Chromatographic separation of chlorophenoxy acid herbicides and their radiolytic degradation products in water samples
HPLC procedure for simultaneous determination of chlorophenoxy acid herbicides and their radiolytic degradation products in waters is described with the use of octadecylsilica column and spectrophotometric detection at 280 nm. The satisfactory separation was achieved with a mobile phase of pH 2.5 co...
Gespeichert in:
| Veröffentlicht in: | Water research (Oxford) 2004-08, Vol.38 (14), p.3259-3264 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 3264 |
|---|---|
| container_issue | 14 |
| container_start_page | 3259 |
| container_title | Water research (Oxford) |
| container_volume | 38 |
| creator | Jankowska, A Biesaga, M Drzewicz, P Trojanowicz, M Pyrzyńska, K |
| description | HPLC procedure for simultaneous determination of chlorophenoxy acid herbicides and their radiolytic degradation products in waters is described with the use of octadecylsilica column and spectrophotometric detection at 280
nm. The satisfactory separation was achieved with a mobile phase of pH 2.5 consisting of 43.7
mM acetic acid with 40% (v/v) acetonitrile. Limit of detection values for herbicides and phenol derivatives were in the range of 19–41
μg/l and 10–60
μg/l, respectively. The developed method was applied for monitoring the effectiveness of radiolytic degradation of herbicides. Studies of products of
γ-radiolysis of 2,4-dichlorophenol have shown that the efficiency of this process is affected by the presence of naturally occurring scavengers of
γ-radiation such as carbonates or nitrates. |
| doi_str_mv | 10.1016/j.watres.2004.03.032 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_16175630</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S004313540400168X</els_id><sourcerecordid>16175630</sourcerecordid><originalsourceid>FETCH-LOGICAL-c443t-4e5acf13ff6c8fa093e1ef8950617eede5d46fffbcc35ce348e383e11d82ce5a3</originalsourceid><addsrcrecordid>eNp9kE1r3DAQhkVpaLZp_0FpdWlv3urLXu-lUJZ-QSCHNGcxK41iLbblSt60--8zwQu5FQYkmGceXl7G3kmxlkI2nw_rvzBnLGslhFkLTaNesJVsN9tKGdO-ZCta6Erq2lyy16UchBBK6e0rdilrtWk2Rq3Yw67LaYA53WeYuuh4wQkyzDGNPAXuuj7lNHU4pn8nDi563mHeR_pg4TB6PncYM8_gY-pPMwk8ksovhiknf3Rz4XHklBYzLzBMPZY37CJAX_Dt-b1id9-__d79rK5vfvzafb2unDF6rgzW4ILUITSuDSC2GiWGdluLRm4QPdbeNCGEvXO6dqhNi7olRvpWObrVV-zT4qUkf45YZjvE4rDvYcR0LFaSp260INAsoMuplIzBTjkOkE9WCvvUtz3YpW_71LcVmkbR2fuz_7gf0D8fnQsm4OMZgOKgDxlGF8sz1wghRauJ-7BwAZKF-0zM3a0SUtNaNLUyRHxZCKS-HiJmW1zE0aGPGd1sfYr_z_oImF2tiw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>16175630</pqid></control><display><type>article</type><title>Chromatographic separation of chlorophenoxy acid herbicides and their radiolytic degradation products in water samples</title><source>MEDLINE</source><source>Access via ScienceDirect (Elsevier)</source><creator>Jankowska, A ; Biesaga, M ; Drzewicz, P ; Trojanowicz, M ; Pyrzyńska, K</creator><creatorcontrib>Jankowska, A ; Biesaga, M ; Drzewicz, P ; Trojanowicz, M ; Pyrzyńska, K</creatorcontrib><description>HPLC procedure for simultaneous determination of chlorophenoxy acid herbicides and their radiolytic degradation products in waters is described with the use of octadecylsilica column and spectrophotometric detection at 280
nm. The satisfactory separation was achieved with a mobile phase of pH 2.5 consisting of 43.7
mM acetic acid with 40% (v/v) acetonitrile. Limit of detection values for herbicides and phenol derivatives were in the range of 19–41
μg/l and 10–60
μg/l, respectively. The developed method was applied for monitoring the effectiveness of radiolytic degradation of herbicides. Studies of products of
γ-radiolysis of 2,4-dichlorophenol have shown that the efficiency of this process is affected by the presence of naturally occurring scavengers of
