A nanoporous oxide interlayer makes a better Pt catalyst on a metallic substrate: Nanoflowers on a nanotube bed

To improve the contact between platinum catalyst and titanium substrate, a layer of TiO2 nanotube arrays has been synthesized before depositing Pt nanoflowers by pulse electrodeposition. Dramatic improvements in electrocatalytic activity (3x) and stability (60x) for methanol oxidation were found, su...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Nano research 2014-07, Vol.7 (7), p.1007-1017
Hauptverfasser: Li, Hongyi, Wang, Jinshu, Liu, Man, Wang, Hong, Su, Penglei, Wu, Junshu, Li, Ju
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 1017
container_issue 7
container_start_page 1007
container_title Nano research
container_volume 7
creator Li, Hongyi
Wang, Jinshu
Liu, Man
Wang, Hong
Su, Penglei
Wu, Junshu
Li, Ju
description To improve the contact between platinum catalyst and titanium substrate, a layer of TiO2 nanotube arrays has been synthesized before depositing Pt nanoflowers by pulse electrodeposition. Dramatic improvements in electrocatalytic activity (3x) and stability (60x) for methanol oxidation were found, suggesting promising applications in direct methanol fuel cells. The 3x and 60x improvements persist for Pt/Pd catalysts used to overcome the CO poisoning problem.
doi_str_mv 10.1007/s12274-014-0464-5
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1567102087</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><cqvip_id>662501306</cqvip_id><sourcerecordid>1567102087</sourcerecordid><originalsourceid>FETCH-LOGICAL-c409t-d59743a9eeef4a031045d619cc0fb2f069ab51ac7e4ae8cb38f39c8a956e8bf3</originalsourceid><addsrcrecordid>eNp9kc1OxCAUhRujiTr6AO6IbtxULxRoWRrjX2LUhXtCmVutdsoM0Oi8is_iO_kKMqka40ISwuXmO-dCTpbtUTiiAOVxoIyVPAeaNpc8F2vZFlWqyiGt9e-aMr6ZbYfwBCAZ5dVWtjghvend3Hk3BOJe2ymSto_oO7NET2bmGQMxpMaYeuQuEmui6ZYhEten_gzTrWstCUMdojcRP97fyE1ybDr3gj6M2GpEHGpMPtOdbKMxXcDdr3OS3Z-f3Z9e5te3F1enJ9e55aBiPhWq5IVRiNhwAwUFLqaSKmuhqVkDUplaUGNL5AYrWxdVUyhbGSUkVnVTTLLD0Xbu3WLAEPWsDRa7zvSYvqqpkCUFBlWZ0IM_6JMbfJ8elyguqBQVZ4miI2W9C8Fjo-e-nRm_1BT0KgM9ZqBTBnqVgRZJw0ZNSGz_gP6X8z-i_a9Bj65_WCTdzyQpmQBagCw-ASTclyo</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1545165842</pqid></control><display><type>article</type><title>A nanoporous oxide interlayer makes a better Pt catalyst on a metallic substrate: Nanoflowers on a nanotube bed</title><source>SpringerNature Complete Journals</source><creator>Li, Hongyi ; Wang, Jinshu ; Liu, Man ; Wang, Hong ; Su, Penglei ; Wu, Junshu ; Li, Ju</creator><creatorcontrib>Li, Hongyi ; Wang, Jinshu ; Liu, Man ; Wang, Hong ; Su, Penglei ; Wu, Junshu ; Li, Ju</creatorcontrib><description>To improve the contact between platinum catalyst and titanium substrate, a layer of TiO2 nanotube arrays has been synthesized before depositing Pt nanoflowers by pulse electrodeposition. Dramatic improvements in electrocatalytic activity (3x) and stability (60x) for methanol oxidation were found, suggesting promising applications in direct methanol fuel cells. The 3x and 60x improvements persist for Pt/Pd catalysts used to overcome the CO poisoning problem.</description><identifier>ISSN: 1998-0124</identifier><identifier>EISSN: 1998-0000</identifier><identifier>DOI: 10.1007/s12274-014-0464-5</identifier><language>eng</language><publisher>Heidelberg: Tsinghua University Press</publisher><subject>Arrays ; Atomic/Molecular Structure and Spectra ; Biomedicine ; Biotechnology ; Catalysts ; Chemistry and Materials Science ; Condensed Matter Physics ; Electrodes ; Fuel cells ; Materials Science ; Methanol ; Methyl alcohol ; Morphology ; Nanoparticles ; Nanostructure ; Nanotechnology ; Oxidation ; Palladium ; Particle size ; Platinum ; Research Article ; Sulfuric acid ; Thin films ; Titanium ; Titanium dioxide ; 甲醇氧化 ; 电催化活性 ; 直接甲醇燃料电池 ; 纳米多孔 ; 纳米管阵列 ; 脉冲电沉积 ; 金属基板 ; 铂催化剂</subject><ispartof>Nano research, 2014-07, Vol.7 (7), p.1007-1017</ispartof><rights>Tsinghua University Press and Springer-Verlag Berlin Heidelberg 2014</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c409t-d59743a9eeef4a031045d619cc0fb2f069ab51ac7e4ae8cb38f39c8a956e8bf3</citedby><cites>FETCH-LOGICAL-c409t-d59743a9eeef4a031045d619cc0fb2f069ab51ac7e4ae8cb38f39c8a956e8bf3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/71233X/71233X.jpg</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12274-014-0464-5$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12274-014-0464-5$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Li, Hongyi</creatorcontrib><creatorcontrib>Wang, Jinshu</creatorcontrib><creatorcontrib>Liu, Man</creatorcontrib><creatorcontrib>Wang, Hong</creatorcontrib><creatorcontrib>Su, Penglei</creatorcontrib><creatorcontrib>Wu, Junshu</creatorcontrib><creatorcontrib>Li, Ju</creatorcontrib><title>A