Effect of Ca on As release FROM FERRIC AND ALUM RESIDUALS
Dewatering of residuals containing arsenic (As) has attracted little research but will become increasingly important as As is removed from water by sorption to ferric or aluminum hydroxides. Lime conditioning proves to be an effective method for immobilizing As even at high pH. In contrast, increasi...
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Veröffentlicht in: | Journal - American Water Works Association 2003-06, Vol.95 (6), p.108-118 |
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creator | PARKS, JEFFREY L. NOVAK, JOHN MACPHEE, MICHAEL ITLE, CORTNEY EDWARDS, MARC |
description | Dewatering of residuals containing arsenic (As) has attracted little research but will become increasingly important as As is removed from water by sorption to ferric or aluminum hydroxides. Lime conditioning proves to be an effective method for immobilizing As even at high pH. In contrast, increasing pH with addition of caustic soda or soda ash leaches As from residuals. Soluble calcium appears to neutralize the negative surface charge on the hydroxide solids to enhance As sorption. In many cases, As‐containing residuals are stored in lagoons for months or even years. Although many parameters contribute to soluble As mobilization, the presence of calcium appears to assist in keeping As immobilized. |
doi_str_mv | 10.1002/j.1551-8833.2003.tb10391.x |
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Lime conditioning proves to be an effective method for immobilizing As even at high pH. In contrast, increasing pH with addition of caustic soda or soda ash leaches As from residuals. Soluble calcium appears to neutralize the negative surface charge on the hydroxide solids to enhance As sorption. In many cases, As‐containing residuals are stored in lagoons for months or even years. Although many parameters contribute to soluble As mobilization, the presence of calcium appears to assist in keeping As immobilized.</description><identifier>ISSN: 0003-150X</identifier><identifier>EISSN: 1551-8833</identifier><identifier>DOI: 10.1002/j.1551-8833.2003.tb10391.x</identifier><identifier>CODEN: JAWWA5</identifier><language>eng</language><publisher>Denver, CO: American Water Works Association</publisher><subject>Acids ; Alum ; Aluminum ; Applied sciences ; Arsenates ; Arsenic ; Calcium ; Carbonates ; Caustic soda ; Chemical reactions ; Drinking water ; Drinking water and swimming-pool water. Desalination ; Exact sciences and technology ; Hazardous materials ; Hydroxides ; Infiltration ; Lagoons ; Landfill ; Landfills ; Methods ; Modeling ; Pollution ; Public safety ; Sodium ; Sorption ; Treatment Plants ; Utilities ; Waste disposal ; Water treatment ; Water treatment and pollution</subject><ispartof>Journal - American Water Works Association, 2003-06, Vol.95 (6), p.108-118</ispartof><rights>Copyright© 2003 AWWA</rights><rights>2003 American Water Works Association</rights><rights>2003 INIST-CNRS</rights><rights>Copyright American Water Works Association Jun 2003</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4951-b2a41ac10eb2be9f12c150373a80d713be30b915e21737ea722a220f0a93675f3</citedby><cites>FETCH-LOGICAL-c4951-b2a41ac10eb2be9f12c150373a80d713be30b915e21737ea722a220f0a93675f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.jstor.org/stable/pdf/41311526$$EPDF$$P50$$Gjstor$$H</linktopdf><linktohtml>$$Uhttps://www.jstor.org/stable/41311526$$EHTML$$P50$$Gjstor$$H</linktohtml><link.rule.ids>314,780,784,803,1416,27922,27923,45572,45573,58015,58248</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=14867549$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>PARKS, JEFFREY L.</creatorcontrib><creatorcontrib>NOVAK, JOHN</creatorcontrib><creatorcontrib>MACPHEE, MICHAEL</creatorcontrib><creatorcontrib>ITLE, CORTNEY</creatorcontrib><creatorcontrib>EDWARDS, MARC</creatorcontrib><title>Effect of Ca on As release FROM FERRIC AND ALUM RESIDUALS</title><title>Journal - American Water Works Association</title><description>Dewatering of residuals containing arsenic (As) has attracted little research but will become increasingly important as As is removed from water by sorption to ferric or aluminum hydroxides. Lime conditioning proves to be an effective method for immobilizing As even at high pH. In contrast, increasing pH with addition of caustic soda or soda ash leaches As from residuals. Soluble calcium appears to neutralize the negative surface charge on the hydroxide solids to enhance As sorption. In many cases, As‐containing residuals are stored in lagoons for months or even years. Although many parameters contribute to soluble As mobilization, the presence of calcium appears to assist in keeping As immobilized.</description><subject>Acids</subject><subject>Alum</subject><subject>Aluminum</subject><subject>Applied sciences</subject><subject>Arsenates</subject><subject>Arsenic</subject><subject>Calcium</subject><subject>Carbonates</subject><subject>Caustic soda</subject><subject>Chemical reactions</subject><subject>Drinking water</subject><subject>Drinking water and swimming-pool water. 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American Water Works Association</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>PARKS, JEFFREY L.</au><au>NOVAK, JOHN</au><au>MACPHEE, MICHAEL</au><au>ITLE, CORTNEY</au><au>EDWARDS, MARC</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of Ca on As release FROM FERRIC AND ALUM RESIDUALS</atitle><jtitle>Journal - American Water Works Association</jtitle><date>2003-06</date><risdate>2003</risdate><volume>95</volume><issue>6</issue><spage>108</spage><epage>118</epage><pages>108-118</pages><issn>0003-150X</issn><eissn>1551-8833</eissn><coden>JAWWA5</coden><abstract>Dewatering of residuals containing arsenic (As) has attracted little research but will become increasingly important as As is removed from water by sorption to ferric or aluminum hydroxides. Lime conditioning proves to be an effective method for immobilizing As even at high pH. In contrast, increasing pH with addition of caustic soda or soda ash leaches As from residuals. Soluble calcium appears to neutralize the negative surface charge on the hydroxide solids to enhance As sorption. In many cases, As‐containing residuals are stored in lagoons for months or even years. Although many parameters contribute to soluble As mobilization, the presence of calcium appears to assist in keeping As immobilized.</abstract><cop>Denver, CO</cop><pub>American Water Works Association</pub><doi>10.1002/j.1551-8833.2003.tb10391.x</doi><tpages>11</tpages></addata></record> |
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subjects | Acids Alum Aluminum Applied sciences Arsenates Arsenic Calcium Carbonates Caustic soda Chemical reactions Drinking water Drinking water and swimming-pool water. Desalination Exact sciences and technology Hazardous materials Hydroxides Infiltration Lagoons Landfill Landfills Methods Modeling Pollution Public safety Sodium Sorption Treatment Plants Utilities Waste disposal Water treatment Water treatment and pollution |
title | Effect of Ca on As release FROM FERRIC AND ALUM RESIDUALS |
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