NO sub(x) and PAHs removal from industrial flue gas by using electron beam technology with alcohol addition

The removal of NO sub(x) and polycyclic aromatic hydrocarbons from flue gas was investigated, as a preliminary test, with alcohol addition by using electron beam irradiation in EPS Kaweczyn. The experimental conditions were the followings: flue gas flow rate 5000 nm super(3)/h; humidity 4-5%; inlet...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Radiation physics and chemistry (Oxford, England : 1993) England : 1993), 2003-06, Vol.67 (3-4), p.555-560
Hauptverfasser: Chmielewski, A G, Sun, Y-X, Licki, J, Bulka, S, Kubica, K, Zimek, Z
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 560
container_issue 3-4
container_start_page 555
container_title Radiation physics and chemistry (Oxford, England : 1993)
container_volume 67
creator Chmielewski, A G
Sun, Y-X
Licki, J
Bulka, S
Kubica, K
Zimek, Z
description The removal of NO sub(x) and polycyclic aromatic hydrocarbons from flue gas was investigated, as a preliminary test, with alcohol addition by using electron beam irradiation in EPS Kaweczyn. The experimental conditions were the followings: flue gas flow rate 5000 nm super(3)/h; humidity 4-5%; inlet concentrations of SO sub(2) and NO sub(x), which were emitted from power station, were 192 and 106 ppm, respectively; ammonia addition was 2.75 m super(3)/h; alcohol addition was 6001/h. It was found that below 6 kGy applied doses the NO sub(x) removal efficiency increased by 10% in the presence of alcohol as compared to the absence of alcohol; on the other hand, the NO sub(x) removal efficiency decreased at doses higher than 10 kGy. In order to understand the behavior of these aromatic hydrocarbons under electron irradiation, unirradiated samples (i.e. as emitted from the coal combustion process, called inlet) and irradiated samples (called outlet) were collected by using a condense bottle connected with an XAD-2 adsorbent and an active carbon adsorbent and were then analyzed by a GC-MS. It was found that using 8 kGy absorbed dose the concentration of aromatic hydrocarbons of small aromatic rings (
doi_str_mv 10.1016/S0969-806X(03)00105-1
format Article
fullrecord <record><control><sourceid>proquest</sourceid><recordid>TN_cdi_proquest_miscellaneous_16157939</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>16157939</sourcerecordid><originalsourceid>FETCH-proquest_miscellaneous_161579393</originalsourceid><addsrcrecordid>eNqNik1Lw0AQQPegYP34CcKcpD1EZwlJm6OI0pMV9OCtbJJpsjrZ0Z1dtf9eBPHs6fEez5hzi5cWbX31iE3dFCusn-dYLhAtVoU9MLO_fGSOVV8Qcbmqypl5vd-A5nb-tQAXeni4XitEmuTDMeyiTOBDnzVF_-OcCQan0O4hqw8DEFOXogRoyU2QqBuDsAx7-PRpBMedjMLg-t4nL-HUHO4cK5398sRc3N0-3ayLtyjvmTRtJ68dMbtAknVra1stm7Ip_z1-Awd4UUE</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>16157939</pqid></control><display><type>article</type><title>NO sub(x) and PAHs removal from industrial flue gas by using electron beam technology with alcohol addition</title><source>Elsevier ScienceDirect Journals</source><creator>Chmielewski, A G ; Sun, Y-X ; Licki, J ; Bulka, S ; Kubica, K ; Zimek, Z</creator><creatorcontrib>Chmielewski, A G ; Sun, Y-X ; Licki, J ; Bulka, S ; Kubica, K ; Zimek, Z</creatorcontrib><description>The removal of NO sub(x) and polycyclic aromatic hydrocarbons from flue gas was investigated, as a preliminary test, with alcohol addition by using electron beam irradiation in EPS Kaweczyn. The experimental conditions were the followings: flue gas flow rate 5000 nm super(3)/h; humidity 4-5%; inlet concentrations of SO sub(2) and NO sub(x), which were emitted from power station, were 192 and 106 ppm, respectively; ammonia addition was 2.75 m super(3)/h; alcohol addition was 6001/h. It was found that below 6 kGy applied