Precipitation of jarosite compounds as a method for removing impurities from acidic wastes from chemical coal cleaning
Spent acid from the washing stage of chemical coal cleaning processes contains sodium, iron, and sulfate impurities. One option for treating the spent acid stream is to precipitate the impurities as double salts in the jarosite compound family. This technique was studied in relation to reaction time...
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Veröffentlicht in: | Environmental science & technology 1991-03, Vol.25 (3), p.449-455 |
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creator | Norton, Glenn A Richardson, Richard G Markuszewski, Richard Levine, Audrey D |
description | Spent acid from the washing stage of chemical coal cleaning processes contains sodium, iron, and sulfate impurities. One option for treating the spent acid stream is to precipitate the impurities as double salts in the jarosite compound family. This technique was studied in relation to reaction time and pH. Fe and sulfate were removed effectively from model solutions at pH levels of 1.5-2.3, but optimum Na removal was possible only within the narrow pH range of 1.4-1.6. Maximum precipitate yields were realized within about 6 hr at both 80 and 95 degree C, with at least 80% of the Fe and sulfate and 60-75% of the Na removed. |
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One option for treating the spent acid stream is to precipitate the impurities as double salts in the jarosite compound family. This technique was studied in relation to reaction time and pH. Fe and sulfate were removed effectively from model solutions at pH levels of 1.5-2.3, but optimum Na removal was possible only within the narrow pH range of 1.4-1.6. Maximum precipitate yields were realized within about 6 hr at both 80 and 95 degree C, with at least 80% of the Fe and sulfate and 60-75% of the Na removed.</description><identifier>ISSN: 0013-936X</identifier><identifier>EISSN: 1520-5851</identifier><identifier>DOI: 10.1021/es00015a011</identifier><identifier>CODEN: ESTHAG</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Applied sciences ; Exact sciences and technology ; Industrial wastewaters ; Pollution ; Wastewaters ; Water treatment and pollution</subject><ispartof>Environmental science & technology, 1991-03, Vol.25 (3), p.449-455</ispartof><rights>1991 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a429t-b88fee33385f222520d2365e3efd5a5850c196a446d5e36ac9b60d71f2f137ac3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/es00015a011$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/es00015a011$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=19601730$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Norton, Glenn A</creatorcontrib><creatorcontrib>Richardson, Richard G</creatorcontrib><creatorcontrib>Markuszewski, Richard</creatorcontrib><creatorcontrib>Levine, Audrey D</creatorcontrib><title>Precipitation of jarosite compounds as a method for removing impurities from acidic wastes from chemical coal cleaning</title><title>Environmental science & technology</title><addtitle>Environ. 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Maximum precipitate yields were realized within about 6 hr at both 80 and 95 degree C, with at least 80% of the Fe and sulfate and 60-75% of the Na removed.</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>Industrial wastewaters</subject><subject>Pollution</subject><subject>Wastewaters</subject><subject>Water treatment and pollution</subject><issn>0013-936X</issn><issn>1520-5851</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1991</creationdate><recordtype>article</recordtype><recordid>eNqFkV9rFTEQxYMoeK0--QXyoj7IaibZZHcftWgrXLBgpcWXMM1ObK67m22yW-u3N-XWPw-CEBI4-c1h5gxjT0G8AiHhNWUhBGgUAPfYBrQUlW413GebIquqU-b8IXuU865gUol2w65PErkwhwWXECcePd9hijksxF0c57hOfeZYDh9puYw99zHxRGO8DtNXHsZ5TWEJlLlPceToQh8c_455-SW5SxqDw6HY3V4D4VQqH7MHHodMT-7eA_b5_bvTw-Nq-_How-GbbYW17Jbqom09kVKq1V5KWebppTKaFPleYxlNOOgM1rXpi2jQdRdG9A146UE16NQBe773nVO8WikvdgzZ0TDgRHHNFnQntKnh_2AtDSjTFfDlHnQlppzI2zmFEdMPC8LeLsH-tYRCP7uzxVxC8AknF_Kfks4IaJQoXLXnQknu5vc_pm_WNKrR9vTkkz2Ds_PtcfPFvi38iz2PLttdXNNUUvxnBz8Buc6j1w</recordid><startdate>19910301</startdate><enddate>19910301</enddate><creator>Norton, Glenn A</creator><creator>Richardson, Richard G</creator><creator>Markuszewski, Richard</creator><creator>Levine, Audrey D</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>C1K</scope><scope>SOI</scope><scope>7T2</scope><scope>7TV</scope><scope>7U2</scope></search><sort><creationdate>19910301</creationdate><title>Precipitation of jarosite compounds as a method for removing impurities from acidic wastes from chemical coal cleaning</title><author>Norton, Glenn A ; Richardson, Richard G ; Markuszewski, Richard ; Levine, Audrey D</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a429t-b88fee33385f222520d2365e3efd5a5850c196a446d5e36ac9b60d71f2f137ac3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1991</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>Industrial wastewaters</topic><topic>Pollution</topic><topic>Wastewaters</topic><topic>Water treatment and pollution</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Norton, Glenn A</creatorcontrib><creatorcontrib>Richardson, Richard G</creatorcontrib><creatorcontrib>Markuszewski, Richard</creatorcontrib><creatorcontrib>Levine, Audrey D</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><collection>Health and Safety Science Abstracts (Full archive)</collection><collection>Pollution Abstracts</collection><collection>Safety Science and Risk</collection><jtitle>Environmental science & technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Norton, Glenn A</au><au>Richardson, Richard G</au><au>Markuszewski, Richard</au><au>Levine, Audrey D</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Precipitation of jarosite compounds as a method for removing impurities from acidic wastes from chemical coal cleaning</atitle><jtitle>Environmental science & technology</jtitle><addtitle>Environ. 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subjects | Applied sciences Exact sciences and technology Industrial wastewaters Pollution Wastewaters Water treatment and pollution |
title | Precipitation of jarosite compounds as a method for removing impurities from acidic wastes from chemical coal cleaning |
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