γ-radiation such as carbonates or nitrates.</description><identifier>ISSN: 0043-1354</identifier><identifier>EISSN: 1879-2448</identifier><identifier>DOI: 10.1016/j.watres.2004.03.032</identifier><identifier>PMID: 15276742</identifier><identifier>CODEN: WATRAG</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Acetic Acid - chemistry ; Acetonitriles - chemistry ; Acids - chemistry ; Applied sciences ; Biological and physicochemical phenomena ; Carbonates - chemistry ; Chlorophenols - analysis ; Chlorophenols - isolation & purification ; Chlorophenols - radiation effects ; Chlorophenoxy acid herbicides ; Chromatography, High Pressure Liquid - methods ; Dose-Response Relationship, Radiation ; Earth sciences ; Earth, ocean, space ; Engineering and environment geology. Geothermics ; Exact sciences and technology ; Gamma Rays ; Herbicides - chemistry ; Herbicides - isolation & purification ; Herbicides - radiation effects ; Natural water pollution ; Nitrates - chemistry ; Pollution ; Pollution, environment geology ; Radiochemistry ; Radiolytic degradation ; Silicon Dioxide - chemistry ; Spectrophotometry, Ultraviolet ; Water analysis ; Water Pollution, Chemical - analysis ; Water Supply - analysis ; Water treatment and pollution</subject><ispartof>Water research (Oxford), 2004-08, Vol.38 (14), p.3259-3264</ispartof><rights>2004 Elsevier Ltd</rights><rights>2004 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c443t-4e5acf13ff6c8fa093e1ef8950617eede5d46fffbcc35ce348e383e11d82ce5a3</citedby><cites>FETCH-LOGICAL-c443t-4e5acf13ff6c8fa093e1ef8950617eede5d46fffbcc35ce348e383e11d82ce5a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.watres.2004.03.032$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=16001083$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/15276742$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Jankowska, A</creatorcontrib><creatorcontrib>Biesaga, M</creatorcontrib><creatorcontrib>Drzewicz, P</creatorcontrib><creatorcontrib>Trojanowicz, M</creatorcontrib><creatorcontrib>Pyrzyńska, K</creatorcontrib><title>Chromatographic separation of chlorophenoxy acid herbicides and their radiolytic degradation products in water samples</title><title>Water research (Oxford)</title><addtitle>Water Res</addtitle><description>HPLC procedure for simultaneous determination of chlorophenoxy acid herbicides and their radiolytic degradation products in waters is described with the use of octadecylsilica column and spectrophotometric detection at 280
nm. The satisfactory separation was achieved with a mobile phase of pH 2.5 consisting of 43.7
mM acetic acid with 40% (v/v) acetonitrile. Limit of detection values for herbicides and phenol derivatives were in the range of 19–41
μg/l and 10–60
μg/l, respectively. The developed method was applied for monitoring the effectiveness of radiolytic degradation of herbicides. Studies of products of
γ-radiolysis of 2,4-dichlorophenol have shown that the efficiency of this process is affected by the presence of naturally occurring scavengers of
γ-radiation such as carbonates or nitrates.</description><subject>Acetic Acid - chemistry</subject><subject>Acetonitriles - chemistry</subject><subject>Acids - chemistry</subject><subject>Applied sciences</subject><subject>Biological and physicochemical phenomena</subject><subject>Carbonates - chemistry</subject><subject>Chlorophenols - analysis</subject><subject>Chlorophenols - isolation & purification</subject><subject>Chlorophenols - radiation effects</subject><subject>Chlorophenoxy acid herbicides</subject><subject>Chromatography, High Pressure Liquid - methods</subject><subject>Dose-Response Relationship, Radiation</subject><subject>Earth sciences</subject><subject>Earth, ocean, space</subject><subject>Engineering and environment geology. Geothermics</subject><subject>Exact