Microporous metal–organic frameworks built from rigid tetrahedral tetrakis(4-tetrazolylphenyl)silane connectors

Microporous metal–organic frameworks built from rigid tetrahedral tetrakis(4-tetrazolylphenyl)silane connectors

Rigid tetrahedral ligands are of particular interest in Metal–Organic Framework (MOF) construction due to their highly branched nature, high symmetry and also their rarity. Within this context the silicon-centred linker tetrakis(4-tetrazolylphenyl)silane is shown to give porous networks exhibiting f...

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Veröffentlicht in:CrystEngComm 2014-01, Vol.16 (35), p.8094-8097
Hauptverfasser: Timokhin, I., White, A. J. P., Lickiss, P. D., Pettinari, C., Davies, R. P.
Format: Artikel
Sprache:eng
Schlagworte:
Branched
Cadmium bronzes
Connectors
Garnets
Ligands
Metal-organic frameworks
Networks
Symmetry
Topology
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Zusammenfassung:Rigid tetrahedral ligands are of particular interest in Metal–Organic Framework (MOF) construction due to their highly branched nature, high symmetry and also their rarity. Within this context the silicon-centred linker tetrakis(4-tetrazolylphenyl)silane is shown to give porous networks exhibiting fluorite or garnet topology with copper( ii ), manganese( ii ) and cadmium( ii ) metal based nodes.
ISSN:1466-8033
1466-8033
DOI:10.1039/C4CE00486H