nanoporous oxide interlayer makes a better Pt catalyst on a metallic substrate: Nanoflowers on a nanotube bed</title><title>Nano research</title><addtitle>Nano Res</addtitle><addtitle>Nano Research</addtitle><description>To improve the contact between platinum catalyst and titanium substrate, a layer of TiO2 nanotube arrays has been synthesized before depositing Pt nanoflowers by pulse electrodeposition. Dramatic improvements in electrocatalytic activity (3x) and stability (60x) for methanol oxidation were found, suggesting promising applications in direct methanol fuel cells. The 3x and 60x improvements persist for Pt/Pd catalysts used to overcome the CO poisoning problem.</description><subject>Arrays</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Biomedicine</subject><subject>Biotechnology</subject><subject>Catalysts</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Electrodes</subject><subject>Fuel cells</subject><subject>Materials Science</subject><subject>Methanol</subject><subject>Methyl alcohol</subject><subject>Morphology</subject><subject>Nanoparticles</subject><subject>Nanostructure</subject><subject>Nanotechnology</subject><subject>Oxidation</subject><subject>Palladium</subject><subject>Particle size</subject><subject>Platinum</subject><subject>Research Article</subject><subject>Sulfuric acid</subject><subject>Thin films</subject><subject>Titanium</subject><subject>Titanium dioxide</subject><subject>甲醇氧化</subject><subject>电催化活性</subject><subject>直接甲醇燃料电池</subject><subject>纳米多孔</subject><subject>纳米管阵列</subject><subject>脉冲电沉积</subject><subject>金属基板</subject><subject>铂催化剂</subject><issn>1998-0124</issn><issn>1998-0000</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9kc1OxCAUhRujiTr6AO6IbtxULxRoWRrjX2LUhXtCmVutdsoM0Oi8is_iO_kKMqka40ISwuXmO-dCTpbtUTiiAOVxoIyVPAeaNpc8F2vZFlWqyiGt9e-aMr6ZbYfwBCAZ5dVWtjghvend3Hk3BOJe2ymSto_oO7NET2bmGQMxpMaYeuQuEmui6ZYhEten_gzTrWstCUMdojcRP97fyE1ybDr3gj6M2GpEHGpMPtOdbKMxXcDdr3OS3Z-f3Z9e5te3F1enJ9e55aBiPhWq5IVRiNhwAwUFLqaSKmuhqVkDUplaUGNL5AYrWxdVUyhbGSUkVnVTTLLD0Xbu3WLAEPWsDRa7zvSYvqqpkCUFBlWZ0IM_6JMbfJ8elyguqBQVZ4miI2W9C8Fjo-e-nRm_1BT0KgM9ZqBTBnqVgRZJw0ZNSGz_gP6X8z-i_a9Bj65_WCTdzyQpmQBagCw-ASTclyo</recordid><startdate>20140701</startdate><enddate>20140701</enddate><creator>Li, Hongyi</creator><creator>Wang, Jinshu</creator><creator>Liu, Man</creator><creator>Wang, Hong</creator><creator>Su, Penglei</creator><creator>Wu, Junshu</creator><creator>Li, Ju</creator><general>Tsinghua University Press</general><general>Springer Nature B.V</general><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>~WA</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SE</scope><scope>7SR</scope><scope>7U5</scope><scope>7X7</scope><scope>7XB</scope><scope>8AO</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FH</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BBNVY</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>FR3</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>H8G</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>K9.</scope><scope>KB.</scope><scope>L7M</scope><scope>LK8</scope><scope>M0S</scope><scope>M7P</scope><scope>P64</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20140701</creationdate><title>A nanoporous oxide interlayer makes a better Pt catalyst on a metallic substrate: Nanoflowers on a nanotube bed</title><author>Li, Hongyi ; Wang, Jinshu ; Liu, Man ; Wang, Hong ; Su, Penglei ; Wu, Junshu ; Li, Ju</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c409t-d59743a9eeef4a031045d619cc0fb2f069ab51ac7e4ae8cb38f39c8a956e8bf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Arrays</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Biomedicine</topic><topic>Biotechnology</topic><topic>Catalysts</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Electrodes</topic><topic>Fuel cells</topic><topic>Materials Science</topic><topic>Methanol</topic><topic>Methyl alcohol</topic><topic>Morphology</topic><topic>Nanoparticles</topic><topic>Nanostructure</topic><topic>Nanotechnology</topic><topic>Oxidation</topic><topic>Palladium</topic><topic>Particle size</topic><topic>Platinum</topic><topic>Research Article</topic><topic>Sulfuric