doses the NO sub(x) removal efficiency increased by 10% in the presence of alcohol as compared to the absence of alcohol; on the other hand, the NO sub(x) removal efficiency decreased at doses higher than 10 kGy. In order to understand the behavior of these aromatic hydrocarbons under electron irradiation, unirradiated samples (i.e. as emitted from the coal combustion process, called inlet) and irradiated samples (called outlet) were collected by using a condense bottle connected with an XAD-2 adsorbent and an active carbon adsorbent and were then analyzed by a GC-MS. It was found that using 8 kGy absorbed dose the concentration of aromatic hydrocarbons of small aromatic rings (&lt;3, except acenaphthylene) were reduced, but the concentration of these hydrocarbons of large aromatic rings ( greater than or equal to 4) were increased. A possible mechanism is proposed.</description><identifier>ISSN: 0969-806X</identifier><identifier>DOI: 10.1016/S0969-806X(03)00105-1</identifier><language>eng</language><ispartof>Radiation physics and chemistry (Oxford, England : 1993), 2003-06, Vol.67 (3-4), p.555-560</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Chmielewski, A G</creatorcontrib><creatorcontrib>Sun, Y-X</creatorcontrib><creatorcontrib>Licki, J</creatorcontrib><creatorcontrib>Bulka, S</creatorcontrib><creatorcontrib>Kubica, K</creatorcontrib><creatorcontrib>Zimek, Z</creatorcontrib><title>NO sub(x) and PAHs removal from industrial flue gas by using electron beam technology with alcohol addition</title><title>Radiation physics and chemistry (Oxford, England : 1993)</title><description>The removal of NO sub(x) and polycyclic aromatic hydrocarbons from flue gas was investigated, as a preliminary test, with alcohol addition by using electron beam irradiation in EPS Kaweczyn. The experimental conditions were the followings: flue gas flow rate 5000 nm super(3)/h; humidity 4-5%; inlet concentrations of SO sub(2) and NO sub(x), which were emitted from power station, were 192 and 106 ppm, respectively; ammonia addition was 2.75 m super(3)/h; alcohol addition was 6001/h. It was found that below 6 kGy applied doses the NO sub(x) removal efficiency increased by 10% in the presence of alcohol as compared to the absence of alcohol; on the other hand, the NO sub(x) removal efficiency decreased at doses higher than 10 kGy. In order to understand the behavior of these aromatic hydrocarbons under electron irradiation, unirradiated samples (i.e. as emitted from the coal combustion process, called inlet) and irradiated samples (called outlet) were collected by using a condense bottle connected with an XAD-2 adsorbent and an active carbon adsorbent and were then analyzed by a GC-MS. It was found that using 8 kGy absorbed dose the concentration of aromatic hydrocarbons of small aromatic rings (&lt;3, except acenaphthylene) were reduced, but the concentration of these hydrocarbons of large aromatic rings ( greater than or equal to 4) were increased. A possible mechanism is proposed.</description><issn>0969-806X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><recordid>eNqNik1Lw0AQQPegYP34CcKcpD1EZwlJm6OI0pMV9OCtbJJpsjrZ0Z1dtf9eBPHs6fEez5hzi5cWbX31iE3dFCusn-dYLhAtVoU9MLO_fGSOVV8Qcbmqypl5vd-A5nb-tQAXeni4XitEmuTDMeyiTOBDnzVF_-OcCQan0O4hqw8DEFOXogRoyU2QqBuDsAx7-PRpBMedjMLg-t4nL-HUHO4cK5398sRc3N0-3ayLtyjvmTRtJ68dMbtAknVra1stm7Ip_z1-Awd4UUE</recordid><startdate>20030601</startdate><enddate>20030601</enddate><creator>Chmielewski, A G</creator><creator>Sun, Y-X</creator><creator>Licki, J</creator><creator>Bulka, S</creator><creator>Kubica, K</creator><creator>Zimek, Z</creator><scope>7TV</scope><scope>C1K</scope></search><sort><creationdate>20030601</creationdate><title>NO sub(x) and PAHs removal from industrial