Correlation of mobility and molecular packing in organic transistors based on cycloalkyl naphthalene diimides
A series of cycloalkyl-substituted naphthalene tetracarboxylic diimides (Cyn-NTCDIs, n= 3-8) are prepared and the transistor properties and molecular packings are systematically investigated. Cy5-Cy8-NTCDIs have similar brickwork structures, where two molecules are located on the top of a molecule w...
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| Veröffentlicht in: | Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2013-01, Vol.1 (34), p.5395-5401 |
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| container_issue | 34 |
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| container_title | Journal of materials chemistry. C, Materials for optical and electronic devices |
| container_volume | 1 |
| creator | Kakinuma, Tomoyuki Kojima, Hirotaka Ashizawa, Minoru Matsumoto, Hidetoshi Mori, Takehiko |
| description | A series of cycloalkyl-substituted naphthalene tetracarboxylic diimides (Cyn-NTCDIs, n= 3-8) are prepared and the transistor properties and molecular packings are systematically investigated. Cy5-Cy8-NTCDIs have similar brickwork structures, where two molecules are located on the top of a molecule with large displacement along the molecular shortaxis. The intermolecular overlap is maximized when the small slipping along the molecular longaxis makes the molecules nearly perpendicular to the substrate. Consequently, the mobility decreases exactly in the same order as the interlayer d-spacings. |
| doi_str_mv | 10.1039/c3tc30920g |
| format | Article |
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Cy5-Cy8-NTCDIs have similar brickwork structures, where two molecules are located on the top of a molecule with large displacement along the molecular shortaxis. The intermolecular overlap is maximized when the small slipping along the molecular longaxis makes the molecules nearly perpendicular to the substrate. Consequently, the mobility decreases exactly in the same order as the interlayer d-spacings.</description><identifier>ISSN: 2050-7526</identifier><identifier>EISSN: 2050-7534</identifier><identifier>DOI: 10.1039/c3tc30920g</identifier><language>eng</language><subject>Correlation ; Diimide ; Displacement ; Interlayers ; Molecular structure ; Naphthalene ; Semiconductor devices ; Transistors</subject><ispartof>Journal of materials chemistry. 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Cy5-Cy8-NTCDIs have similar brickwork structures, where two molecules are located on the top of a molecule with large displacement along the molecular shortaxis. The intermolecular overlap is maximized when the small slipping along the molecular longaxis makes the molecules nearly perpendicular to the substrate. Consequently, the mobility decreases exactly in the same order as the interlayer d-spacings.</abstract><doi>10.1039/c3tc30920g</doi><tpages>7</tpages></addata></record> |
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| ispartof | Journal of materials chemistry. C, Materials for optical and electronic devices, 2013-01, Vol.1 (34), p.5395-5401 |
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| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Correlation Diimide Displacement Interlayers Molecular structure Naphthalene Semiconductor devices Transistors |
| title | Correlation of mobility and molecular packing in organic transistors based on cycloalkyl naphthalene diimides |
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