Simultaneous two and three photon resonant enhancement of third-order NLO susceptibility in an azo-dye functionalized polymer film

We report the observation of simultaneous two and three photon resonances, enhancing the third-order NLO susceptibility in a thin film of an azo-dye polymer. The possibility of 2-3 orders of magnitude increase in χ((3)) susceptibility is sustained by quantum mechanical calculations. This improves th...

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Veröffentlicht in:Physical chemistry chemical physics : PCCP 2013-01, Vol.15 (19), p.7060-7063
Hauptverfasser: JERCA, Florica Adriana, JERCA, Valentin Victor, KAJZAR, Francois, MANEA, Ana Maria, RAU, Ileana, MIRCEA VULUGA, Dumitru
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container_end_page 7063
container_issue 19
container_start_page 7060
container_title Physical chemistry chemical physics : PCCP
container_volume 15
creator JERCA, Florica Adriana
JERCA, Valentin Victor
KAJZAR, Francois
MANEA, Ana Maria
RAU, Ileana
MIRCEA VULUGA, Dumitru
description We report the observation of simultaneous two and three photon resonances, enhancing the third-order NLO susceptibility in a thin film of an azo-dye polymer. The possibility of 2-3 orders of magnitude increase in χ((3)) susceptibility is sustained by quantum mechanical calculations. This improves the applications of azo-polymers in all optical signal processing as well as in nonlinear optical imaging.
doi_str_mv 10.1039/c3cp50547b
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Applied sciences
Exact sciences and technology
Forms of application and semi-finished materials
Mathematical analysis
Nonlinearity
Optical data processing
Photons
Physical chemistry
Polymer industry, paints, wood
Polymeric films
Quantum mechanics
Sheets and films
Technology of polymers
Thin films
title Simultaneous two and three photon resonant enhancement of third-order NLO susceptibility in an azo-dye functionalized polymer film
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