Influence of Side-Chain Regiochemistry on the Transistor Performance of High-Mobility, All-Donor Polymers

Influence of Side-Chain Regiochemistry on the Transistor Performance of High-Mobility, All-Donor Polymers

Three novel polythiophene isomers are reported whereby the only difference in structure relates to the regiochemistry of the solubilizing side chains on the backbone. This is demonstrated to have a significant impact on the optoelectronic properties of the polymers and their propensity to aggregate...

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Veröffentlicht in:Journal of the American Chemical Society 2014-10, Vol.136 (43), p.15154-15157
Hauptverfasser: Fei, Zhuping, Pattanasattayavong, Pichaya, Han, Yang, Schroeder, Bob C, Yan, Feng, Kline, R. Joseph, Anthopoulos, Thomas D, Heeney, Martin
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container_end_page 15157
container_issue 43
container_start_page 15154
container_title Journal of the American Chemical Society
container_volume 136
creator Fei, Zhuping
Pattanasattayavong, Pichaya
Han, Yang
Schroeder, Bob C
Yan, Feng
Kline, R. Joseph
Anthopoulos, Thomas D
Heeney, Martin
description Three novel polythiophene isomers are reported whereby the only difference in structure relates to the regiochemistry of the solubilizing side chains on the backbone. This is demonstrated to have a significant impact on the optoelectronic properties of the polymers and their propensity to aggregate in solution. These differences are rationalized on the basis of differences in backbone torsion. The polymer with the largest effective conjugation length is demonstrated to exhibit the highest field-effect mobility, with peak values up to 4.6 cm2 V–1 s–1.
doi_str_mv 10.1021/ja508798s
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title Influence of Side-Chain Regiochemistry on the Transistor Performance of High-Mobility, All-Donor Polymers
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