sciences and technology</subject><subject>Gamma Rays</subject><subject>Herbicides - chemistry</subject><subject>Herbicides - isolation & purification</subject><subject>Herbicides - radiation effects</subject><subject>Natural water pollution</subject><subject>Nitrates - chemistry</subject><subject>Pollution</subject><subject>Pollution, environment geology</subject><subject>Radiochemistry</subject><subject>Radiolytic degradation</subject><subject>Silicon Dioxide - chemistry</subject><subject>Spectrophotometry, Ultraviolet</subject><subject>Water analysis</subject><subject>Water Pollution, Chemical - analysis</subject><subject>Water Supply - analysis</subject><subject>Water treatment and pollution</subject><issn>0043-1354</issn><issn>1879-2448</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp9kE1r3DAQhkVpaLZp_0FpdWlv3urLXu-lUJZ-QSCHNGcxK41iLbblSt60--8zwQu5FQYkmGceXl7G3kmxlkI2nw_rvzBnLGslhFkLTaNesJVsN9tKGdO-ZCta6Erq2lyy16UchBBK6e0rdilrtWk2Rq3Yw67LaYA53WeYuuh4wQkyzDGNPAXuuj7lNHU4pn8nDi563mHeR_pg4TB6PncYM8_gY-pPMwk8ksovhiknf3Rz4XHklBYzLzBMPZY37CJAX_Dt-b1id9-__d79rK5vfvzafb2unDF6rgzW4ILUITSuDSC2GiWGdluLRm4QPdbeNCGEvXO6dqhNi7olRvpWObrVV-zT4qUkf45YZjvE4rDvYcR0LFaSp260INAsoMuplIzBTjkOkE9WCvvUtz3YpW_71LcVmkbR2fuz_7gf0D8fnQsm4OMZgOKgDxlGF8sz1wghRauJ-7BwAZKF-0zM3a0SUtNaNLUyRHxZCKS-HiJmW1zE0aGPGd1sfYr_z_oImF2tiw</recordid><startdate>20040801</startdate><enddate>20040801</enddate><creator>Jankowska, A</creator><creator>Biesaga, M</creator><creator>Drzewicz, P</creator><creator>Trojanowicz, M</creator><creator>Pyrzyńska, K</creator><general>Elsevier Ltd</general><general>Elsevier Science</general><scope>FBQ</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope><scope>7TV</scope><scope>7UA</scope><scope>C1K</scope><scope>F1W</scope><scope>H96</scope><scope>L.G</scope></search><sort><creationdate>20040801</creationdate><title>Chromatographic separation of chlorophenoxy acid herbicides and their radiolytic degradation products in water samples</title><author>Jankowska, A ; Biesaga, M ; Drzewicz, P ; Trojanowicz, M ; Pyrzyńska, K</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c443t-4e5acf13ff6c8fa093e1ef8950617eede5d46fffbcc35ce348e383e11d82ce5a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Acetic Acid - chemistry</topic><topic>Acetonitriles - chemistry</topic><topic>Acids - chemistry</topic><topic>Applied sciences</topic><topic>Biological and physicochemical phenomena</topic><topic>Carbonates - chemistry</topic><topic>Chlorophenols - analysis</topic><topic>Chlorophenols - isolation & purification</topic><topic>Chlorophenols - radiation effects</topic><topic>Chlorophenoxy acid herbicides</topic><topic>Chromatography, High Pressure Liquid - methods</topic><topic>Dose-Response Relationship, Radiation</topic><topic>Earth sciences</topic><topic>Earth, ocean, space</topic><topic>Engineering and environment geology. Geothermics</topic><topic>Exact sciences and technology</topic><topic>Gamma Rays</topic><topic>Herbicides - chemistry</topic><topic>Herbicides - isolation & purification</topic><topic>Herbicides - radiation effects</topic><topic>Natural water pollution</topic><topic>Nitrates - chemistry</topic><topic>Pollution</topic><topic>Pollution, environment geology</topic><topic>Radiochemistry</topic><topic>Radiolytic degradation</topic><topic>Silicon Dioxide - chemistry</topic><topic>Spectrophotometry, Ultraviolet</topic><topic>Water analysis</topic><topic>Water Pollution, Chemical - analysis</topic><topic>Water Supply - analysis</topic><topic>Water treatment and pollution</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jankowska, A</creatorcontrib><creatorcontrib>Biesaga, M</creatorcontrib><creatorcontrib>Drzewicz, P</creatorcontrib><creatorcontrib>Trojanowicz, M</creatorcontrib><creatorcontrib>Pyrzyńska, K</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aqualine</collection><collection>Pollution