Exploring the in situ Utilization of Cyclic Imine Intermediates Generated by Isocyanoacetate Cycloaddition: Convergent Assembly of cis-3a,8a-Hexahydropyrrolo[2,3-b]indole Scaffolds

Under copper(I) or silver(I)/base cocatalysis conditions, transient 2H‐pyrroline intermediates generated by the cycloaddition of isocyanoacetates and olefins can be in situ subjected to further transformations. A strategically novel, convergent, mild, efficient, general and atom‐economic access to c...

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Veröffentlicht in:	Advanced synthesis & catalysis 2014-08, Vol.356 (11-12), p.2477-2484
Hauptverfasser:	Huang, Lin, Cheng, Hengguang, Zhang, Runmei, Wang, Min, Xie, Chunsong
Format:	Artikel
Sprache:	eng
Schlagworte:	3-b]indoles Assembly Cycloaddition domino reactions hexahydropyrrolo hexahydropyrrolo[2,3‐b]indoles Imines Indoles isocyanoacetates Olefins Scaffolds Synthesis Transformations
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