Copper and zinc retention by an organically amended soil

This paper describes changes in retention of Cu and Zn in laboratory experiments by a sandy soil that had been amended in the field with different composted wastes. The amounts of the metals retained increased as a result of the amendments, especially after two years. Desorption of the sorbed metals...

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Veröffentlicht in:Chemosphere (Oxford) 2003-02, Vol.50 (7), p.911-917
Hauptverfasser: Dı́az-Barrientos, E, Madrid, L, Maqueda, C, Morillo, E, Ruiz-Cortés, E, Basallote, E, Carrillo, M
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container_end_page 917
container_issue 7
container_start_page 911
container_title Chemosphere (Oxford)
container_volume 50
creator Dı́az-Barrientos, E
Madrid, L
Maqueda, C
Morillo, E
Ruiz-Cortés, E
Basallote, E
Carrillo, M
description This paper describes changes in retention of Cu and Zn in laboratory experiments by a sandy soil that had been amended in the field with different composted wastes. The amounts of the metals retained increased as a result of the amendments, especially after two years. Desorption of the sorbed metals was always negligible, regardless of the treatment. The proportion of Cu retained was considerably higher than that of Zn, suggesting a higher affinity of the soil for the former. The greater sorption in the amended soils indicates a build-up of fresh sites for metal retention. The use of ‘log(activity) vs. pH’ plots showed that the nature of the surfaces retaining metals on the untreated and amended soils is different. At comparable pH values, the amended soils gave higher solution metal concentrations. Some of the possible environmental consequences of the use of these amendments for remediation purposes are discussed.
doi_str_mv 10.1016/S0045-6535(02)00695-1
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subjects Adsorption
Applied sciences
Biological and physicochemical properties of pollutants. Interaction in the soil
Composted waste amendments
Copper - analysis
Copper - chemistry
Earth sciences
Earth, ocean, space
Engineering and environment geology. Geothermics
Exact sciences and technology
Hydrogen-Ion Concentration
Pollution
Pollution, environment geology
Refuse Disposal
Silicon Dioxide
Soil and sediments pollution
Soil Pollutants - analysis
Sorption
Zinc - analysis
Zinc - chemistry
title Copper and zinc retention by an organically amended soil
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