Nonlocal reactive transport with physical, chemical, and biological heterogeneity

When a natural porous medium is viewed from an eulerian perspective, incomplete characterization of the hydraulic conductivity, chemical reactivity, and biological activity leads to nonlocal constitutive theories, irrespective of whether the medium has evolving heterogeneity with fluctuations over a...

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Veröffentlicht in:Advances in water resources 1997, Vol.20 (5), p.293-308
Hauptverfasser: Hu, Bill X., Cushman, John H., Deng, Fei-Wen
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creator Hu, Bill X.
Cushman, John H.
Deng, Fei-Wen
description When a natural porous medium is viewed from an eulerian perspective, incomplete characterization of the hydraulic conductivity, chemical reactivity, and biological activity leads to nonlocal constitutive theories, irrespective of whether the medium has evolving heterogeneity with fluctuations over all scales. Within this framework a constitutive theory involving nonlocal dispersive and convective fluxes and nonlocal sources/sinks is developed for chemicals undergoing random linear nonequilibrium reactions and random equilibrium first-order decay in a random conductivity field. The resulting transport equations are solved exactly in Fourier-Laplace space and then numerically inverted to real space. Mean concentration contours and various spatial moments are presented graphically for several covariance structures. © 1997 Published by Elsevier Science Ltd. All rights reserved
doi_str_mv 10.1016/S0309-1708(96)00051-6
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subjects biodegradation
chemical reactions
contaminants
equations
groundwater contamination
groundwater flow
mathematics and statistics
pollutants
porous media
transport equations
transport processes
title Nonlocal reactive transport with physical, chemical, and biological heterogeneity
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