Chemical Dynamic Kinetic Resolution and S/R Interconversion of Unprotected α-Amino Acids

Reported herein is the first purely chemical method for the dynamic kinetic resolution (DKR) of unprotected racemic α‐amino acids (α‐AAs), a method which can rival the economic efficiency of the enzymatic reactions. The DKR reaction principle can be readily applied for S/R interconversions of α‐AAs,...

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Veröffentlicht in:	Angewandte Chemie International Edition 2014-11, Vol.53 (45), p.12214-12217
Hauptverfasser:	Takeda, Ryosuke, Kawamura, Akie, Kawashima, Aki, Sato, Tatsunori, Moriwaki, Hiroki, Izawa, Kunisuke, Akaji, Kenichi, Wang, Shuni, Liu, Hong, Aceña, José Luis, Soloshonok, Vadim A.
Format:	Artikel
Sprache:	eng
Schlagworte:	amino acids Amino Acids - chemistry Catalysis chirality diastereoselectivity kinetic resolution Kinetics nickel Stereoisomerism
Online-Zugang:	Volltext
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