flue gas by using electron beam technology with alcohol addition</title><author>Chmielewski, A G ; Sun, Y-X ; Licki, J ; Bulka, S ; Kubica, K ; Zimek, Z</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-proquest_miscellaneous_161579393</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chmielewski, A G</creatorcontrib><creatorcontrib>Sun, Y-X</creatorcontrib><creatorcontrib>Licki, J</creatorcontrib><creatorcontrib>Bulka, S</creatorcontrib><creatorcontrib>Kubica, K</creatorcontrib><creatorcontrib>Zimek, Z</creatorcontrib><collection>Pollution Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><jtitle>Radiation physics and chemistry (Oxford, England : 1993)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chmielewski, A G</au><au>Sun, Y-X</au><au>Licki, J</au><au>Bulka, S</au><au>Kubica, K</au><au>Zimek, Z</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>NO sub(x) and PAHs removal from industrial flue gas by using electron beam technology with alcohol addition</atitle><jtitle>Radiation physics and chemistry (Oxford, England : 1993)</jtitle><date>2003-06-01</date><risdate>2003</risdate><volume>67</volume><issue>3-4</issue><spage>555</spage><epage>560</epage><pages>555-560</pages><issn>0969-806X</issn><abstract>The removal of NO sub(x) and polycyclic aromatic hydrocarbons from flue gas was investigated, as a preliminary test, with alcohol addition by using electron beam irradiation in EPS Kaweczyn. The experimental conditions were the followings: flue gas flow rate 5000 nm super(3)/h; humidity 4-5%; inlet concentrations of SO sub(2) and NO sub(x), which were emitted from power station, were 192 and 106 ppm, respectively; ammonia addition was 2.75 m super(3)/h; alcohol addition was 6001/h. It was found that below 6 kGy applied doses the NO sub(x) removal efficiency increased by 10% in the presence of alcohol as compared to the absence of alcohol; on the other hand, the NO sub(x) removal efficiency decreased at doses higher than 10 kGy. In order to understand the behavior of these aromatic hydrocarbons under electron irradiation, unirradiated samples (i.e. as emitted from the coal combustion process, called inlet) and irradiated samples (called outlet) were collected by using a condense bottle connected with an XAD-2 adsorbent and an active carbon adsorbent and were then analyzed by a GC-MS. It was found that using 8 kGy absorbed dose the concentration of aromatic hydrocarbons of small aromatic rings (&lt;3, except acenaphthylene) were reduced, but the concentration of these hydrocarbons of large aromatic rings ( greater than or equal to 4) were increased. A possible mechanism is proposed.</abstract><doi>10.1016/S0969-806X(03)00105-1</doi></addata></record>
fulltext fulltext
identifier ISSN: 0969-806X
ispartof Radiation physics and chemistry (Oxford, England : 1993), 2003-06, Vol.67 (3-4), p.555-560
issn 0969-806X
language eng
recordid cdi_proquest_miscellaneous_16157939
source Elsevier ScienceDirect Journals
title NO sub(x) and PAHs removal from industrial flue gas by using electron beam technology with alcohol addition
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-31T01%3A54%3A43IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=NO%20sub(x)%20and%20PAHs%20removal%20from%20industrial%20flue%20gas%20by%20using%20electron%20beam%20technology%20with%20alcohol%20addition&rft.jtitle=Radiation%20physics%20and%20chemistry%20(Oxford,%20England%20:%201993)&rft.au=Chmielewski,%20A%20G&rft.date=2003-06-01&rft.volume=67&rft.issue=3-4&rft.spage=555&rft.epage=560&rft.pages=555-560&rft.issn=0969-806X&rft_id=info:doi/10.1016/S0969-806X(03)00105-1&rft_dat=%3Cproquest%3E16157939%3C/proquest%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=16157939&rft_id=info:pmid/&rfr_iscdi=true