Supramolecular self-assembly and photovoltaic property of soluble fluorogallium phthalocyanine
Within the present work, two soluble phthalocyanine compounds, fluorogallium tetra- tert -butylphthalocyanine (ttbPcGaF) and its precursor hydroxygallium tetra- tert -butylphthalocyanine (ttbPcGaOH) were successfully synthesized. ttbPcGaF had a considerably stronger ability than that of ttbPcGaOH to...
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| Veröffentlicht in: | RSC advances 2014-01, Vol.4 (56), p.29485-29492 |
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| container_title | RSC advances |
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| creator | Zhang, Jian Li, Yaowen Wang, Laibing Fujiki, Michiya Li, Xiaopeng Zhang, Zhengbiao Zhang, Wei Zhou, Nianchen Zhu, Xiulin |
| description | Within the present work, two soluble phthalocyanine compounds, fluorogallium tetra-
tert
-butylphthalocyanine (ttbPcGaF) and its precursor hydroxygallium tetra-
tert
-butylphthalocyanine (ttbPcGaOH) were successfully synthesized. ttbPcGaF had a considerably stronger ability than that of ttbPcGaOH to self-organize into well-ordered one-dimensional (1D) supramolecular polymers in solid state by solution-coating technique. The photovoltaic properties of ttbPcGaF and ttbPcGaOH as electron donor materials in solution-processed bulk heterojunction (BHJ) organic solar cells (OSCs) were investigated. Due to the retention of the self-assembly property of ttbPcGaF and nanoscale phase separation in the ttbPcGaF : PC
61
BM blend film, the ttbPcGaF-based BHJ OSC provided a profoundly improved power conversion efficiency (PCE) of 0.41%, as compared with a low PCE of 0.03% afforded by ttbPcGaOH. |
| doi_str_mv | 10.1039/C4RA03941F |
| format | Article |
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tert
-butylphthalocyanine (ttbPcGaF) and its precursor hydroxygallium tetra-
tert
-butylphthalocyanine (ttbPcGaOH) were successfully synthesized. ttbPcGaF had a considerably stronger ability than that of ttbPcGaOH to self-organize into well-ordered one-dimensional (1D) supramolecular polymers in solid state by solution-coating technique. The photovoltaic properties of ttbPcGaF and ttbPcGaOH as electron donor materials in solution-processed bulk heterojunction (BHJ) organic solar cells (OSCs) were investigated. Due to the retention of the self-assembly property of ttbPcGaF and nanoscale phase separation in the ttbPcGaF : PC
61
BM blend film, the ttbPcGaF-based BHJ OSC provided a profoundly improved power conversion efficiency (PCE) of 0.41%, as compared with a low PCE of 0.03% afforded by ttbPcGaOH.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/C4RA03941F</identifier><language>eng</language><subject>Blends ; Energy conversion efficiency ; Heterojunctions ; Nanostructure ; Photovoltaic cells ; Precursors ; Self assembly ; Solar cells</subject><ispartof>RSC advances, 2014-01, Vol.4 (56), p.29485-29492</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c264t-5d818007e73c327d74a763cdb8f26da9a29db36d537a7af5c3199bc9b27654223</citedby><cites>FETCH-LOGICAL-c264t-5d818007e73c327d74a763cdb8f26da9a29db36d537a7af5c3199bc9b27654223</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,27929,27930</link.rule.ids></links><search><creatorcontrib>Zhang, Jian</creatorcontrib><creatorcontrib>Li, Yaowen</creatorcontrib><creatorcontrib>Wang, Laibing</creatorcontrib><creatorcontrib>Fujiki, Michiya</creatorcontrib><creatorcontrib>Li, Xiaopeng</creatorcontrib><creatorcontrib>Zhang, Zhengbiao</creatorcontrib><creatorcontrib>Zhang, Wei</creatorcontrib><creatorcontrib>Zhou, Nianchen</creatorcontrib><creatorcontrib>Zhu, Xiulin</creatorcontrib><title>Supramolecular self-assembly and photovoltaic property of soluble fluorogallium phthalocyanine</title><title>RSC advances</title><description>Within the present work, two soluble phthalocyanine compounds, fluorogallium tetra-
tert
-butylphthalocyanine (ttbPcGaF) and its precursor hydroxygallium tetra-
tert
-butylphthalocyanine (ttbPcGaOH) were successfully synthesized. ttbPcGaF had a considerably stronger ability than that of ttbPcGaOH to self-organize into well-ordered one-dimensional (1D) supramolecular polymers in solid state by solution-coating technique. The photovoltaic properties of ttbPcGaF and ttbPcGaOH as electron donor materials in solution-processed bulk heterojunction (BHJ) organic solar cells (OSCs) were investigated. Due to the retention of the self-assembly property of ttbPcGaF and nanoscale phase separation in the ttbPcGaF : PC