acid</topic><topic>Thin films</topic><topic>Titanium</topic><topic>Titanium dioxide</topic><topic>甲醇氧化</topic><topic>电催化活性</topic><topic>直接甲醇燃料电池</topic><topic>纳米多孔</topic><topic>纳米管阵列</topic><topic>脉冲电沉积</topic><topic>金属基板</topic><topic>铂催化剂</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Hongyi</creatorcontrib><creatorcontrib>Wang, Jinshu</creatorcontrib><creatorcontrib>Liu, Man</creatorcontrib><creatorcontrib>Wang, Hong</creatorcontrib><creatorcontrib>Su, Penglei</creatorcontrib><creatorcontrib>Wu, Junshu</creatorcontrib><creatorcontrib>Li, Ju</creatorcontrib><collection>中文科技期刊数据库</collection><collection>中文科技期刊数据库-CALIS站点</collection><collection>中文科技期刊数据库-7.0平台</collection><collection>中文科技期刊数据库- 镜像站点</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Health &amp; Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>ProQuest Pharma Collection</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Natural Science Collection</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science &amp; Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>Biological Science Collection</collection><collection>ProQuest Central</collection><collection>Technology Collection (ProQuest)</collection><collection>Natural Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>Engineering Research Database</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>Copper Technical Reference Library</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>ProQuest Health &amp; Medical Complete (Alumni)</collection><collection>Materials Science Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>ProQuest Biological Science Collection</collection><collection>Health &amp; Medical Collection (Alumni Edition)</collection><collection>Biological Science Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Nano research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Hongyi</au><au>Wang, Jinshu</au><au>Liu, Man</au><au>Wang, Hong</au><au>Su, Penglei</au><au>Wu, Junshu</au><au>Li, Ju</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A nanoporous oxide interlayer makes a better Pt catalyst on a metallic substrate: Nanoflowers on a nanotube bed</atitle><jtitle>Nano research</jtitle><stitle>Nano Res</stitle><addtitle>Nano Research</addtitle><date>2014-07-01</date><risdate>2014</risdate><volume>7</volume><issue>7</issue><spage>1007</spage><epage>1017</epage><pages>1007-1017</pages><issn>1998-0124</issn><eissn>1998-0000</eissn><abstract>To improve the contact between platinum catalyst and titanium substrate, a layer of TiO2 nanotube arrays has been synthesized before depositing Pt nanoflowers by pulse electrodeposition. Dramatic improvements in electrocatalytic activity (3x) and stability (60x) for methanol oxidation were found, suggesting promising applications in direct methanol fuel cells. The 3x and 60x improvements persist for Pt/Pd catalysts used to overcome the CO poisoning problem.</abstract><cop>Heidelberg</cop><pub>Tsinghua University Press</pub><doi>10.1007/s12274-014-0464-5</doi><tpages>11</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1998-0124
ispartof Nano research, 2014-07, Vol.7 (7), p.1007-1017
issn 1998-0124
1998-0000
language eng
recordid cdi_proquest_miscellaneous_1567102087
source SpringerNature Complete Journals
subjects Arrays
Atomic/Molecular Structure and Spectra
Biomedicine
Biotechnology
Catalysts
Chemistry and Materials Science
Condensed Matter Physics
Electrodes
Fuel cells
Materials Science
Methanol
Methyl alcohol
Morphology
Nanoparticles
Nanostructure
Nanotechnology
Oxidation
Palladium
Particle size
Platinum
Research Article
Sulfuric acid
Thin films
Titanium
Titanium dioxide
甲醇氧化
电催化活性
直接甲醇燃料电池
纳米多孔
纳米管阵列
脉冲电沉积
金属基板
铂催化剂
title A nanoporous oxide interlayer makes a better Pt catalyst on a metallic substrate: Nanoflowers on a nanotube bed
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-07T09%3A43%3A56IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20nanoporous%20oxide%20interlayer%20makes%20a%20better%20Pt%20catalyst%20on%20a%20metallic%20substrate%EF%BC%9A%20Nanoflowers%20on%20a%20nanotube%20bed&rft.jtitle=Nano%20research&rft.au=Li,%20Hongyi&rft.date=2014-07-01&rft.volume=7&rft.issue=7&rft.spage=1007&rft.epage=1017&rft.pages=1007-1017&rft.issn=1998-0124&rft.eissn=1998-0000&rft_id=info:doi/10.1007/s12274-014-0464-5&rft_dat=%3Cproquest_cross%3E1567102087%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1545165842&rft_id=info:pmid/&rft_cqvip_id=662501306&rfr_iscdi=true