First-principle investigation on mechanism of Ca ion activating flotation of spodumene

Different hypotheses of the activation mechanisms of metallic ions for silicate minerals flotation were stated in this work. Spodumene and Ca ion were taken to illustrate this issue. Flotation test results and diagram of Ca ion species distribution vs pH show that the dominant hydrolyzed species are...

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Veröffentlicht in:Rare metals 2014-06, Vol.33 (3), p.358-362
Hauptverfasser: Yu, Fu-Shun, Wang, Yu-Hua, Wang, Jin-Ming, Xie, Zhen-Fu, Zhang, Lei
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container_title Rare metals
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creator Yu, Fu-Shun
Wang, Yu-Hua
Wang, Jin-Ming
Xie, Zhen-Fu
Zhang, Lei
description Different hypotheses of the activation mechanisms of metallic ions for silicate minerals flotation were stated in this work. Spodumene and Ca ion were taken to illustrate this issue. Flotation test results and diagram of Ca ion species distribution vs pH show that the dominant hydrolyzed species are Ca(OH)?and Ca(OH)2, which is in correspondence with the maximum flotation recovery of spodumene. Density functional theory(DFT) calculation results reveal further that the precipitation of calcium hydroxide on spodumene surface is the effective process to activate the flotation of spodumene.
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source SpringerLink Journals; Alma/SFX Local Collection
subjects Biomaterials
Ca(OH)2
Chemistry and Materials Science
Density functional theory
Energy
Flotation
Materials Engineering
Materials Science
Mathematical analysis
Metallic Materials
Nanoscale Science and Technology
Physical Chemistry
Precipitation
Silicates
Slaked lime
Spodumene
Surface chemistry
密度泛函理论
浮选回收率
激活机制
矿物浮选
第一性原理
钙离子
锂辉石
title First-principle investigation on mechanism of Ca ion activating flotation of spodumene
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