61
BM blend film, the ttbPcGaF-based BHJ OSC provided a profoundly improved power conversion efficiency (PCE) of 0.41%, as compared with a low PCE of 0.03% afforded by ttbPcGaOH.</description><subject>Blends</subject><subject>Energy conversion efficiency</subject><subject>Heterojunctions</subject><subject>Nanostructure</subject><subject>Photovoltaic cells</subject><subject>Precursors</subject><subject>Self assembly</subject><subject>Solar cells</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNpNkEtLxDAcxIMouOhe_AQ5ilDNo002x2VxVVgQfFwt_-bhVtKmJo3Qb29lBZ3LzOHHMAxCF5RcU8LVzaZ8Ws9e0u0RWjBSioIRoY7_5VO0TOmDzBIVZYIu0NtzHiJ0wVudPUScrHcFpGS7xk8YeoOHfRjDV_AjtBoPMQw2jhMODqfgc-Mtdj6HGN7B-zZ3Mz7uwQc9Qd_29hydOPDJLn_9DL1ub18298Xu8e5hs94VmolyLCqzoitCpJVccyaNLEEKrk2zckwYUMCUabgwFZcgwVWaU6UarRomRVUyxs_Q5aF3HviZbRrrrk3aeg-9DTnVVDBCuCCCzujVAdUxpBStq4fYdhCnmpL658f670f-DXBLZsg</recordid><startdate>20140101</startdate><enddate>20140101</enddate><creator>Zhang, Jian</creator><creator>Li, Yaowen</creator><creator>Wang, Laibing</creator><creator>Fujiki, Michiya</creator><creator>Li, Xiaopeng</creator><creator>Zhang, Zhengbiao</creator><creator>Zhang, Wei</creator><creator>Zhou, Nianchen</creator><creator>Zhu, Xiulin</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20140101</creationdate><title>Supramolecular self-assembly and photovoltaic property of soluble fluorogallium phthalocyanine</title><author>Zhang, Jian ; Li, Yaowen ; Wang, Laibing ; Fujiki, Michiya ; Li, Xiaopeng ; Zhang, Zhengbiao ; Zhang, Wei ; Zhou, Nianchen ; Zhu, Xiulin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c264t-5d818007e73c327d74a763cdb8f26da9a29db36d537a7af5c3199bc9b27654223</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Blends</topic><topic>Energy conversion efficiency</topic><topic>Heterojunctions</topic><topic>Nanostructure</topic><topic>Photovoltaic cells</topic><topic>Precursors</topic><topic>Self assembly</topic><topic>Solar cells</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Jian</creatorcontrib><creatorcontrib>Li, Yaowen</creatorcontrib><creatorcontrib>Wang, Laibing</creatorcontrib><creatorcontrib>Fujiki, Michiya</creatorcontrib><creatorcontrib>Li, Xiaopeng</creatorcontrib><creatorcontrib>Zhang, Zhengbiao</creatorcontrib><creatorcontrib>Zhang, Wei</creatorcontrib><creatorcontrib>Zhou, Nianchen</creatorcontrib><creatorcontrib>Zhu, Xiulin</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Jian</au><au>Li, Yaowen</au><au>Wang, Laibing</au><au>Fujiki, Michiya</au><au>Li, Xiaopeng</au><au>Zhang, Zhengbiao</au><au>Zhang, Wei</au><au>Zhou, Nianchen</au><au>Zhu, Xiulin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Supramolecular self-assembly and photovoltaic property of soluble fluorogallium phthalocyanine</atitle><jtitle>RSC advances</jtitle><date>2014-01-01</date><risdate>2014</risdate><volume>4</volume><issue>56</issue><spage>29485</spage><epage>29492</epage><pages>29485-29492</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>Within the present work, two soluble phthalocyanine compounds, fluorogallium tetra-
tert
-butylphthalocyanine (ttbPcGaF) and its precursor hydroxygallium tetra-
tert
-butylphthalocyanine (ttbPcGaOH) were successfully synthesized. ttbPcGaF had a considerably stronger ability than that of ttbPcGaOH to self-organize into well-ordered one-dimensional (1D) supramolecular polymers in solid state by solution-coating technique. The photovoltaic properties of ttbPcGaF and ttbPcGaOH as electron donor materials in solution-processed bulk heterojunction (BHJ) organic solar cells (OSCs) were investigated. Due to the retention of the self-assembly property of ttbPcGaF and nanoscale phase separation in the ttbPcGaF : PC
61
BM blend film, the ttbPcGaF-based BHJ OSC provided a profoundly improved power conversion efficiency (PCE) of 0.41%, as compared with a low PCE of 0.03% afforded by ttbPcGaOH.</abstract><doi>10.1039/C4RA03941F</doi><tpages>8</tpages></addata></record> |
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| ispartof | RSC advances, 2014-01, Vol.4 (56), p.29485-29492 |
| issn | 2046-2069 2046-2069 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1620036061 |
| source | Royal Society Of Chemistry Journals |
| subjects | Blends Energy conversion efficiency Heterojunctions Nanostructure Photovoltaic cells Precursors Self assembly Solar cells |
| title | Supramolecular self-assembly and photovoltaic property of soluble fluorogallium phthalocyanine |
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