yanshuo, Ban, Yujie, Peng, Yuan, Jin, Hua, Bux, Helge, Xu, Longya, Caro, Jürgen, Yang, Weishen
Format: Artikel
Sprache:eng
Schlagworte:
Adsorption
Hydrolysis
Membranes
Performance enhancement
Separation
Stability
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Beschreibung
Zusammenfassung:The metal-organic framework ZIF-8, which undergoes hydrolysis under hydrothermal conditions, is endowed with high water-resistance after a shell-ligand-exchange-reaction. The stabilized ZIF-8 retains its structural characteristics with improved application performances in adsorption and membrane separation.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc45308a