Abstracts</collection><collection>Water Resources Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy & Non-Living Resources</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><jtitle>Water research (Oxford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jankowska, A</au><au>Biesaga, M</au><au>Drzewicz, P</au><au>Trojanowicz, M</au><au>Pyrzyńska, K</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Chromatographic separation of chlorophenoxy acid herbicides and their radiolytic degradation products in water samples</atitle><jtitle>Water research (Oxford)</jtitle><addtitle>Water Res</addtitle><date>2004-08-01</date><risdate>2004</risdate><volume>38</volume><issue>14</issue><spage>3259</spage><epage>3264</epage><pages>3259-3264</pages><issn>0043-1354</issn><eissn>1879-2448</eissn><coden>WATRAG</coden><abstract>HPLC procedure for simultaneous determination of chlorophenoxy acid herbicides and their radiolytic degradation products in waters is described with the use of octadecylsilica column and spectrophotometric detection at 280
nm. The satisfactory separation was achieved with a mobile phase of pH 2.5 consisting of 43.7
mM acetic acid with 40% (v/v) acetonitrile. Limit of detection values for herbicides and phenol derivatives were in the range of 19–41
μg/l and 10–60
μg/l, respectively. The developed method was applied for monitoring the effectiveness of radiolytic degradation of herbicides. Studies of products of
γ-radiolysis of 2,4-dichlorophenol have shown that the efficiency of this process is affected by the presence of naturally occurring scavengers of
γ-radiation such as carbonates or nitrates.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><pmid>15276742</pmid><doi>10.1016/j.watres.2004.03.032</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0043-1354 |
| ispartof | Water research (Oxford), 2004-08, Vol.38 (14), p.3259-3264 |
| issn | 0043-1354 1879-2448 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_16175630 |
| source | MEDLINE; Access via ScienceDirect (Elsevier) |
| subjects | Acetic Acid - chemistry Acetonitriles - chemistry Acids - chemistry Applied sciences Biological and physicochemical phenomena Carbonates - chemistry Chlorophenols - analysis Chlorophenols - isolation & purification Chlorophenols - radiation effects Chlorophenoxy acid herbicides Chromatography, High Pressure Liquid - methods Dose-Response Relationship, Radiation Earth sciences Earth, ocean, space Engineering and environment geology. Geothermics Exact sciences and technology Gamma Rays Herbicides - chemistry Herbicides - isolation & purification Herbicides - radiation effects Natural water pollution Nitrates - chemistry Pollution Pollution, environment geology Radiochemistry Radiolytic degradation Silicon Dioxide - chemistry Spectrophotometry, Ultraviolet Water analysis Water Pollution, Chemical - analysis Water Supply - analysis Water treatment and pollution |
| title | Chromatographic separation of chlorophenoxy acid herbicides and their radiolytic degradation products in water samples |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-29T21%3A06%3A13IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Chromatographic%20separation%20of%20chlorophenoxy%20acid%20herbicides%20and%20their%20radiolytic%20degradation%20products%20in%20water%20samples&rft.jtitle=Water%20research%20(Oxford)&rft.au=Jankowska,%20A&rft.date=2004-08-01&rft.volume=38&rft.issue=14&rft.spage=3259&rft.epage=3264&rft.pages=3259-3264&rft.issn=0043-1354&rft.eissn=1879-2448&rft.coden=WATRAG&rft_id=info:doi/10.1016/j.watres.2004.03.032&rft_dat=%3Cproquest_cross%3E16175630%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=16175630&rft_id=info:pmid/15276742&rft_els_id=S004313540400168X&rfr_iscdi=true |