Characterization of the TE-NORM waste associated with oil and natural gas production in Abu Rudeis, Egypt

The present study was conducted to characterize the Technically Enhanced Naturally Occurring Radioactive Materials (TE-NORM) waste generated from oil and gas production. The waste was characterized by means of dry screening solid fractionation, X-ray analysis (XRF and XRD) and γ-ray spectrometry. Se...

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Veröffentlicht in:Journal of environmental radioactivity 2005, Vol.82 (1), p.7-19
Hauptverfasser: El Afifi, E.M., Awwad, N.S.
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description The present study was conducted to characterize the Technically Enhanced Naturally Occurring Radioactive Materials (TE-NORM) waste generated from oil and gas production. The waste was characterized by means of dry screening solid fractionation, X-ray analysis (XRF and XRD) and γ-ray spectrometry. Sediment of the TE-NORM waste was fractionated into ten fractions with particle sizes varying from less than 100 μm to more than 3 mm. The results showed that the TE-NORM waste contains mainly radionuclides of the 238U, 235U and 232Th series. The mean activity concentrations of 226Ra (of U-series), 228Ra (of Th-series) and 40K in the waste samples before fractionation (i.e. 3 mm) were found to amount to 68.9, 24 and 1.3 Bq/g (dry weight), respectively. After dry fractionation, the activity concentrations were widely distributed and enriched in certain fractions. This represented a 1.48 and 1.82-fold enrichment of 226Ra and 228Ra, respectively, in fraction F8 (2.0–2.5 mm) over those in bulk TE-NORM waste samples. The activity ratios of 238U/ 226Ra, 210Pb/ 226Ra, 223Ra/ 226Ra and 228Ra/ 224Ra were calculated and evaluated. Activity of the most hazardous radionuclide 226Ra was found to be higher than the exemption levels established by IAEA [International Atomic Energy Agency, 1994. International Basic Safety Standards for the Protection against Ionizing Radiation and for the Safety of Radiation Sources. GOV/2715/94, Vienna]. The radium equivalent activity (Ra-eq), radon ( 222Rn) emanation coefficient (EC) and absorbed dose rate ( D γr) were estimated and these are further discussed.
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The waste was characterized by means of dry screening solid fractionation, X-ray analysis (XRF and XRD) and γ-ray spectrometry. Sediment of the TE-NORM waste was fractionated into ten fractions with particle sizes varying from less than 100 μm to more than 3 mm. The results showed that the TE-NORM waste contains mainly radionuclides of the 238U, 235U and 232Th series. The mean activity concentrations of 226Ra (of U-series), 228Ra (of Th-series) and 40K in the waste samples before fractionation (i.e. 3 mm) were found to amount to 68.9, 24 and 1.3 Bq/g (dry weight), respectively. After dry fractionation, the activity concentrations were widely distributed and enriched in certain fractions. This represented a 1.48 and 1.82-fold enrichment of 226Ra and 228Ra, respectively, in fraction F8 (2.0–2.5 mm) over those in bulk TE-NORM waste samples. The activity ratios of 238U/ 226Ra, 210Pb/ 226Ra, 223Ra/ 226Ra and 228Ra/ 224Ra were calculated and evaluated. Activity of the most hazardous radionuclide 226Ra was found to be higher than the exemption levels established by IAEA [International Atomic Energy Agency, 1994. International Basic Safety Standards for the Protection against Ionizing Radiation and for the Safety of Radiation Sources. GOV/2715/94, Vienna]. The radium equivalent activity (Ra-eq), radon ( 222Rn) emanation coefficient (EC) and absorbed dose rate ( D γr) were estimated and these are further discussed.</description><subject>Applied sciences</subject><subject>Earth sciences</subject><subject>Earth, ocean, space</subject><subject>Egypt</subject><subject>Engineering and environment geology. 