Effect of Ca on As release FROM FERRIC AND ALUM RESIDUALS

Dewatering of residuals containing arsenic (As) has attracted little research but will become increasingly important as As is removed from water by sorption to ferric or aluminum hydroxides. Lime conditioning proves to be an effective method for immobilizing As even at high pH. In contrast, increasi...

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Veröffentlicht in:Journal - American Water Works Association 2003-06, Vol.95 (6), p.108-118
Hauptverfasser: PARKS, JEFFREY L., NOVAK, JOHN, MACPHEE, MICHAEL, ITLE, CORTNEY, EDWARDS, MARC
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container_end_page 118
container_issue 6
container_start_page 108
container_title Journal - American Water Works Association
container_volume 95
creator PARKS, JEFFREY L.
NOVAK, JOHN
MACPHEE, MICHAEL
ITLE, CORTNEY
EDWARDS, MARC
description Dewatering of residuals containing arsenic (As) has attracted little research but will become increasingly important as As is removed from water by sorption to ferric or aluminum hydroxides. Lime conditioning proves to be an effective method for immobilizing As even at high pH. In contrast, increasing pH with addition of caustic soda or soda ash leaches As from residuals. Soluble calcium appears to neutralize the negative surface charge on the hydroxide solids to enhance As sorption. In many cases, As‐containing residuals are stored in lagoons for months or even years. Although many parameters contribute to soluble As mobilization, the presence of calcium appears to assist in keeping As immobilized.
doi_str_mv 10.1002/j.1551-8833.2003.tb10391.x
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Lime conditioning proves to be an effective method for immobilizing As even at high pH. In contrast, increasing pH with addition of caustic soda or soda ash leaches As from residuals. Soluble calcium appears to neutralize the negative surface charge on the hydroxide solids to enhance As sorption. In many cases, As‐containing residuals are stored in lagoons for months or even years. Although many parameters contribute to soluble As mobilization, the presence of calcium appears to assist in keeping As immobilized.</abstract><cop>Denver, CO</cop><pub>American Water Works Association</pub><doi>10.1002/j.1551-8833.2003.tb10391.x</doi><tpages>11</tpages></addata></record>
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source JSTOR Archive Collection A-Z Listing; Wiley Online Library All Journals
subjects Acids
Alum
Aluminum
Applied sciences
Arsenates
Arsenic
Calcium
Carbonates
Caustic soda
Chemical reactions
Drinking water
Drinking water and swimming-pool water. Desalination
Exact sciences and technology
Hazardous materials
Hydroxides
Infiltration
Lagoons
Landfill
Landfills
Methods
Modeling
Pollution
Public safety
Sodium
Sorption
Treatment Plants
Utilities
Waste disposal
Water treatment
Water treatment and pollution
title Effect of Ca on As release FROM FERRIC AND ALUM RESIDUALS
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