Novel Redox Chemistry of [3Fe−4S] Clusters:  Electrochemical Characterization of the All-Fe(II) Form of the [3Fe−4S] Cluster Generated Reversibly in Various Proteins and Its Spectroscopic Investigation in Sulfolobus acidocaldarius Ferredoxin

The novel “hyper-reduced” form of protein-bound [3Fe−4S] clusters, which is two electron equivalents below the normal reduced form [3Fe−4S]0 and thus formally composed entirely of Fe(II) subsites, has been characterized by electrochemistry and by EPR, MCD, and UV/visible spectroscopy. The two-electr...

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Veröffentlicht in:	Journal of the American Chemical Society 1996-09, Vol.118 (36), p.8593-8603
Hauptverfasser:	Duff, Jillian L. C, Breton, Jacques L. J, Butt, Julea N, Armstrong, Fraser A, Thomson, Andrew J
Format:	Artikel
Sprache:	eng
Schlagworte:	Sulfolobus acidocaldarius
Online-Zugang:	Volltext
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