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Geothermics</topic><topic>Exact sciences and technology</topic><topic>Extraction and Processing Industry</topic><topic>Fractionation</topic><topic>Humans</topic><topic>Metals - analysis</topic><topic>Natural series</topic><topic>Occupational Exposure</topic><topic>Oil and gas production</topic><topic>Particle Size</topic><topic>Petroleum</topic><topic>Pollution</topic><topic>Pollution, environment geology</topic><topic>Radiation Dosage</topic><topic>Radiation indices</topic><topic>Radiation Monitoring</topic><topic>Radioactive Waste - analysis</topic><topic>Radioactive wastes</topic><topic>Radioisotopes - analysis</topic><topic>Radioisotopes - standards</topic><topic>Spectrometry, Gamma</topic><topic>Spectrometry, X-Ray Emission</topic><topic>Spectroscopic analysis</topic><topic>TE-NORM</topic><topic>Wastes</topic><topic>X-Ray Diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>El Afifi, E.M.</creatorcontrib><creatorcontrib>Awwad, N.S.</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><collection>Pollution Abstracts</collection><jtitle>Journal of environmental radioactivity</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>El Afifi, E.M.</au><au>Awwad, N.S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Characterization of the TE-NORM waste associated with oil and natural gas production in Abu Rudeis, Egypt</atitle><jtitle>Journal of environmental radioactivity</jtitle><addtitle>J Environ Radioact</addtitle><date>2005</date><risdate>2005</risdate><volume>82</volume><issue>1</issue><spage>7</spage><epage>19</epage><pages>7-19</pages><issn>0265-931X</issn><eissn>1879-1700</eissn><coden>JERAEE</coden><abstract>The present study was conducted to characterize the Technically Enhanced Naturally Occurring Radioactive Materials (TE-NORM) waste generated from oil and gas production. The waste was characterized by means of dry screening solid fractionation, X-ray analysis (XRF and XRD) and γ-ray spectrometry. Sediment of the TE-NORM waste was fractionated into ten fractions with particle sizes varying from less than 100 μm to more than 3 mm. The results showed that the TE-NORM waste contains mainly radionuclides of the 238U, 235U and 232Th series. The mean activity concentrations of 226Ra (of U-series), 228Ra (of Th-series) and 40K in the waste samples before fractionation (i.e. 3 mm) were found to amount to 68.9, 24 and 1.3 Bq/g (dry weight), respectively. After dry fractionation, the activity concentrations were widely distributed and enriched in certain fractions. This represented a 1.48 and 1.82-fold enrichment of 226Ra and 228Ra, respectively, in fraction F8 (2.0–2.5 mm) over those in bulk TE-NORM waste samples. The activity ratios of 238U/ 226Ra, 210Pb/ 226Ra, 223Ra/ 226Ra and 228Ra/ 224Ra were calculated and evaluated. Activity of the most hazardous radionuclide 226Ra was found to be higher than the exemption levels established by IAEA [International Atomic Energy Agency, 1994. International Basic Safety Standards for the Protection against Ionizing Radiation and for the Safety of Radiation Sources. GOV/2715/94, Vienna]. The radium equivalent activity (Ra-eq), radon ( 222Rn) emanation coefficient (EC) and absorbed dose rate ( D γr) were estimated and these are further discussed.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><pmid>15829333</pmid><doi>10.1016/j.jenvrad.2004.11.001</doi><tpages>13</tpages></addata></record>
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subjects Applied sciences
Earth sciences
Earth, ocean, space
Egypt
Engineering and environment geology. Geothermics
Exact sciences and technology
Extraction and Processing Industry
Fractionation
Humans
Metals - analysis
Natural series
Occupational Exposure
Oil and gas production
Particle Size
Petroleum
Pollution
Pollution, environment geology
Radiation Dosage
Radiation indices
Radiation Monitoring
Radioactive Waste - analysis
Radioactive wastes
Radioisotopes - analysis
Radioisotopes - standards
Spectrometry, Gamma
Spectrometry, X-Ray Emission
Spectroscopic analysis
TE-NORM
Wastes
X-Ray Diffraction
title Characterization of the TE-NORM waste associated with oil and natural gas production in Abu Rudeis, Egypt
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