Studies on electroless nickel boride coating on boron carbide particles

Ni-B alloy deposits were successfully formed over alkali surface treated boron carbide by electroless technique and the effects of processing parameters such as reduction bath pH, temperature and post-heat treatment were investigated. Microstructural studies show remarkable changes in structural mor...

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Veröffentlicht in:Surface engineering 2014-10, Vol.30 (10), p.702-708
Hauptverfasser: Deepa, J. P., Rajan, T. P. D., Pavithran, C., Pai, B. C.
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container_issue 10
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container_title Surface engineering
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creator Deepa, J. P.
Rajan, T. P. D.
Pavithran, C.
Pai, B. C.
description Ni-B alloy deposits were successfully formed over alkali surface treated boron carbide by electroless technique and the effects of processing parameters such as reduction bath pH, temperature and post-heat treatment were investigated. Microstructural studies show remarkable changes in structural morphology from mesh-like structure to platelet type Ni-B coating. The main Ni-B phases observed were NiB, Ni 2 B, Ni 3 B and Ni 4 B 3 . An effective Ni-B alloy coating with better surface characteristics was formed at pH 8 under 75°C reaction bath temperature in the presence of bath stabiliser. The post-heat treatment of Ni-B coated particles under varying bath reaction temperatures at 400°C showed remarkable Ni-B phase transformation from metastable NiB and Ni 2 B to stable crystalline Ni 3 B phase. The NiB coated particle shows lower particle-matrix interfacial reaction, better wettability and enhanced dispersion in aluminium composites compared to uncoated particles.
doi_str_mv 10.1179/1743294414Y.0000000279
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subjects Amorphous coating
Boron carbide
Coated particles
Coating
Electroless coating
Electroless plating
Interface reactions
Nickel
Nickel base alloys
Nickel boride
Phase transformation
Plating baths
Sodium borohydride
title Studies on electroless nickel boride coating on boron carbide particles
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