From Ketones to Esters by a Cu-Catalyzed Highly Selective C(CO)–C(alkyl) Bond Cleavage: Aerobic Oxidation and Oxygenation with Air

The Cu-catalyzed aerobic oxidative esterification of simple ketones via C–C bond cleavage has been developed. Varieties of common ketones, even inactive aryl long-chain alkyl ketones, are selectively converted into esters. The reaction tolerates a wide range of alcohols, including primary and second...

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Veröffentlicht in:	Journal of the American Chemical Society 2014-10, Vol.136 (42), p.14858-14865
Hauptverfasser:	Huang, Xiaoqiang, Li, Xinyao, Zou, Miancheng, Song, Song, Tang, Conghui, Yuan, Yizhi, Jiao, Ning
Format:	Artikel
Sprache:	eng
Schlagworte:	Air Catalysis Esters Ketones - chemistry Oxidation-Reduction Oxygen - chemistry Substrate Specificity
Online-Zugang:	Volltext
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